The history of productivity of the κ-chain condition in partial orders, topological spaces, or Boolean algebras is surveyed, and its connection to the set-theoretic notion of a weakly compact cardinal is highlighted. Then, it is proved that for every regular cardinal κ > א1, the principle □ is equivalent to the existence of a certain strong coloring c : [κ]2 → κ for which the family of fibers T is a nonspecial κ-Aronszajn tree. The theorem follows from an analysis of (...) a new characteristic function for walks on ordinals, and implies in particular that if the κ-chain condition is productive for a given regular cardinal κ > א1, then κ is weakly compact in some inner model of ZFC. This provides a partial converse to the fact that if κ is a weakly compact cardinal, then the κ-chain condition is productive. (shrink)