The so-called ‘redintegration experiment’ is traditionally at the center of the comments on the supposed Boyle/Spinoza controversy. A. Clericuzio influentially argued in his publications that, in De nitro, Boyle accounted for the ‘redintegration’ of saltpeter on the grounds of the chemical properties of corpuscles and “did not make any attempt to deduce them from mechanical principles”. By way of contrast, this paper argues that with his De nitro Boyle wanted to illustrate and promote his new corpuscular or mechanical philosophy, and (...) that he made significant attempts to explain the phenomena in terms of mechanical qualities. Boyle had borrowed the ‘redintegration experiment’ from R. Glauber and used it in an attempt to demonstrate that his philosophy was superior to the Peripatetic and Paracelsian theory. Consequently, Clericuzio’s characterization of the Boyle/Spinoza controversy as a discussion between a strict mechanical philosopher and a chemist is problematic and a wider view of Spinoza’s interpretation and its context gives a fairer picture. (shrink)

Alan Chalmers uses Robert Boyle’s mechanical philosophy as an example of the irrelevance of ‘philosophy’ to ‘science’ and criticizes my 2006 book Atoms and alchemy for overemphasizing Boyle’s successes. The present paper responds as follows: first, it argues that Chalmers employs an overly simplistic methodology insensitive to the distinction between historical and philosophical claims; second, it shows that the central theses of Atoms and alchemy are untouched by Chalmers’s criticisms; and third, it uses Boyle’s analysis of subordinate causes and his (...) debate with Henry More in the 1670s to demonstrate the inadequacy of Chalmers’s construal of the mechanical philosophy.Keywords: Robert Boyle; Alan Chalmers; Geber; Paul of Taranto; Daniel Sennert; Alchemy; Chymistry; Mechanical philosophy; Reduction to the pristine state. (shrink)

William Newman construes the Scientific Revolution as a change in matter theory, from a hylomorphic, Aristotelian to a corpuscular, mechanical one. He sees Robert Boyle as making a major contribution to that change by way of his corpuscular chemistry. In this article it is argued that it is seriously misleading to identify what was scientific about the Scientific Revolution in terms of a change in theories of the ultimate structure of matter. Boyle showed, especially in his pneumatics, how empirically accessible, (...) intermediate causes, as opposed to ultimate, mechanical ones can be explored and identified by experiment. Newman is right to observe that Boyle constantly sought intimate links between chemistry and the mechanical philosophy. However, by doing so he did not thereby significantly aid the cause of attaining experimental knowledge of chemical phenomena and the support that Boyle’s chemistry provided for the mechanical philosophy was weaker than both Boyle and Newman imply. Boyle was intent on articulating and defending a strict, mechanical account of the ultimate structure of matter to be sure, but his contributions to the new experimental science in general, and chemistry in particular, are best seen as distinct from that endeavour.Keywords: Chemistry; Mechanical philosophy; Corpuscular philosophy; Experiment; Robert Boyle; William Newman. (shrink)

Although Boyle has been regarded as a champion of the seventeenth century Cartesian mechanical philosophy, I defend the position that Boyle’s views conciliate between a strictly mechanistic conception of fundamental matter and a non-reductionist conception of chemical qualities. In particular, I argue that this conciliation is evident in Boyle’s ontological distinction between fundamental corpuscles endowed with mechanistic properties and higher-level corpuscular concretions endowed with chemical properties. Some of these points have already been acknowledged by contemporary scholars, and I actively engage (...) with their ideas in this paper. However I attempt to contribute to the debate over Boyle’s mechanical philosophy by arguing that Boyle’s writings suggest an emergentist, albeit still mechanistic, notion of chemical properties. I contrast Boyle’s views against those of strict reductionist mechanical philosophers, focusing on the famous debate with Spinoza over the redintegration of niter, and argue that Boyle’s complex chemical ontology provides a more satisfactory understanding of chemical phenomena than is provided by a strictly reductionist and Cartesian mechanical philosophy. (shrink)

Chemistry is the study of the structure and transformation of matter. When Aristotle founded the field in the 4th century BCE, his conceptual grasp of the nature of matter was tailored to accommodate a relatively simple range of observable phenomena. In the 21st century, chemistry has become the largest scientific discipline, producing over half a million publications a year ranging from direct empirical investigations to substantial theoretical work. However, the specialized interest in the conceptual issues arising in chemistry, hereafter Philosophy (...) of Chemistry, is a relatively recent addition to philosophy of science. Philosophy of chemistry has two major parts. In the first, conceptual issues arising within chemistry are carefully articulated and analyzed. Such questions which are internal to chemistry include the nature of substance, atomism, the chemical bond, and synthesis. In the second, traditional topics in philosophy of science such as realism, reduction, explanation, confirmation, and modeling are taken up within the context of chemistry. (shrink)

Two inter-linked theses are defended in this paper. One is the Duhemian theme that a rigid distinction between physical and chemical properties cannot be upheld. Duhem maintained this view not because the latter are reducible to the former, but because if physics is to remain consistent with chemistry it must prove possible to expand it to accommodate new features, and a rigid distinction would be a barrier to this process. The second theme is that naturally occurring isotopic variants of water (...) are in fact distinct substances, and naturally occurring samples of water are mixtures of these substances. For most practical purposes it is convenient to treat protium oxide, deuterium oxide, and so on, as the same chemical substance, but to insist on this as a matter of principle would stand in conflict with the first thesis. (shrink)

The so-called ‘redintegration experiment’ is traditionally at the center of the comments on the supposed Boyle/Spinoza controversy. A. Clericuzio influentially argued in his publications that, in De nitro, Boyle accounted for the ‘redintegration’ of saltpeter on the grounds of the chemical properties of corpuscles and “did not make any attempt to deduce them from mechanical principles”. By way of contrast, this paper argues that with his De nitro Boyle wanted to illustrate and promote his new corpuscular or mechanical philosophy, and (...) that he made significant attempts to explain the phenomena in terms of mechanical qualities. Boyle had borrowed the ‘redintegration experiment’ from R. Glauber and used it in an attempt to demonstrate that his philosophy was superior to the Peripatetic and Paracelsian theory. Consequently, Clericuzio’s characterization of the Boyle/Spinoza controversy as a discussion between a strict mechanical philosopher and a chemist is problematic and a wider view of Spinoza’s interpretation and its context gives a fairer picture. (shrink)