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The Gibbs Paradox

Entropy 20 (8):552 (2018)

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  1. Subtle Is the Lord: The Science and the Life of Albert Einstein.Abraham Pais - 1986 - Science and Society 50 (1):117-121.
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  • The Emergent Multiverse: Quantum Theory According to the Everett Interpretation.David Wallace - 2012 - Oxford, GB: Oxford University Press.
    David Wallace argues that we should take quantum theory seriously as an account of what the world is like--which means accepting the idea that the universe is constantly branching into new universes. He presents an accessible but rigorous account of the 'Everett interpretation', the best way to make coherent sense of quantum physics.
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  • How Classical Particles Emerge From the Quantum World.Dennis Dieks & Andrea Lubberdink - 2011 - Foundations of Physics 41 (6):1051-1064.
    The symmetrization postulates of quantum mechanics (symmetry for bosons, antisymmetry for fermions) are usually taken to entail that quantum particles of the same kind (e.g., electrons) are all in exactly the same state and therefore indistinguishable in the strongest possible sense. These symmetrization postulates possess a general validity that survives the classical limit, and the conclusion seems therefore unavoidable that even classical particles of the same kind must all be in the same state—in clear conflict with what we know about (...)
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  • On the indistinguishability of classical particles.S. Fujita - 1991 - Foundations of Physics 21 (4):439-457.
    If no property of a system of many particles discriminates among the particles, they are said to be indistinguishable. This indistinguishability is equivalent to the requirement that the many-particle distribution function and all of the dynamic functions for the system be symmetric. The indistinguishability defined in terms of the discrete symmetry of many-particle functions cannot change in the continuous classical statistical limit in which the number density n and the reciprocal temperature β become small. Thus, microscopic particles like electrons must (...)
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  • The logic of the past hypothesis.David Wallace - 2023 - In Barry Loewer, Brad Weslake & Eric B. Winsberg (eds.), The Probability Map of the Universe: Essays on David Albert’s _Time and Chance_. Cambridge MA: Harvard University Press. pp. 76-109.
    I attempt to get as clear as possible on the chain of reasoning by which irreversible macrodynamics is derivable from time-reversible microphysics, and in particular to clarify just what kinds of assumptions about the initial state of the universe, and about the nature of the microdynamics, are needed in these derivations. I conclude that while a “Past Hypothesis” about the early Universe does seem necessary to carry out such derivations, that Hypothesis is not correctly understood as a constraint on the (...)
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  • Gibbs' paradox and non-uniform convergence.K. G. Denbigh & M. L. G. Redhead - 1989 - Synthese 81 (3):283 - 312.
    It is only when mixing two or more pure substances along a reversible path that the entropy of the mixing can be made physically manifest. It is not, in this case, a mere mathematical artifact. This mixing requires a process of successive stages. In any finite number of stages, the external manifestation of the entropy change, as a definite and measurable quantity of heat, isa fully continuous function of the relevant variables. It is only at an infinite and unattainable limit (...)
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  • On the explanation for quantum statistics.Simon Saunders - 2006 - Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics 37 (1):192-211.
    The concept of classical indistinguishability is analyzed and defended against a number of well-known criticisms, with particular attention to the Gibbs’paradox. Granted that it is as much at home in classical as in quantum statistical mechanics, the question arises as to why indistinguishability, in quantum mechanics but not in classical mechanics, forces a change in statistics. The answer, illustrated with simple examples, is that the equilibrium measure on classical phase space is continuous, whilst on Hilbert space it is discrete. The (...)
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  • The Logic of Identity: Distinguishability and Indistinguishability in Classical and Quantum Physics.Dennis Dieks - 2014 - Foundations of Physics 44 (12):1302-1316.
    The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical statistical mechanics. In particular, the Gibbs paradox has sometimes been interpreted as a sign of the untenability of the classical concept of a particle and as a premonition that quantum theory is needed. This idea of a ‘quantum connection’ stubbornly persists in the literature, (...)
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