This article aims to clarify how aspects of current chemical understanding relate to some important contemporary problems of philosophy. The first section points out that the long-running philosophical debates concerning how properties stay together in substances have neglected the important topic of structure-determining closure. The second part describes several chemically-important types of closure and the third part shows how such closures ground the properties of chemical substances. The fourth section introduces current discussions of structural realism (SR) and contextual emergence: the (...) final sections reconsider the coherence of the properties of substances and concludes that recognition that structures qualify as determinants of specific outcomes—as ‘causes’ as that designation is used in Standard English—clarifies how properties stay together in chemical entities, and by analogy, how characteristics cohere in ordinary items. (shrink)

Philosophical debates about chemistry have clarified that the issue of emergence plays a critical role in the epistemology and ontology of chemistry. In this article, it is argued that the issue of emergence has also significant implications for understanding learning difficulties and finding ways of addressing them in chemistry. Particularly, it is argued that many misconceptions in chemistry may derive from students’ failure to consider emergence in a systemic manner by taking into account all relevant factors in conjunction. Based on (...) this argument, undergraduate students’ conceptions of acids, and acid strength were investigated and it was examined whether or not they conceptualized acid strength as an emergent chemical property. The participants were 41 third- and fourth-year undergraduate students. A concept test and semi-structured interviews were used to probe students’ conceptualizations and reasoning about acid strength. Findings of the study revealed that the majority of the undergraduate students did not conceptualize acid strength as an emergent property that arises from interactions among multiple factors. They generally focused on a single factor to predict and explain acid strength, and their faulty responses stemmed from their failure to recognize and consider all factors that affect acid strength. Based on these findings and insights from philosophy of chemistry, promoting system thinking and epistemologically sound argumentative discourses among students is suggested for meaningful chemical education. (shrink)

It is argued that explanations of shock waves display explanatory emergence in two different ways. Firstly, the use of discontinuities to model jumps in flow variables is an example of “physics avoidance”. This is where microphysical details can be ignored in an abstract model thus allowing us access to modal information which cannot be attained in principle in any other way. Secondly, Whitham’s interleaving criterion for continuous shock structure is an example of the way different characteristic scales interact in shock (...) dynamics. To fully explain the shock structure one must take account of these different scales, and by doing so explanations of shock structure have irreducible aspects. Lastly, the implications of this explanatory irreducibility are examined in the context of explanatory indispensability arguments used in realism debates elsewhere in the philosophy of science. It is concluded that explanatory emergence on its own only supports an epistemic form of emergence. Yet this epistemic emergence is fully objective. (shrink)

The analysis of the concept of orbital allows us to argue that—in opposition to a recent position in philosophy of science—it is impossible to defend the autonomy of the chemical reality in regard to physical reality, appealing to the idea that there is a conceptual rupture among a chemical interpretation and a quantuminterpretation of the concept. This is the case because there are not two different interpretations of the concept of orbital. On the contrary, the concept involved in structural chemistry (...) and in quantum chemistry comes from quantum mechanics.El análisis del concepto de orbital permite argumentar—en oposición a una propuesta reciente en filosofía de la química—que no es posible defender la autonomía ontológica de la realidad química respecto de la física, sobre la base de una ruptura conceptual entre una interpretación química del concepto y otra propia de la mecánica cuántica. Esto es así porque no existen tales interpretaciones distintas del concepto de orbital, sino que, por el contrario, este concepto en química cuántica y en química estructural proviene de la mecánica cuántica. (shrink)

In learning chemistry at the entry level, many learners labor under misconceptions about the subject matter that are so fundamental that they are typically never addressed. A fundamental misconception in chemistry appears to arise from an adding of existing phenomenal concepts to newly-acquired chemical concepts, so that beginning learners think of chemical entities as themselves having the very same ‘macro’ properties that we observe through the senses. Those who teach or practice chemistry never acquire these misconceptions because they were able (...) to naturally pick up the nature of the subject to begin with. But as a result, they remain unaware of the foundational assumptions and understanding that they operate with and that many beginning learners persistently lack. Thus, a systematic picture of the workings of chemical theory as they relate to observable phenomena needs to be elucidated so that the attention of chemical educators is drawn to the fundamental understanding of the subject that they already possess and that beginning learners of chemistry lack, so that beginning learners can be given the opportunity to gain an understanding of how chemical explanations are in general related to observable phenomena. The ‘layered’ way in which chemical and physical entities are related to each other within chemical theory can also be clarified in this way. To afford this picture, the philosophical concepts of supervenience and emergence are explained and applied to chemistry, as philosophers of chemistry have already done. The result provides a model for teaching chemistry that, if consistently applied, has the potential to greatly enhance fundamental understanding of the subject matter. (shrink)

This paper aims to show that there is a lot of philosophy in the philosophy of chemistry—not only in the problems and questions specific to chemistry, which this science brings up in philosophical discussions, but also in the topics of wider interest like reductionism and emergence, for which chemistry proves to be an ideal case study. The fact that chemical entities and properties are amenable to a quantitative understanding, to measurement and experiment to a greater extent than those in psychology (...) or biology, makes chemistry an ideal case study for those interested in reductionism and emergence. (shrink)

The term emergence, or irreducibility, has been used in a great variety of senses over the years, and different senses are useful in different discursive contexts. In this paper the focus is on one specific context, that of methodologically oriented social theory, and the question to answer is, what might be the most useful sense of emergent irreducibility in that field? To answer that question, key intuitions of emergence are first abstracted from the concept’s history. Three main senses of the (...) term are distinguished based on those different intuitions. Then the likely linguistic functions of emergence in each of those main senses are gauged in social theory and methodology. It is argued that one of the senses – here called “contingently epistemological irreducibility” – is in fact more useful as regards social scientific methodology than the others. (shrink)

I argue that there are two distinct approaches to understanding reduction: the ontology-first approach and the theory-first approach. They concern the relation between ontological reduction and inter-theoretic reduction. Further, I argue for the significance of this distinction by demonstrating that either one or the other approach has been taken as an implicit assumption in, and has in fact shaped, our understanding of what statistical mechanics is. More specifically, I argue that the Boltzmannian framework of statistical mechanics assumes and relies on (...) the ontology-first approach, whereas the Gibbsian framework should assume the theory-first approach. -/- . (shrink)