This paper discusses the proposal made by Lombardi and Labarca (Found Chem 7:125–148, 2005) that internal realism can secure the ontological autonomy of chemistry. I argue that internal realism is not, by itself, sufficient to accomplish this task. The fact that conceptual schemes may differ with respect to their theoretical virtues, and the possibility that the relations between them may be reductive undermine the premise that each conceptual scheme has an equal right to define its own ontology, which is a (...) key premise in Lombardi and Labarca’s proposal. (shrink)

The analysis of the concept of orbital allows us to argue that—in opposition to a recent position in philosophy of science—it is impossible to defend the autonomy of the chemical reality in regard to physical reality, appealing to the idea that there is a conceptual rupture among a chemical interpretation and a quantuminterpretation of the concept. This is the case because there are not two different interpretations of the concept of orbital. On the contrary, the concept involved in structural chemistry (...) and in quantum chemistry comes from quantum mechanics.El análisis del concepto de orbital permite argumentar—en oposición a una propuesta reciente en filosofía de la química—que no es posible defender la autonomía ontológica de la realidad química respecto de la física, sobre la base de una ruptura conceptual entre una interpretación química del concepto y otra propia de la mecánica cuántica. Esto es así porque no existen tales interpretaciones distintas del concepto de orbital, sino que, por el contrario, este concepto en química cuántica y en química estructural proviene de la mecánica cuántica. (shrink)

All suggested notions of reduction of two scientific theories are critically reviewed and analyzed. In particular those applied to the case of the alleged reduction of Chemistry to Quantum mechanics are examined. Since it is recognized that the weakness of this field of research is the lack of a definition of a scientific theory, it is suggested that a scientific theory is characterized by two choices regarding two dichotomies, that is, the kind of mathematics and the kind of logic. According (...) to this view a reduction is only possible between two theories in which the same choices are shared. As a consequence, only one case of reduction in the history of physics is recognized: physical optics to electromagnetism, a case that is commonly accepted. The other cases of claimed reductions are recognized as impossible, owing to the different choices of the two theories at issue and hence the radical variations in meaning of their shared basic notions. In particular, the claimed reduction of Chemistry to Quantum mechanics is disproved in detail. (shrink)

En el presente trabajo se evalúa críticamente el pluralismo ideológico de Hasok Chang, una concepción epistemológica considerada muy significativa en la filosofía actual de la ciencia, que afirma que la ciencia progresa, al propio tiempo que deja de lado la noción de verdad y rechaza todo compromiso ontológico. Se argumentará que el abandono de la idea de verdad y la abstención respecto de la ontología resultan problemáticos. Su posición filosófica sobre la ciencia podría resultar más robusta si se revisaran estos (...) aspectos. A fin de argumentar en este sentido, se establecerá un diálogo entre la posición del autor y otras posiciones pluralistas. (shrink)

This paper aims to show that there is a lot of philosophy in the philosophy of chemistry—not only in the problems and questions specific to chemistry, which this science brings up in philosophical discussions, but also in the topics of wider interest like reductionism and emergence, for which chemistry proves to be an ideal case study. The fact that chemical entities and properties are amenable to a quantitative understanding, to measurement and experiment to a greater extent than those in psychology (...) or biology, makes chemistry an ideal case study for those interested in reductionism and emergence. (shrink)

The many-faced relationship between chemistry and physics is one of the most discussed topics in the philosophy of chemistry. In his recent book Reducing Chemistry to Physics. Limits, Models, Consequences, Hinne Hettema conceives this relationship as a reduction link, and devotes his work to defend this position on the basis of a “naturalized” concept of reduction. In the present paper I critically review three kinds of issues stemming from Hettema’s argumentation: philosophical, scientific and methodological.

The autonomy of chemistry and the legitimacy of the philosophy of chemistry are usually discussed in the context of the issue of reduction of chemistry to physics, and defended making use of the failure of reductionistic claims. Until quite recent times a rather widespread viewpoint was, however, that the failure of reductionistic claims concerns actually epistemological aspect of reduction only, but the ontological reduction of chemistry to physics cannot be denied. The new problems of the autonomy of chemistry in the (...) context of reductionism seem to be ontological and metaphysical. In the present paper it is argued that there is no need for some kind of metaphysical-ontological underpinning for rejection of the secondary positions of chemistry and philosophy of chemistry with respect to physics and philosophy of physics. The issue can be elucidated in terms of the philosophy of science accepting practical realism (also known by other names). (shrink)

The aim of the present paper is to analyze the problem of the relationship between chemistry and physics, by focusing on the widely discussed case of the atomic orbitals. We will begin by remembering the difference between the physical and the chemical interpretation of the concept of orbital. Then, we will refer to the claim made in 1999 that atomic orbitals have been directly imaged for the first time. On this basis, we will analyze the problem from a new approach, (...) by comparing the concept of orbital used in physics with the concept of orbital used in chemistry. Such an analysis will allow us to argue for an ontological pluralism that admits the coexistence of different ontologies without priorities or metaphysical privileges. From this philosophical framework, the concepts of chemical orbital and physical orbital correspond to two different ontologies. As a consequence, chemical orbitals are real entities belonging to the ontology of molecular chemistry, and can be observed like any other entity not belonging to the quantum mechanical ontology. DOI:10.5007/1808-1711.2010v14n3p309. (shrink)