Whether or not quantum physics can account for molecular structure is a matter of considerable controversy. Three of the problems raised in this regard are the problems of molecular structure. We argue that these problems are just special cases of the measurement problem of quantum mechanics: insofar as the measurement problem is solved, the problems of molecular structure are resolved as well. In addition, we explore one consequence of our argument: that claims about the reduction or emergence of molecular structure (...) cannot be settled independently of the choice of a particular resolution to the measurement problem. Specifically, we consider how three standard putative solutions to the measurement problem inform our under- standing of a molecule in isolation, as well as of chemistry’s relation to quantum physics. (shrink)

A brief introduction to the physics and philosophy of symmetry breaking.

Spontaneous symmetry breaking in quantum systems, such as ferromagnets, is normally described as degeneracy of the ground state; however, it is well established that this degeneracy only occurs in spatially infinite systems, and even better established that ferromagnets are not spatially infinite. I review this well-known paradox, and consider a popular solution where the symmetry is explicitly broken by some external field which goes to zero in the infinite-volume limit; although this is formally satisfactory, I argue that it must be (...) rejected as a physical explanation of SSB since it fails to reproduce some important features of the phenomenology. Motivated by considerations from the analogous classical system, I argue that SSB in finite systems should be understood in terms of the approximate decoupling of the system's state space into dynamically-isolated sectors, related by a symmetry transformation; I use the formalism of decoherent histories to make this more precise and to quantify the effect, showing that it is more than sufficient to explain SSB in realistic systems and that it goes over in a smooth and natural way to the infinite limit. (shrink)

In this essay, I provide an overview of the debate on infinite and essential idealizations in physics. I will first present two ostensible examples: phase transitions and the Aharonov– Bohm effect. Then, I will describe the literature on the topic as a debate between two positions: Essentialists claim that idealizations are essential or indispensable for scientific accounts of certain physical phenomena, while dispensabilists maintain that idealizations are dispensable from mature scientific theory. I will also identify some attempts at finding a (...) middle ground between the essentialists and dispensabilists camps. Finally, I will raise questions for future research on essential and infinite idealizations via the notion of exploration. (shrink)

Two approaches to understanding the idealizations that arise in the Aharonov–Bohm effect are presented. It is argued that a common topological approach, which takes the non-simply connected electron configuration space to be an essential element in the explanation and understanding of the effect, is flawed. An alternative approach is outlined. Consequently, it is shown that the existence and uniqueness of self-adjoint extensions of symmetric operators in quantum mechanics have important implications for philosophical issues. Also, the alleged indispensable explanatory role of (...) said idealizations is examined via a minimal model explanatory scheme. Last, the idealizations involved in the AB effect are placed in a wider philosophical context via a short survey of part of the literature on infinite and essential idealizations. (shrink)