This paper studies the notion of virtuality in the Bohr-Kramers-Slater theory of 1924. We situate the virtual entities of BKS within the tradition of the correspondence principle and the radiation theory of the Bohr model. We show how, in this context, virtual oscillators emerged as classical substitute radiators and were used to describe the otherwise elusive quantum transitions. They played an effective role in the quantum theory of radiation while remaining categorically distinct and ontologically separated from the quantum world of (...) the Bohr model. The notion of virtuality thus differs markedly from its counterpart in quantum mechanics or QFT. (shrink)

The specific heat of hydrogen gas at low temperatures was first measured in 1912 by Arnold Eucken in Walther Nernst’s laboratory in Berlin, and provided one of the earliest experimental supports for the new quantum theory. Even earlier, Nernst had developed a quantum theory of rotating diatomic gas molecules that figured in the discussions at the first Solvay conference in late 1911. Between 1913 and 1925, Albert Einstein, Paul Ehrenfest, Max Planck, Fritz Reiche, and Erwin Schrödinger, among many others, attempted (...) theoretical descriptions of the rotational specific heat of hydrogen, with only limited success. Quantum theory also was central to the study of molecular spectra, where initially it was more successful. Moreover, the two problems interacted in sometimes surprising ways. Not until 1927, following Werner Heisenberg’s discovery of the behavior of indistinguishable particles in modern quantum mechanics, did American theorist David Dennison find a successful theory of the specific heat of hydrogen. (shrink)

Once one of the main protagonists of history of science, the historiography on quantum theory has recently gone through a process of reconfiguration of methods, research questions and epistemological framework. In this paper, I review the recent developments and propose some reflections on its future evolution.

This paper re-evaluates the formative year of quantum mechanics—from Heisenberg’s first paper on matrix mechanics to Schrödinger’s equivalence proof—by focusing on the role of radiation in the emerging theory. We argue that the radiation problem played a key role in early quantum mechanics, a role that has not been taken into account in the standard histories. Radiation was perceived by the main protagonists of matrix and wave mechanics as a central lacuna in these emerging theories and continued to contribute to (...) the theoretical development and conceptual clarification of quantum mechanics. Studying the interplay between quantum mechanics and radiation, the paper provides an account of (a) how quantum mechanics was able to connect to its empirical basis in spectroscopy and (b) how Schrödinger’s equivalence proof emerged from his explorative calculations on the emission of radiation. (shrink)