The discussion of different principles of additivity for probability functions has been largely focused on the personalist interpretation of probability. Very little attention has been given to additivity principles for physical probabilities. The form of additivity for quantum probabilities is determined by the algebra of observables that characterize a physical system and the type of quantum state that is realizable and preparable for that system. We assess arguments designed to show that only normal quantum states are realizable and preparable and, (...) therefore, quantum probabilities satisfy the principle of complete additivity. We underscore the little remarked fact that unless the dimension of the Hilbert space is incredibly large, complete additivity in ordinary non-relativistic quantum mechanics reduces to countable additivity. We then turn to ways in which knowledge of quantum probabilities may constrain rational credence about quantum events and, thereby, constrain the additivity principle satisfied by rational credence functions. (shrink)