Based on the property of extensivity , we derive in a mathematically consistent manner the explicit expressions of the chemical potential μμ and the Clausius entropy S for the case of monoatomic ideal gases in open systems within phenomenological thermodynamics. Neither information theoretic nor quantum mechanical statistical concepts are invoked in this derivation. Considering a specific expression of the constant term of S, the derived entropy coincides with the Sackur–Tetrode entropy in the thermodynamic limit. We demonstrate, however, that the former (...) limit is not contained in the classical thermodynamic relations, implying that the usual resolutions of Gibbs paradox do not succeed in bridging the gap between the thermodynamics and statistical mechanics. We finally consider the volume of the phase space as an entropic measure, albeit, without invoking the thermodynamic limit to investigate its relation to the thermodynamic equation of state and observables. (shrink)

I discuss the statistical mechanics of gravitating systems and in particular its cosmological implications, and argue that many conventional views on this subject in the foundations of statistical mechanics embody significant confusion; I attempt to provide a clearer and more accurate account. In particular, I observe that (i) the role of gravity in entropy calculations must be distinguished from the entropy of gravity, that (ii) although gravitational collapse is entropy-increasing, this is not usually because the collapsing matter itself increases in (...) entropy, and that (iii) the Second Law of thermodynamics does not owe its validity to the statistical mechanics of gravitational collapse. (shrink)

I summarize, in this informal interview, the main approaches to the ‘Past Hypothesis’, the postulation of a low-entropy initial state of the universe. I’ve chosen this as an open problem in the philosophical foundations of physics. I hope that this brief overview helps readers in gaining perspective and in appreciating the diverse range of approaches in this fascinating unresolved debate.

Black hole thermodynamics is regarded as one of the deepest clues we have to a quantum theory of gravity. It motivates scores of proposals in the field, from the thought that the world is a hologram to calculations in string theory. The rationale for BHT playing this important role, and for much of BHT itself, originates in the analogy between black hole behavior and ordinary thermodynamic systems. Claiming the relationship is “more than a formal analogy,” black holes are said to (...) be governed by deep thermodynamic principles: what causes your tea to come to room temperature is said additionally to cause the area of black holes to increase. Playing the role of philosophical gadfly, we pour a little cold water on the claim that BHT is more than a formal analogy. First, we show that BHT is often based on a kind of caricature of thermodynamics. Second, we point out an important ambiguity in what systems the analogy is supposed to govern, local or global ones. Finally, and perhaps worst, we point out that one of the primary motivations for the theory arises from a terribly controversial understanding of entropy. BHT may be a useful guide to future physics. Only time will tell. But the analogy is not nearly as good as is commonly supposed. (shrink)

I discuss the formal implementation, interpretation, and justification of likelihood attributions in cosmology. I show that likelihood arguments in cosmology suffer from significant conceptual and formal problems that undermine their applicability in this context.

I discuss how modern cosmology illustrates underdetermination of theoretical hypotheses by data, in ways that are different from most philosophical discussions. I confine the discussion to the history of the observable universe from about one second after the Big Bang, as described by the mainstream cosmological model: in effect, what cosmologists in the early 1970s dubbed the ‘standard model’, as elaborated since then. Or rather, the discussion is confined to a (very!) few aspects of that history. I emphasize that despite (...) the underdetermination, a scientific realist can, and should, endorse this description. (shrink)

Based on the property of extensivity, we derive in a mathematically consistent manner the explicit expressions of the chemical potential and the Clausius entropy $S$ for the case of monoatomic ideal gases in open systems within phenomenological thermodynamics. Neither information theoretic nor quantum mechanical statistical concepts are invoked in this derivation. Considering a specific expression of the constant term of $S$, the derived entropy coincides with the Sackur-Tetrode entropy in the thermodynamic limit. We demonstrate however, that the former limit is (...) not contained in the classical thermodynamic relations, implying that the usual resolutions of Gibbs paradox do not succeed in bridging the gap between the thermodynamics and statistical mechanics. We finally consider the volume of the phase space as an entropic measure, albeit, without invoking the thermodynamic limit to investigate its relation to the thermodynamic equation of state and observables. (shrink)

Phase transitions are an important instance of putatively emergent behavior. Unlike many things claimed emergent by philosophers, the alleged emergence of phase transitions stems from both philosophical and scientific arguments. Here we focus on the case for emergence built from physics, in particular, arguments based upon the infinite idealization invoked in the statistical mechanical treatment of phase transitions. After teasing apart several challenges, we defend the idea that phase transitions are best thought of as conceptually novel, but not ontologically or (...) explanatorily irreducible to finite physics; indeed, by looking at ongoing work on “smooth phase transitions” we even suggest that they’re not even conceptually novel. In the case of renormalization group theory, consideration of infinite systems and their singular behavior provides a central theoretical tool, but this is compatible with an explanatory reduction. Phase transitions may be “emergent” in some sense of this protean term, but not in a sense that is incompatible with the reductionist project broadly construed. (shrink)

Thermodynamics is the science that describes much of the time asymmetric behavior found in the world. This entry's first task, consequently, is to show how thermodynamics treats temporally ‘directed’ behavior. It then concentrates on the following two questions. (1) What is the origin of the thermodynamic asymmetry in time? In a world possibly governed by time symmetric laws, how should we understand the time asymmetric laws of thermodynamics? (2) Does the thermodynamic time asymmetry explain the other temporal asymmetries? Does it (...) account, for instance, for the fact that we know more about the past than the future? The discussion thus divides between thermodynamics being an explanandum or explanans. In the former case the answer will be found in philosophy of physics; in the latter case it will be found in metaphysics, epistemology, and other fields, though in each case there will be blurring between the disciplines. (shrink)

I give a fairly systematic and thorough presentation of the case for regarding black holes as thermodynamic systems in the fullest sense, aimed at students and non-specialists and not presuming advanced knowledge of quantum gravity. I pay particular attention to the availability in classical black hole thermodynamics of a well-defined notion of adiabatic intervention; the power of the membrane paradigm to make black hole thermodynamics precise and to extend it to local-equilibrium contexts; the central role of Hawking radiation in permitting (...) black holes to be in thermal contact with one another; the wide range of routes by which Hawking radiation can be derived and its back-reaction on the black hole calculated; the interpretation of Hawking radiation close to the black hole as a gravitationally bound thermal atmosphere. In an appendix I discuss recent criticisms of black hole thermodynamics by Dougherty and Callender. This paper confines its attention to the thermodynamics of black holes; a sequel will consider their statistical mechanics. (shrink)

The perturbative approach to quantum field theory has long been viewed with suspicion by philosophers of science. This article offers a diagnosis of its conceptual problems. Drawing on Norton’s discussion of the notion of approximation I argue that perturbative QFT ought to be understood as producing approximations without specifying an underlying QFT model. This analysis leads to a reassessment of common worries about perturbative QFT. What ends up being the key issue with the approach on this picture is not mathematical (...) rigour, or the threat of inconsistency, but the need for a physical explanation of its empirical success. 1Three Worries about Perturbative Quantum Field Theory2The Perturbative Formalism 2.1Expanding the S-matrix2.2Perturbative renormalization3Approximations and Models4Perturbative Quantum Field Theory Produces Approximations5The Real Problem. (shrink)

Foundational puzzles surround gravitational thermal physics—a realm in which stars are treated as akin to molecules in a gas. Whether such an enterprise is successful and the domain of thermal physics extends beyond our terrestrial sphere is disputed. There are successes and paradoxical features. Callender :960–981, 2011) advocates reconciling the two sides of the dispute by taking a broader view of thermodynamics. Here I argue for an alternative position: if we are careful in distinguishing statistical mechanics and thermodynamics, then no (...) reconciliation is required. Both sides can live in harmony because whilst statistical mechanics applies, thermodynamics does not. This state of affairs—the applicability of statistical mechanics without the emergence of thermodynamic behaviour—can be explained in terms of an infamous infinite idealisation: the thermodynamic limit. (shrink)