In 1858, August Kekulé and Archibald Scott Couper independently published similar ideas regarding the tetravalence and self-linking ability of carbon atoms; three years later, the Russian chemist Aleksandr Mikhailovich Butlerov read a paper at the German Naturforscherversammlung in Speyer, which restated, clarified, and enlarged upon the ideas of Kekulé and Couper. In 1958, the centenary of the structure theory was celebrated in Chicago, London, Heidelberg, and Ghent; the celebrations in Moscow, Frunze, and Kazan took place three years later. For over (...) a century chemists and chemical historians have disputed the origins of structure theory. Sometimes this activity has been confined to occasional sniping, but at other times determined battles have been fought. The polemic has never been characterized by cool and dispassionate discourse. Western historians have in general been unwilling or unable to master the extensive Russian literature on the question; the arguments of Soviet historians have often been clothed in Marxist rhetoric or otherwise influenced by political considerations. (shrink)

This paper is intended to be an introductory survey of subjects related to the problems dealt with in the three other papers in this symposium on quantum field theory. A brief history of quantum electrodynamics is given and some of the objections to it are stated. A brief history of quantum field theories from the 1970's to the present is then provided. Finally, a sketch of some of the philosophical work that has been done on quantum field theories is presented. (...) The object of the paper is to explain why philosophers of physics have tended to neglect quantum field theories and to point out several of the conceptual issues raised by quantum field theories that call out for further analysis. (shrink)

Analytic philosophy has recently demonstrated a revived interest in metaphysical problems about possibility and necessity. Graeme Forbes here provides a careful description of the logical background of recent work in this area for those who may be unfamiliar with it, moving on to d discuss the distinction between modality de re and modality de dicto and the ontological commitments of possible worlds semantics. In addition, Forbes offers a unified theory of the essential properties of sets, organisms, artefacts, substances, and events, (...) based on the doctrine that identity facts must be intrinsically grounded, and analyzes and rejects apparent counterexamples to this doctrine. (shrink)

In this sequence of philosophical essays about natural science, the author argues that fundamental explanatory laws, the deepest and most admired successes of modern physics, do not in fact describe regularities that exist in nature. Cartwright draws from many real-life examples to propound a novel distinction: that theoretical entities, and the complex and localized laws that describe them, can be interpreted realistically, but the simple unifying laws of basic theory cannot.

The concept underlying Prigogine's ideas is the asymmetric "lifetime" he introduces into thermodynamics in addition to the symmetric time parameter. By identifying processes by means of causal chains of genidentical events, we examine the intrinsic order of lifetime adopting Grunbaum's symmetric time order. Further, we define the physical meaning and the actuality of the processes under consideration. We conclude that Prigogine's microscopic temporal irreversibility is tacitly assumed at macroscopic level. Moreover, his "new" complementarity lacks any scientific foundation. Finally, we put (...) forward the fact-like origin of temporal irreversibility referring to classical thermodynamics. (shrink)

In this paper I evaluate the soundness of the prototype paradigm, in particular its basic assumption that there are pan-human psychological essences or core meanings that refer to basic-level natural kinds, explaining why, on the whole, human communication and learning are successful. Instead I argue that there are no particular pan-human basic elements for thought, meaning and cognition, neither prototypes, nor otherwise. To illuminate my view I draw on examples from anthropology. More generally I argue that the prototype paradigm exemplifies (...) two assumptions that dominate cognitive science: (1) If human beings use words they mean something particular and what they mean can be discovered by scientific methods. (2) There is a fixed number of domains of categorization, each made up of a fixed number of basic categories. I suggest that these two assumptions lead to Brave New World. (shrink)

There are various senses in which a physical theory may be said to "unify" different forces, with the unification being deeper of more shallow in different cases. This paper discusses some of these distinctions.

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

Summary Opinion is divided as to whether chemistry is reducible to physics. The problem can be given a satisfactory solution provided three conditions are met: that a science not be identified with its theories; that several notions of theory dependence be distinguished; and that quantum chemistry, rather than classical chemistry, be compared with physics. This paper proposes to perform all three tasks. It does so by analyzing the methodological concepts concerned as well as by examining the way a chemical rate (...) constant is derivable with the help of the quantum atomic theory. The conclusion is that chemistry, and in particular quantum chemistry, is not a part of physics although it is certainly based on the latter. (shrink)

A highly condensed account of the author's present view of some philosophical problems unresolved in The Structure of Scientific Revolutions. The concept of incommensurability, now considerably developed, remains at center stage, but the evolutionary metaphor, introduced in the final pages of the book, now also plays a principal role.