This is the first of a pair of papers. It focuses on the development of the most notable phlogistic theories during the period 1766–1791, including the main experiments that their proponents proposed them to interpret. There was a rapid proliferation of late phlogistic theories, particularly from 1784, and the accounts of composition and important implications of the main theories are set out and their issues analysed. Each of them either reached impasses due to internal problems, or included features that made (...) them unacceptable even to other phlogistians. The expositions and analyses of these theories are given in terms of details that were in the literature at the time or otherwise potentially understandable by the participants given contemporary practice. Some relevant methodological aspects of the history of science are discussed, and the secondary literature is briefly surveyed. The second paper deals with the contemporary development of the new chemistry, and with theory comparison and theory choice in the same period. (shrink)

In this article, we provide a detailed discussion of Hasok Chang’s analysis of the Chemical Revolution. Our focus lies on his use of the framework of systems of practice and his claim that the abandonment of the phlogiston theory was irrational. We argue that his framework runs into problems when applied to the chemical revolution because of its static view on the aims of the historical actors and we suggest using Nicholas Jardine’s concept of the reality of questions instead as (...) a more flexible historiographical tool. We show how Chang’s claim regarding the irrational aspects of the chemical revolution follows from his strictly individualistic epistemology, leading him to see institutional and social aspects that impact the determination of aims as external to scientific rationality. We argue that a viable pragmatist and pluralist philosophy of science needs to embrace ‘academic politics’ as an explicit part of its view of rationality. (shrink)

Retail realists advocate abandoning wholesale arguments, which concern the reality of theoretical entities in general, and embracing retail arguments, which concern the reality of particular kinds of theoretical entities. They can thus be realists about some and anti-realists about others. But realism about a kind of entity can take different forms depending on how retail realists individuate kinds of entities. This chapter introduces the notion of the inclusiveness of individuation: the more inclusively we individuate a kind of entity, the more (...) theories there are in which it appears. The form of realism that retail realists accept regarding a particular kind of entity can be more selective or more encompassing depending on how inclusively they individuate that kind of entity. This chapter illustrates these ideas in terms of a case from the history of chemistry involving the hypothetical component of hydrochloric acid known as the muriatic radical. (shrink)