Let M be an MV-algebra and ΩM be the set of all σ -valuations from M into the MV-unit interval. This paper focuses on the characterization of MV-algebras using σ -valuations of MV-algebras and proves that a σ -complete MV-algebra is σ -regular, which means that a ≤ b if and only if v ≤ v for any v ∈ ΩM. Then one can introduce in a natural way a fuzzy topology δ on ΩM. The representation theorem forMV-algebras is established (...) by means of fuzzy topology. Some properties of fuzzy topology δ and its cut topology U are investigated. (shrink)