Relations between J. A. C. Chaptal, pioneer of heavy chemical industry in France, and A. L. Lavoisier, reformer of chemical theory, are examined in the light of unpublished correspondence they exchanged in the period 1784–1790. The letters, together with Chaptal's early publications, allow a reconstruction of his conversion to Lavoisier's antiphlogistic chemistry. They also reveal a series of petitions that Chaptal made to Lavoisier, in the latter's official capacity as a director of the Régie des poudres et salpêtres, for relief (...) from the controlled price of saltpetre for his acid works in Languedoc. Finally, the relationship is explored as a window on the interplay between chemical theory and industrial practice during the period of the Industrial Revolution. (shrink)

In Éléments de l'art de la teinture, Claude-Louis Berthollet organized and described knowledge of a chemical craft in terms of contemporary chemical science. The resulting intellectual structure of his treatise established a programme and method for the subsequent improvement of dyeing. Berthollet's descriptive and hierarchical systematization of knowledge rendered problems intelligible and isolated them so that they could be attacked and solved by methodical experimentation. This double-edged processes of solving practical problems, first cognitively and then experimentally, provides a key to (...) understanding the way science has contributed to rapid and systematic technological change. (shrink)

Jean Antoine Claude Chaptal was not only a chemical manufacturer and one of the first ‘industrial scientists’ but was also, according to his own testimony, one of the early supporters of Lavoisier's system of chemistry. It might be assumed that Chaptal's pioneering work in industrial chemistry was intimately linked with his acceptance of the oxygen system of chemistry; more specifically, that this theory served to direct and inform his applied research and contributed not a little to its success. Indeed, he (...) himself in 1790 explicitly stated this to have been the case. A close study of his work prior to 1790 fails, however, to establish the importance of such a linkage. First, his selection of research topics proves to have owed little to the ‘new chemistry’ but much to the scientific and economic milieu of his province of Languedoc and of Montpellier, its administrative seat. Second, the significance of his acceptance of the ‘new chemistry’ appears rather problematic, not the least because of the rather hazy boundaries between the phlogistic and Lavoisian theories in the 1780s. Third, it is not clear from the evidence available how the new theory helped solve the various problems of industrial chemistry he faced, or could have done so, other than to offer alternative explanations for processes with which he was already familiar and indeed had often mastered. It will be suggested that it is precisely this less dramatic role which was filled by the new chemistry: that of ‘rectifying’ his ideas by providing alternative and more satisfactory rationalizations of his experiences and experiments in the laboratory and the factory, not that of enabling him to simplify and perfect old processes nor to invent new ones. To put the point more bluntly: Chaptal's early successes and reputation in industrial chemistry were not a by-product of his allegiance to the new chemistry; rather, his growing adherence to that system was a by-product of its ability to provide satisfactory post-hoc explanations of the chemical processes and products with which he was concerned. (shrink)

Summary Kant's critique of corpuscular theory created a tabula rasa situation in natural philosophy and opened up a vast new field of research, particularly related to the study of heat, light, electricity and magnetism. ?rsted introduced Kantian epistemology in Scandinavia and made friends with J. W. Ritter, an outstanding experimenter who was the first to make dynamical philosophy productive. The ?rsted?Ritter partnership aimed at the construction of a cosmology based on dynamical philosophy as well as galvanic interpretations of the Lichtenberg (...) and Chladni patterns. It is suggested that Kantian critique and dynamical cosmology provided the framework within which ?rsted and Ritter made their epochal discoveries as well as their bold speculations. Finally, it is argued that the Romantics widened the scope of natural philosophy itself. (shrink)

(1983). Hydrogen production for ballooning during the French Revolution: An early example of chemical process development. Annals of Science: Vol. 40, No. 6, pp. 531-558.