The problem of the irreversibility's origin in thermodynamic processes occupies a distinguished place among many and lasting attempts by researchers to derive irreversibility from molecular-mechanical principles. However, this problem is still open and no universally accepted solution may be given during any course. In this paper, I shall try to show that the examining of Maxwell's demon thought experiment may provide insight into the difficulties that emerge, looking for this origin because: it is connected with the notion of irreversibility, and (...) one of its functions is that of the "reversibility objection." In order to illustrate this point, I study Boltzmann's approach to the problem of a molecular-mechanical interpretation of irreversibility and I show that an auxiliary assumption is responsible for producing irreversibility. But this result is accordant with the predictions of Maxwell's demon thought experiment: the assumptions of this kind are not dictated by molecular-mechanical principles but are separate input in the model-systems used. (shrink)

It is usually claimed that in order to assess a thought experiment we should assess the nomological possibility, or realizability in principle, of its scenario. This is undoubtedly true for many TEs, such as Bohr’s reply to Einstein’s photon box. Nevertheless, in some cases, such as Maxwell’s demon, this requirement should be relaxed. Many accounts of TEs fail in this regard. In particular, experimental and some mental model accounts are too strict, since they always require realizability in principle. This paper (...) aims at analysing the notion of possibility at play in the scenarios of scientific TEs, and sheds some new light on their nature and function. (shrink)

demon thought experiment remains ambiguous even today. One of the most delightful thought It seems that Maxwell originally invoked experiments in the history of physical science is..