A re-visitation of Joule’s experiment motivates a critical analysis of thermodynamic notions: heat, total energy, first principle, organization of a scientific theory, its relationships with logic and mathematics. A rational re-construction of thermodynamics is suggested according to the model of a problem-based organization, that Sadi Carnot applied to his formulation. The new formulation accomplishes the long time theoretical process started by Joule’s experiment within physicists community's collective mind, i.e. the process of exiting out Baconian science for suggesting a first theory (...) out Newton’s paradigm, and eventually for introducing a pluralism of incompatible physical theories. (shrink)

All suggested notions of reduction of two scientific theories are critically reviewed and analyzed. In particular those applied to the case of the alleged reduction of Chemistry to Quantum mechanics are examined. Since it is recognized that the weakness of this field of research is the lack of a definition of a scientific theory, it is suggested that a scientific theory is characterized by two choices regarding two dichotomies, that is, the kind of mathematics and the kind of logic. According (...) to this view a reduction is only possible between two theories in which the same choices are shared. As a consequence, only one case of reduction in the history of physics is recognized: physical optics to electromagnetism, a case that is commonly accepted. The other cases of claimed reductions are recognized as impossible, owing to the different choices of the two theories at issue and hence the radical variations in meaning of their shared basic notions. In particular, the claimed reduction of Chemistry to Quantum mechanics is disproved in detail. (shrink)