The term philosophy of chemistry is here construed broadly to include some publications from the history of chemistry and chemical education. Of course this initial selection of material has inevitably been biased by the interests of the author. This bibliography supersedes that of van Brakel and Vermeeren (1981), although no attempt has been made to include every single one of their entries, especially in languages other than English. Also, readers interested particularly in articles in German may wish to consult the (...) bibliography by Dittus and Mayer which also contains some material not included here (Dittus and Mayer, 1992). The aim is to maintain an up-to-date version of this bibliography and to publish a revised version in due course. Suggestions for further inclusions should be sent to the author. (shrink)

The relational approach to tense holds that the now, passage, and becoming are to be understood in terms of relations between events. The debate over the adequacy of this framework is illustrated by a comparative study of the sense in which physical theories, (in)deterministic and (non)relativistic, can lend expression to the metaphysics at issue. The objective is not to settle the matter, but to clarify the nature of this metaphysics and to establish that the same issues are at stake in (...) the relational approach to value-definiteness and probability in quantum mechanics. They concern the existence of a unique present, respectively actuality, and a notion of identity over time that cannot be paraphrased in terms of relations. (shrink)

A variety of ideas arising in decoherence theory, and in the ongoing debate over Everett's relative-state theory, can be linked to issues in relativity theory and the philosophy of time, specifically the relational theory of tense and of identity over time. These have been systematically presented in companion papers (Saunders 1995; 1996a); in what follows we shall consider the same circle of ideas, but specifically in relation to the interpretation of probability, and its identification with relations in the Hilbert Space (...) norm. The familiar objection that Everett's approach yields probabilities different from quantum mechanics is easily dealt with. The more fundamental question is how to interpret these probabilities consistent with the relational theory of change, and the relational theory of identity over time. I shall show that the relational theory needs nothing more than the physical, minimal criterion of identity as defined by Everett's theory, and that this can be transparently interpreted in terms of the ordinary notion of the chance occurrence of an event, as witnessed in the present. It is in this sense that the theory has empirical content. (shrink)

We review the decoherent histories approach to the interpretation of quantum mechanics. The Everett relative-state theory is reformulated in terms of decoherent histories. A model of evolutionary adaptation is shown to imply decoherence. A general interpretative framework is proposed: probability and value-definiteness are to have a similar status to the attribution of tense in classical spacetime theory.

We demonstrate that the quantum-mechanical description of composite physical systems of an arbitrary number of similar fermions in all their admissible states, mixed or pure, for all finite-dimensional Hilbert spaces, is not in conflict with Leibniz's Principle of the Identity of Indiscernibles (PII). We discern the fermions by means of physically meaningful, permutation-invariant categorical relations, i.e. relations independent of the quantum-mechanical probabilities. If, indeed, probabilistic relations are permitted as well, we argue that similar bosons can also be discerned in all (...) their admissible states; but their categorical discernibility turns out to be a state-dependent matter. In all demonstrated cases of discernibility, the fermions and the bosons are discerned (i) with only minimal assumptions on the interpretation of quantum mechanics; (ii) without appealing to metaphysical notions, such as Scotusian haecceitas, Lockean substrata, Postian transcendental individuality or Adamsian primitive thisness; and (iii) without revising the general framework of classical elementary predicate logic and standard set theory, thus without revising standard mathematics. This confutes: (a) the currently dominant view that, provided (i) and (ii), the quantum-mechanical description of such composite physical systems always conflicts with PII; and (b) that if PII can be saved at all, the only way to do it is by adopting one or other of the thick metaphysical notions mentioned above. Among the most general and influential arguments for the currently dominant view are those due to Schrodinger, Margenau, Cortes, Dalla Chiara, Di Francia, Redhead, French, Teller, Butterfield, Giuntini, Mittelstaedt, Castellani, Krause and Huggett. We review them succinctly and critically as well as related arguments by van Fraassen and Massimi. (shrink)

Particle indistinguishability has always been considered a purely quantum mechanical concept. In parallel, indistinguishable particles have been thought to be entities that are not properly speaking objects at all. I argue, to the contrary, that the concept can equally be applied to classical particles, and that in either case particles may (with certain exceptions) be counted as objects even though they are indistinguishable. The exceptions are elementary bosons (for example photons).

We discuss three problems concerning the use of formal languages in theoretical physics: (i) the definability of time and spacetime in classical physical theories; (ii) how to cope with indistinguishable elementary particles in quantum mechanics without labeling them; and (iii) how to get a formal picture of quantum states jumping.

I examine two claims that arise in Brown’s account of inertial motion. Brown claims there is something objectionable about the way in which the motions of free particles in Newtonian theory and special relativity are coordinated. Brown also claims that since a geodesic principle can be derived in Einsteinian gravitation, the objectionable feature is explained away. I argue that there is nothing objectionable about inertia and that while the theorems that motivate Brown’s second claim can be said to figure in (...) a deductive-nomological explanation, their main contribution lies in their explication rather than their explanation of inertial motion. (shrink)

The empirical study of visual space has centered on determining its geometry, whether it is a perspective projection, flat or curved, Euclidean or non-Euclidean, whereas the topology of space consists of those properties that remain invariant under stretching but not tearing. For that reason distance is a property not preserved in topological space whereas the property of spatial order is preserved. Specifically the topological properties of dimensionality, orientability, continuity, and connectivity define “real” space as studied by physics and are the (...) spatial properties that characterize the physical universe as being an integral whole. By contrast the geometrical analysis of VS has taken little cognizance of its topology. Instead such properties have been presupposed a priori rather than being established a posteriori by empirical means, perhaps because these properties are self-evident. Applying the method of coordinative definition expounded by Hans Reichenbach for determining geometrical and topological properties of physical space, it can be shown that VS fulfills the topological criteria of being a “real” space sui generis. Though theorized to be produced by the brain, the topology of VS is not topologically equivalent with the structure and activity of the brain because, as will be shown, the topology of VS cannot be formed from the topology of the brain without tearing and/or cutting and pasting. (shrink)

This paper is a contribution to a book symposium on my book Experiencing Time. I reply to comments on the book by Natalja Deng, Geoffrey Lee and Bradford Skow. Although several chapters of the book are discussed, the main focus of my reply is on Chapters 2 and 6. In Chapter 2 I argue that the putative mind-independent passage of time could not be experienced, and from this I develop an argument against the A-theory of time. In Chapter 6 I (...) offer one part of an explanation of why we are disposed to think that time passes, relating to the supposedly ‘dynamic’ quality of experienced change. Deng, Lee, and Skow’s comments help me to clarify several issues, add some new thoughts, and make a new distinction that was needed, and I acknowledge, as I did in the book, that certain arguments in Chapter 6 are not conclusive; but I otherwise concede very little regarding the main claims and arguments defended in the book. (shrink)

This paper offers a new interpretation for Wittgenstein`s treatment of mathematical identities. As it is widely known, Wittgenstein`s mature philosophy of mathematics includes a general rejection of abstract objects. On the other hand, the traditional interpretation of mathematical identities involves precisely the idea of a single abstract object – usually a number –named by both sides of an equation.

My target is the epistemological dimension of the realism debate. After establishing a stance voluntarist framework with a Jamesian background, drawing mostly on Wylie, Chakravarty, and van Fraassen, I argue that current voluntarists are too permissive. I show that especially various anti-realist stances but also some realist and selective realist stances block themselves from refutation by the history of science. I argue that such stances should be rejected. Finally, I propose that any disagreement that cannot be resolved by this strategy (...) frequently boils down to an epistemic value disagreement about balancing the truth-goal. (shrink)

The paper explores the view that in mathematics, in particular where the infinite is involved, the application of classical logic to statements involving the infinite cannot be taken for granted. L. E. J. Brouwer’s well-known rejection of classical logic is sketched, and the views of David Hilbert and especially Hermann Weyl, both of whom used classical logic in their mathematical practice, are explored. We inquire whether arguments for a critical view can be found that are independent of constructivist premises and (...) consider the entanglement of logic and mathematics. This offers a convincing case regarding second-order logic, but for first-order logic, it is not so clear. Still, we ask whether we understand the application of logic to the higher infinite better than we understand the higher infinite itself. (shrink)

Saunders' recent arguments in favour of the weak discernibility of (certain) quantum particles seem to be grounded in the 'generalist' view that science only provides general descriptions of the worlIn this paper, I introduce the ‘generalist’ perspective and consider its possible justification and philosophical basis; and then look at the notion of weak discernibility. I expand on the criticisms formulated by Hawley (2006) and Dieks and Veerstegh (2008) and explain what I take to be the basic problem: that the properties (...) invoked by Saunders cannot be pointed to as ‘individuators’ of otherwise indiscernible (and thus numerically identical) entities because their ontological status remains underdetermined by the evidence and the established interpretation of the theory. In addition to to this, I suggest that Saunders does not deal adequately with bosons, and cannot do so exactly because he subscribes to PII and the generalist picture. The last part of the paper contains a critical examination of the claim (or at least implicit assumption) that the generalist picture should be regarded as obviously compelling by the modern-day empiricist. (shrink)

Mi objetivo es discutir las principales dificultades que Frank P. Ramsey encontró en Principia Mathematica y la solución que, vía el Tractatus Logico-Philosophicus, propuso al respecto. Sostengo que las principales dificultades que Ramsey encontró en Principia Mathematica están, todas, relacionadas con que Russell y Whitehead desatendieron la forma lógica de las proposiciones matemáticas, las cuales, según Ramsey, deben ser tautológicas.

The following definition of “objective” is proposed: A statement S is objective if and only if in S all parameters that are relevant to its truth value are made explicit. The objectivity of predicates and relations can be defined in a similar manner. This simple conception of objectivity-which could be called “explicitness conception of objectivity”-can be found in Hermann Weyl and plays a central part in the natural sciences. There are grades of objectivity depending on the ‘quality’ and the number (...) of parameters our predicates are relativized to A relativistic Ockham principle has to be recognized: Relativization parameters are not to be multiplied beyond necessity. The explicitness conception of objectivity is accessible to mathematical specifications, is the core of the idea of invariance, has a lot of philosophical applications and leads to precise notions of ‘subjectivity’ and a precise formulation of the problem of the limits of objectivity. (shrink)

This article deals with empty spacetime and the question of its physical reality. By “empty spacetime” we mean a collection of bare spacetime points, the remains of ridding spacetime of all matter and fields. We ask whether these geometric objects—themselves intrinsic to the concept of field—might be observable through some physical test. By taking quantum-mechanical notions into account, we challenge the negative conclusion drawn from the diffeomorphism invariance postulate of general relativity, and we propose new foundational ideas regarding the possible (...) observation—as well as conceptual overthrow—of this geometric ether. (shrink)

After a survey of disagreements among Thomists on the nature of mathematical abstraction, the author cites Aquinas's text Scriptum super libros Sententiarum, I, d. 2, a.3 (a late text inserted in an older work). It assimilates the objects of mathematics to those of logic, thus admitting a remote foundation in reality but not the direct one of the concepts of the physical sciences.

Absolutism about mass claims that mass ratios obtain in virtue of absolute masses. Comparativism denies this. Dasgupta, Oxford studies in metaphysics, Oxford University Press, Oxford, 2013) argues for comparativism about mass, in the context of Newtonian Gravity. Such an argument requires proving that comparativism is empirically adequate. Dasgupta equates this to showing that absolute masses are undetectable, and attempts to do so. This paper develops an argument by Baker to the contrary: absolute masses are in fact empirically meaningful, that is (...) detectable. Additionally, it is argued that the requirement of empirical adequacy should not be cashed out in terms of undetectability in the first place. The paper closes by sketching the possible strategies that remain for the comparativist. Along the way a framework is developed that is useful for thinking about these issues: Ozma games—how could one explain to an alien civilisation what an absolute mass is? (shrink)

The dependence on history of both present and future dynamics of life is a common intuition in biology and in humanities. Historicity will be understood in terms of changes of the space of possibilities as well as by the role of diversity in life’s structural stability and of rare events in history formation. We hint to a rigorous analysis of “path dependence” in terms of invariants and invariance preserving transformations, as it may be found also in physics, while departing from (...) the physico-mathematical analyses. The idea is that the invariant traces of the past under organismal or ecosystemic transformations contribute to the understanding of present and future states of affairs. This yields a peculiar form of unpredictability in biology, at the core of novelty formation: the changes of observables and pertinent parameters may depend also on past events. In particular, in relation to the properties of synchronic measurement in physics, the relevance of diachronic measurement in biology is highlighted. This analysis may a fortiori apply to cognitive and historical human dynamics, while allowing to investigate some general properties of historicity in biology. (shrink)

The aim of this paper is to put into context the historical, foundational and philosophical significance of category theory. We use our historical investigation to inform the various category-theoretic foundational debates and to point to some common elements found among those who advocate adopting a foundational stance. We then use these elements to argue for the philosophical position that category theory provides a framework for an algebraic in re interpretation of mathematical structuralism. In each context, what we aim to show (...) is that, whatever the significance of category theory, it need not rely upon any set-theoretic underpinning. (shrink)

The concept of indiscernibility in a structure is analysed with the aim of emphasizing that in asserting that two objects are indiscernible, it is useful to consider these objects as members of (the domain of) a structure. A case for this usefulness is presented by examining the consequences of this view to the philosophical discussion on identity and indiscernibility in quantum theory.

H. Post's conception of quantal particles as non-individuals is set in a formal logico-mathematical framework. By means of this approach certain metaphysical implications of quantum mechanics can be further explored.

Standard quantum mechanics unquestionably violates the separability principle that classical physics (be it point-like analytic, statistical, or field-theoretic) accustomed us to consider as valid. In this paper, quantum nonseparability is viewed as a consequence of the Hilbert-space quantum mechanical formalism, avoiding thus any direct recourse to the ramifications of Kochen-Specker’s argument or Bell’s inequality. Depending on the mode of assignment of states to physical systems – unit state vectors versus non-idempotent density operators – we distinguish between strong/relational and weak/deconstructional forms (...) of quantum nonseparability. The origin of the latter is traced down and discussed at length, whereas its relation to the all important concept of potentiality in forming a coherent picture of the puzzling entangled interconnections among spatially separated systems is also considered. Finally, certain philosophical consequences of quantum non-separability concerning the nature of quantum objects, the question of realism in quantum mechanics, and possible limitations in revealing the actual character of physical reality in its entirety are explored. (shrink)

It has been suggested that puzzles in the interpretation of quantum mechanics motivate consideration of entities that are numerically distinct but do not stand in a relation of identity with themselves or non-identity with others. Quite apart from metaphysical concerns, I argue that talk about such entities is either meaningless or not about such entities. It is meaningless insofar as we attempt to take the foregoing characterization literally. It is meaningful, however, if talk about entities without identity is taken as (...) elliptical for either nominal or predicative use of a special class of mass terms. (shrink)

This paper is concerned with the problem of experimental error. The prevalent view that experimental errors can be dismissed as a tiresome but trivial blemish on the method of experimentation is criticized. It is stressed that the occurrence of errors in experiments constitutes a permanent feature of the attempt to test theories in the physical world, and this feature deserves proper attention. It is suggested that a classification of types of experimental error may be useful as a heuristic device in (...) studying the nature of these errors. However, the standard classification of systematic and random errors is mathematically based does not focus on the causes of the errors, their origins, or the contexts in which they arise. A new typology of experimental errors is therefore proposed whose criterion is epistemological. This typology reflects the various stages that can be discerned in the execution of an experiment, each stage constituting a category of a certain type of experimental error. The proposed classification consists of four categories which are illustrated by historical cases. (shrink)

The living forms represented in this paper are sets of parts that spontaneously increase in organization. Their organizations are measured by an information-theoretic function derived from the work of Boltzmann and Shannon. We briefly review its derivation in the context of the troubled role of mathematics in biology, and then define the function. We illustrate its nature by measuring the 22 different organizations of a set of eight things; and we facilitate its use by defining the parameters that determine an (...) amount of organization. The measure is then applied to show that the organization of limb pairs on free-living arthropods, based on data given by Cisne, confirms a pattern of increasing organization in their evolution from the Cambrian era to the present. Further applications measure the changes in organizations of ideal (theoretical) life forms, and contrasting changes in inanimate systems. Our main results represent the reproduction of unicellular organisms, and the formation of hierarchies, as processes of increasing organization. (shrink)

To what extent can constructive mathematics based on intuitionistc logic recover the mathematics needed for spacetime physics? Certain aspects of this important question are examined, both technical and philosophical. On the technical side, order, connectivity, and extremization properties of the continuum are reviewed, and attention is called to certain striking results concerning causal structure in General Relativity Theory, in particular the singularity theorems of Hawking and Penrose. As they stand, these results appear to elude constructivization. On the philosophical side, it (...) is argued that any mentalist-based radical constructivism suffers from a kind of neo-Kantian apriorism. It would be at best a lucky accident if objective spacetime structure mirrored mentalist mathematics. the latter would seem implicitly committed to a Leibnizian relationist view of spacetime, but is it doubtful if implementation of such a view would overcome the objection. As a result, an anti-realist view of physics seems forced on the radical constructivist. (shrink)

The indistinguishability of bosons and fermions has been an essential part of our ideas of quantum mechanics since the 1920s. But what is the mathematical basis for this indistinguishability? An answer was provided in the group representation theory that developed alongside quantum theory and quickly became a major part of its mathematical structure. In the 1930s such a complex and seemingly abstract theory came to be rejected by physicists as the standard functional analysis picture presented by John von Neumann took (...) hold. The purpose of the present account is to show how indistinguishability is explained within representation theory. (shrink)

The Received View of particles in quantum mechanics is that they are indistinguishable entities within their kinds and that, as a consequence, they are not individuals in the metaphysical sense and self-identity does not meaningfully apply to them. Nevertheless cardinality does apply, in that one can have n> 1 such particles. A number of authors have recently argued that this cluster of claims is internally contradictory: roughly, that having more than one such particle requires that the concepts of distinctness and (...) identity must apply after all. A common thread here is that the notion of identity is too fundamental to forego in any metaphysical account. I argue that this argument fails. I then argue that the failure of individuality and identity applies also to macroscopic physical objects, that the problems cannot be constrained to apply only within the microscopic realm. (shrink)

The paper exposes the philosophical and mathematical flaws in an attempt to settle the continuum problem by a new class of axioms based on probabilistic reasoning. I also examine the larger proposal behind this approach, namely the introduction of new primitive notions that would supersede the set theoretic foundation of mathematics.

Husserl’s notion of definiteness, i.e., completeness is crucial to understanding Husserl’s view of logic, and consequently several related philosophical views, such as his argument against psychologism, his notion of ideality, and his view of formal ontology. Initially Husserl developed the notion of definiteness to clarify Hermann Hankel’s ‘principle of permanence’. One of the first attempts at formulating definiteness can be found in the Philosophy of Arithmetic, where definiteness serves the purpose of the modern notion of ‘soundness’ and leads Husserl to (...) a ‘computational’ view of logic. Inspired by Gauss and Grassmann Husserl then undertakes a further investigation of theories of manifolds. When Husserl subsequently renounces psychologism and changes his view of logic, his idea of definiteness also develops. The notion of definiteness is discussed most extensively in the pair of lectures Husserl gave in front of the mathematical society in Göttingen (1901). A detailed analysis of the lectures, together with an elaboration of Husserl’s lectures on logic beginning in 1895, shows that Husserl meant by definiteness what is today called ‘categoricity’. In so doing Husserl was not doing anything particularly original; since Dedekind’s ‘Was sind und sollen die Zahlen’ (1888) the notion was ‘in the air’. It also characterizes Hilbert’s (1900) notion of completeness. In the end, Husserl’s view of definiteness is discussed in light of Gödel’s (1931) incompleteness results. (shrink)

This paper explicates Husserl’s usage of what he calls “radical Besinnung” in Formale und transzendentale Logik. Husserl introduces radical Besinnung as his method in the introduction to FTL. Radical Besinnung aims at criticizing the practice of formal sciences by means of transcendental phenomenological clarification of its aims and presuppositions. By showing how Husserl applies this method to the history of formal sciences down to mathematicians’ work in his time, the paper explains in detail the relationship between historical critical Besinnung and (...) transcendental phenomenology. Ultimately the paper suggests that radical Besinnung should be viewed as a general methodological framework within which transcendental phenomenological descriptions are used to criticize historically given goal-directed practices. (shrink)