During large parts of its history chemistry was seen as a science of progress, admired by many. But contemporary public debates on chemistry have been quite critical, mainly for environmental reasons. Therefore is it interesting to note that in the course of the 1990s “green chemistry” emerged. The origins, scientific meaning and drivers behind the spectacular growth of that new field are the subject of Research between Science, Society and Politics: The History and Scientific Development of Green Chemistry. The scientific (...) character of green chemistry has been a matter of dispute since its inception. This book aims to clarify that dispute. It presents a historical analysis of its birth and evolution, with a special focus on the USA, the UK and the Netherlands and the chemical societies in these countries. The emergence of green chemistry differed from one country to another, which is analyzed and compared as well. Based on quantitative and qualitive research methods and a wide range of primary sources never studied before, this book ultimately offers a new characterization of “green chemistry”. It should be of interest to chemists, policy makers and historians & philosophers of chemistry, because Research between Science, Society and Politics accounts for both internal scientific as well as socio-cultural factors that played a role during the emergence and growth of green chemistry. (shrink)

The concept of green chemistry dominated the imagination of environmentally-minded chemists over the last thirty years. The conceptual frameworks laid by the American Environmental Protection Agency scholars in the 1990s constitute today the core of a line of thinking aimed at transforming chemistry into a sustainable science. And yet, in the shadow of green chemistry, a broader, even if less popular, concept of sustainable chemistry started taking shape. Initially, it was either loosely associated with green chemistry or left undefined as (...) a distinct but generaly different approach. In such a vague form, it was endorsed by the organizations such as OECD and the IUPAC in the late 1990s. It was not until the 2010s however, when it solidified as a separate more embracing and more overarching tradition that could compete with green chemistry by offering insights that the latter lacked. Sustainable chemistry seeks to transcend the narrow focus on chemical synthesis and embrace a much more holistic view of chemical activities including social responsibility and sustainable business models. Due to an interesting historical coincidence, it was in Germany where sustainable chemistry took roots and became institutionalized for the first time. It was thanks to German exceptionalism and the unwillingness of German scholars to embrace the “green” terminology originating from the US, the concept of sustainable chemistry could safely mature and develop in the German-speaking world, before reaching a high degree of formalization with dedicated journals, founding articles, and programmatic principles aspiring to transform the entire chemical enterprise in the years to come. (shrink)

The objective of the present review on the evolution of Green Chemistry, since its emergence until 2016, aimed an integrated vision of its progress along the three phases of its development: emergence, divulgation and consolidation. The methodology involved the analysis of a selection of bibliography on the evolution of GC collected from issues of the ACS symposia series; editorials in specialized GC journals; and commemorative birthday papers/editorials of these journals and of the GC itself. The analysis allowed to identify and (...) discuss the characteristics and conceptions of GC agents about fundamental concepts and procedures, in order to visualize and better understand the state of knowledge and the subject areas that make up the field. The main alterations identified in the evolution of GC were: it acquired a better defined identity, with more participation of academy and increased scope; was progressively framed in sustainability; has been aspiring to a holistic frame and to a change on the nature of the innovation for its implementation, from incremental to transformative. The analysis suggests that for supporting expansion and consolidation of GC the following aspects deserve attention: full validation of chemical greenness by metrics; better characterization of the frontiers of GC research areas/themes; increased integration between academy and industry; and penetration in chemistry curricula. Its basic philosophy being the practice of a chemistry more focused on the environment preservation, GC means a new stage in nature and in the history of Chemistry. (shrink)

The modern world can be described as a globalized risk society. It is characterized by increasing complexity, unpredictable consequences of techno-scientific innovations and production, and its environmental consequences. Therefore, chemistry, just like many other knowledge areas, is in an ongoing process of environmentalization. For example, green chemistry has emerged as a new chemical metadiscipline and movement. The philosophy of green chemistry was originally based on a suggestion of twelve principles for environment-friendly chemistry research and production. The present article problematizes limitations (...) in green chemistry when it comes to education. It argues that the philosophy of green chemistry in the context of education needs to be extended with socio-critical perspectives to form educated professionals and citizens who are able to understand the complexity of the world, to make value-based decisions, and to become able to engage more thoroughly in democratic decision-making on sustainability issues. Different versions of sustainability-oriented science/chemistry education are discussed to sharpen a focus on the most complex type, which is Bildung-oriented, focusing emancipation and leading to eco-reflexive education. The term eco-reflexive is used for a problematizing stance towards the modern risk society, an understanding of the complexity of life and society and their interactions, and a responsibility for individual and collective actions towards socio-ecojustice and global sustainability. The philosophical foundation and characteristics of eco-reflexive science education are sketched on in the article. (shrink)

Conventional wisdom and many published histories of “Green Chemistry” describe its start as being a result of governmental and/or regulatory actions at the US Environmental Protection Agency during the early 1990’s. But there were many Real World industrial examples of environmentally friendly commercial processes in the oil and commodity chemicals industries for decades prior to the 1990s. Some early examples of commercial “Green Chemistry” are briefly described in this article. The Boots/Hoechst Celanese Ibuprofen process was one of the earliest multiple-award-winning (...) examples of industrial “Green Chemistry” in the fine chemical/pharmaceutical industry. The author, who conceived the BHC Ibuprofen synthetic strategy in 1984, reveals and documents that the BHC Ibuprofen process was not primarily a result of governmental or regulatory mandates, or environmentalist or political motivations. The BHC ibuprofen process, and probably many other early industrial “green” inventions, evolved from, and their development and commercialization motivated and guided by, a long prior industrial culture of both scientific and technical evolution. The invention and commercialization of these early industrial commercialized processes, and the BHC Ibuprofen process were also guided by both competitive and economic market needs, personal human motivations, and a low waste culture of “Quality” and “Continuous Improvement” that the commodity chemical industry internally promoted in the 1980’s. The author comments on some perceptions of the status of Green Chemistry now, and directions it should consider going in the future. The author recommends that young Green Chemists and/or Green Engineers reconsider “Quality” approaches in order to genuinely lead Society toward a Greener future. (shrink)

The article examines and extends work bringing together engineering ethics and Science and Technology Studies, which had built upon Diane Vaughan’s analysis of the Challenger shuttle accident as a test case. Reconsidering the use of her term “normalization of deviance,” the article argues for a middle path between moralizing against and excusing away engineering practices contributing to engineering disaster. To explore an illustrative pedagogical case and to suggest avenues for constructive research developing this middle path, it examines the emergence of (...) green chemistry and green engineering. Green chemistry began when Paul Anastas and John Warner developed a set of new rules for chemical synthesis that sought to learn from missed opportunities to avoid environmental damage in the twentieth century, an approach that was soon extended to engineering as well. Examination of tacit assumptions about historical counterfactuals in recent, interdisciplinary discussions of green chemistry illuminate competing views about the field’s prospects. An integrated perspective is sought, addressing how both technical practice within chemistry and engineering and the influence of a wider “social movement” can play a role in remedying environmental problems. (shrink)

A new chronology is introduced to address the history of chemistry, with educational purposes, particularly for the end of the twentieth century and here identified as the fifth chemical revolution. Each revolution are considered in terms of the Kuhnian notion of ‘exemplar,’ rather than ‘paradigm.’ This approach enables the incorporation of instruments, as well as concepts and the rise of new subdisciplines into the revolutionary process and provides a more adequate representation of such periods of development and consolidation. The fifth (...) revolution developed from 1973 to 1999 and is characterized by a deep transformation in the very heart of chemistry. That is to say, the size and type of objects, the way in which they must be done and the time in which they are transformed. In one way or another, chemistry’ limits had been set out. (shrink)

This study discusses the relationship between Green Chemistry and Environmental Sustainability as expressed in textbooks and articles on Green Chemistry authored by their promoters. It was found that although the Brundtland concept of Sustainable Development/Sustainability has been mentioned often by green chemists, a full analysis of that relationship was almost never attempted. In particular, green chemists have paid scarce attention to the importance of The Second Law of thermodynamics on Environmental Sustainability and the consequences of the limitations it imposes on (...) Green Chemistry, which are discussed in this paper. (shrink)