The search for the statistical mechanical underpinning of thermodynamic irreversibility has so far focussed on the spontaneous approach to equilibrium. But this is the search for the underpinning of what Brown and Uffink have dubbed the ‘minus first law’ of thermodynamics. In contrast, the second law tells us that certain interventions on equilibrium states render the initial state ‘irrecoverable’. In this article, I discuss the unusual nature of processes in thermodynamics, and the type of irreversibility that the second law embodies. (...) I then search for the microscopic underpinning or statistical mechanical ‘reductive basis’ of the second law of thermodynamics by taking a functionalist strategy. First, I outline the functional role of the thermodynamic entropy: for a thermally isolated system, the thermodynamic entropy is constant in quasi-static processes, but increasing in non-quasi-static processes. I then search for the statistical mechanical quantity that plays this role—rather than the role of the traditional ‘holy grail’ as described by Callender. I argue that in statistical mechanics, the Gibbs entropy plays this role. (shrink)

While the fundamental laws of physics are time-reversal invariant, most macroscopic processes are irreversible. Given that the fundamental laws are taken to underpin all other processes, how can the fundamental time-symmetry be reconciled with the asymmetry manifest elsewhere? In statistical mechanics, progress can be made with this question. What I dub the ‘Zwanzig–Zeh–Wallace framework’ can be used to construct the irreversible equations of SM from the underlying microdynamics. Yet this framework uses coarse-graining, a procedure that has faced much criticism. I (...) focus on two objections in the literature: claims that coarse-graining makes time-asymmetry ‘illusory’ and ‘anthropocentric’. I argue that these objections arise from an unsatisfactory justification of coarse-graining prevalent in the literature, rather than from coarse-graining itself. This justification relies on the idea of measurement imprecision. By considering the role that abstraction and autonomy play, I provide an alternative justification and offer replies to the illusory and anthropocentric objections. Finally, I consider the broader consequences of this alternative justification: the connection to debates about inter-theoretic reduction and the implication that the time-asymmetry in SM is weakly emergent. 1Introduction 1.1Prospectus2The Zwanzig–Zeh–Wallace Framework3Why Does This Method Work? 3.1The special conditions account3.2When is a density forwards-compatible?4Anthropocentrism and Illusion: Two Objections 4.1The two objections in more detail4.2Against the justification by measurement imprecision5An Alternative Justification 5.1Abstraction and autonomy5.2An illustration: the Game of Life6Reply to Illusory7Reply to Anthropocentric8The Wider Landscape: Concluding Remarks 8.1Inter-theoretic relations8.2The nature of irreversibility. (shrink)

Standard quantum mechanics unquestionably violates the separability principle that classical physics (be it point-like analytic, statistical, or field-theoretic) accustomed us to consider as valid. In this paper, quantum nonseparability is viewed as a consequence of the Hilbert-space quantum mechanical formalism, avoiding thus any direct recourse to the ramifications of Kochen-Specker’s argument or Bell’s inequality. Depending on the mode of assignment of states to physical systems – unit state vectors versus non-idempotent density operators – we distinguish between strong/relational and weak/deconstructional forms (...) of quantum nonseparability. The origin of the latter is traced down and discussed at length, whereas its relation to the all important concept of potentiality in forming a coherent picture of the puzzling entangled interconnections among spatially separated systems is also considered. Finally, certain philosophical consequences of quantum non-separability concerning the nature of quantum objects, the question of realism in quantum mechanics, and possible limitations in revealing the actual character of physical reality in its entirety are explored. (shrink)

Explaining the emergence of stochastic irreversible macroscopic dynamics from time-reversible deterministic microscopic dynamics is one of the key problems in philosophy of physics. The Mori-Zwanzig projection operator formalism, which is one of the most important methods of modern nonequilibrium statistical mechanics, allows for a systematic derivation of irreversible transport equations from reversible microdynamics and thus provides a useful framework for understanding this issue. However, discussions of the MZ formalism in philosophy of physics tend to focus on simple variants rather than (...) on the more sophisticated ones used in modern physical research. In this work, I will close this gap by studying the problems of probability and irreversibility using the example of Grabert’s time-dependent projection operator formalism. This allows to better understand how general proposals for understanding probability in statistical mechanics, namely quantum approaches and almost-objective probabilities, can be accomodated in the MZ formalism. Moreover, I will provide a detailed physical analysis, based on the MZ formalism, of various proposals from the philosophical literature, such as Robertson’s theory of justifying coarse-graining via autonomous macrodynamics, Myrvold’s problem of explaining autonomous macrodynamics, and Wallace’s simple dynamical conjecture. (shrink)

Three disciplines address the codified forms and rules of human thought and reasoning: logic, available since antiquity; dialectics as a process of logical reasoning; and semiotics which focuses on the epistemological properties of the extant domain. However, both the paradigmatic-historical model of knowledge and the logical-semiotic model of thought tend to incorrectly emphasize the separation and differences between the respective domains vs. their overlap and interactions. We propose a sublation of linguistic logics of objects and static forms by a dynamic (...) logic of real physical-mental processes designated as the Logic in Reality (LIR). In our generalized logical theory, dialectics and semiotics are recovered from reductionist interpretations and reunited in a new synthetic paradigm centered on meaning and its communication. Our theory constitutes a meta-thesis composed of elements from science, logic and philosophy. We apply the theory to gain new insights into the structure and role of semiosis, information and communication and propose the concept of ‘ontolon’ to define the element of reasoning as a real dynamic process. It is part of a project within natural philosophy, which will address broader aspects of the dynamics of the growth of civilizations and their potential implications for the information society. (shrink)

Classical statistical mechanics posits probabilities for various events to occur, and these probabilities seem to be objective chances. This does not seem to sit well with the fact that the theory’s time evolution is deterministic. We argue that the tension between the two is only apparent. We present a theory of Humean objective chance and show that chances thus understood are compatible with underlying determinism and provide an interpretation of the probabilities we find in Boltzmannian statistical mechanics.