One kind of generalized measures called quantum measures on finite effect algebras, which fulfil the grade-2 additive sum rule, is considered. One basis of vector space of quantum measures on a finite effect algebra with the Riesz decomposition property (RDP for short) is given. It is proved that any diagonally positive symmetric signed measure \(\lambda \) on the tensor product \(E\otimes E\) can determine a quantum measure \(\mu \) on a finite effect algebra \(E\) with the RDP such that \(\mu (...) (x)=\lambda (x\otimes x)\) for any \(x\in E\) . Furthermore, some conditions for a grade-2 additive measure \(\mu \) on a finite effect algebra \(E\) are provided to guarantee that there exists a unique diagonally positive symmetric signed measure \(\lambda \) on \(E\otimes E\) such that \(\mu (x)=\lambda (x\otimes x)\) for any \(x\in E\) . At last, it is showed that any grade- \(t\) quantum measure on a finite effect algebra \(E\) with the RDP is essentially established by the values on a subset of \(E\). (shrink)