# Entropy : A concept that is not a physical quantity

*Physics Essays*25 (2):172-176 (2012)

**Abstract**

This study has demonstrated that entropy is not a physical quantity, that is, the physical quantity called entropy does not exist. If the efficiency of heat engine is defined as η = W/W1, and the reversible cycle is considered to be the Stirling cycle, then, given ∮dQ/T = 0, we can prove ∮dW/T = 0 and ∮d/T = 0. If ∮dQ/T = 0, ∮dW/T = 0 and ∮dE/T = 0 are thought to define new system state variables, such definitions would be absurd. The fundamental error of entropy is that in any reversible process, the polytropic process function Q is not a single-valued function of T, and the key step of Σ[(ΔQ)/T)] to ∫dQ/T doesn’t hold, P-V fig. should be P-V-T fig.in thermodynamics. Similarly, ∮dQ/T = 0, ∮dW/T = 0 and ∮dE/T = 0 do not hold, either. Since the absolute entropy of Boltzmann is used to explain Clausius entropy and the unit (J/K) of the former is transformed from the latter, the non-existence of Clausius entropy simultaneously denies Boltzmann entropy.

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