This is a textbook on quantum mechanics. It is addressed to graduates and advanced undergraduates. The book presents quantum theory as a logically coherent system, placing stronger emphasis on the theory' s probabilistic structure and on the role of symmetries. It makes students aware of foundational problems from the very beginning, but at the same time, it urges them to adopt a pragmatic attitude towards the quantum formalism. The book consists of five parts. Part I is a review of classical (...) physics, including probability theory, and a historical introduction to quantum theory. Part II presents quantum theory in terms of six fundamental principles. The principles are presented together with the necessary mathematical background and with applications to simple systems. Part III analyses the properties of quantum particles. It starts with the description of symmetries, continues to non-relativistic particles, the introduction of spin, and particle statistics. It concludes with a symmetries-based introduction to relativistic quantum systems and with the first steps towards relativistic quantum field theory. Part IV presents techniques adapted to specific problems: the structure and spectra of composite systems, decays and transitions, particle scattering, and open quantum systems. Finally, Part V revisits quantum foundations: quantum measurement theory, the major interpretations of quantum theory, and the frontiers of quantum theory in contemporary research. (shrink)

In this article I examine several related views expressed by Robin Hendry concerning molecular structure, emergence and chemical bonding. There is a long-standing problem in the philosophy of chemistry arising from the fact that molecular structure cannot be strictly derived from quantum mechanics. Two or more compounds which share a molecular formula, but which differ with respect to their structures, have identical Hamiltonian operators within the quantum mechanical formalism. As a consequence, the properties of all such isomers yield precisely the (...) same calculated quantities such as their energies, dipole moments etc. The only means through which the difference between the isomers can be recovered is to build their structures into the quantum mechanical calculations, something that is carried out by the application of the Born-Oppenheimer approximation. Consequently, it has been argued by many authors that molecular structure is written in ‘by hand’ rather than derived. Robin Hendry is one such author, but he goes a great deal further by proposing that this situation implies the existence of emergence and downward causation. In the current article I argue that there are alternative explanations which render emergence and downward causation redundant. Such an alternative lies in the notion of quantum decoherence and the appeal to work in the foundations of physics, which posits that the various isomers exist as a superposition until their wavefunctions are collapsed either by observation or by interacting with their environment. Hendry also alludes to a debate among chemists as to whether chemical bonds are real or not, in the sense of directional connections between two or more nuclei in any given molecule. I reject this view and propose that the structural and energetic views of chemical bonding, that have been discussed by some philosophers of chemistry including Hendry, do not refer to any essential ontological differences. I agree that chemists view bonding in a more realistic fashion and may consider bonds to be in some senses real, while physicists may consider bonding in more abstract energetic terms. However, I do not believe that such differences in scientific practice and attitudes should be considered to offer a window as to the ontological status of bonding or whether bonding is real. Finally, I discuss the kinetic energy school of chemical bonding which would seem to challenge any notion of bonds as directional entities, since bonding is no longer regarded as being primarily due to the build-up of electron density between nuclei. (shrink)