The specific heat of hydrogen gas at low temperatures was first measured in 1912 by Arnold Eucken in Walther Nernst’s laboratory in Berlin, and provided one of the earliest experimental supports for the new quantum theory. Even earlier, Nernst had developed a quantum theory of rotating diatomic gas molecules that figured in the discussions at the first Solvay conference in late 1911. Between 1913 and 1925, Albert Einstein, Paul Ehrenfest, Max Planck, Fritz Reiche, and Erwin Schrödinger, among many others, attempted (...) theoretical descriptions of the rotational specific heat of hydrogen, with only limited success. Quantum theory also was central to the study of molecular spectra, where initially it was more successful. Moreover, the two problems interacted in sometimes surprising ways. Not until 1927, following Werner Heisenberg’s discovery of the behavior of indistinguishable particles in modern quantum mechanics, did American theorist David Dennison find a successful theory of the specific heat of hydrogen. (shrink)

When, how, and by whom scientific knowledge is recognized with highest honors is illustrated by this avowedly atypical episode involving the Nobel Prize awarded to Walther Nernst for 1920. Mine is not a postmortem “wie es eigentlich gewesen” evaluation of the cognitive legitimation of his 1905 third law of thermodynamics, of whether the debates surrounding his work were justified, or whether the prize was merited. Rather, it is an admittedly close reading of many new and some old sources, an intrusive (...) scrutiny of human imperfection and an excursion into the cultural symbolism of the Nobel Prize, the twentieth century’s emblematic arbiter in matters scientific. (shrink)

In this article, I consider some of the first appearances of a hypothesis of quantized energy between the years 1900 and 1913 and provide an analysis of the nature of the unificatory power of this hypothesis in a Bayesian framework. I argue that the best way to understand the unification here is in terms of informational relevance: on the assumption of the quantum hypothesis, phenomena that were previously thought to be unrelated turned out to yield information about one another on (...) the basis of agreeing measurements of the numerical value of Planck’s constant. (shrink)

In this article, I evaluate Hartmann and Fitelson’s solution to the Bayesian problem of old evidence by applying it to an early stage in the development of quantum theory. I argue that this case study suggests that whether old evidence is anomalous affects its support for a hypothesis. I introduce and defend two formal assumptions to accommodate this idea. This analysis not only explicates an important historical example, but it also shows that the given solution captures the intuitive importance of (...) “surprising” evidence that has previously been problematic in the context of old evidence. (shrink)

The purpose of this dissertation is to contribute to our understanding of scientific theory pursuit by providing a detailed case study on the development of early quantum theory, from roughly 1900 to 1916. I first elaborate on why this case should be considered an instance of piecemeal pursuit by presenting the historical quantum conjectures that were being used in different contexts. These conjectures gave varied interpretations of quantization. By comparing these conjectures, I identify a general quantum postulate that captures the (...) underlying assumption common to all the cases. I argue that it is possible to consider a general postulate about quantization even when its proper application is ambiguous in a given context, and that the postulate can be separated from different elements of the framework being used to investigate it. I show that the quantum postulate can be deemed promising by analysing the support it gains using a Bayesian framework. I first defend the use of such a framework by considering the purported inconsistencies in Planck's introduction of his quantum conjecture and how we should handle these. I then explicate two cases of support for the postulate. First, I show how we can use a particular solution to the Bayesian problem of old evidence to interpret the support the quantum postulate received by accounting for phenomena that had no previous explanation. Finally, I show that the quantum postulate is also supported by a unification argument, where unification is interpreted as informational relevance between the different domains of inquiry. (shrink)

Once one of the main protagonists of history of science, the historiography on quantum theory has recently gone through a process of reconfiguration of methods, research questions and epistemological framework. In this paper, I review the recent developments and propose some reflections on its future evolution.