Häggqvist and Wikforss argued that in the case of so-called natural kind terms, semantic externalism relies on an untenable metaphysics of kinds: microessentialism. They further claimed that this metaphysics fails, for largely empirical reasons. Focussing on the case of water, Hoefer and Martí European Journal for the Philosophy of Science, 9, rejoin that suitably construed, microessentialism is correct. I argue that their defence of microessentialism fails.

Natural kind concepts have the function of tracking categories that exist independently of our beliefs and purposes. But not all ways of tracking categories in the natural world involve conceiving of them as natural kinds. Anthropic concepts represent groups of natural, mind‐independent entities that are apt for serving various human interests, goals, and projects. They represent the natural world under a practical mode of presentation, as a set of material resources that can be transformed to further a host of functions (...) and ends. I argue that cross‐cultural studies of traditional ecological knowledge provide evidence that many chemical, mineral, and biological concepts that are frequently taken to be natural kind concepts turn out on closer inspection to be anthropic concepts. Anthropic concepts are distinguished from artifact concepts, and a form of realism about the anthropic kinds that they refer to is defended. (shrink)

In this article we critically evaluate Robin Le Poidevin's recent attempt to set out an argument for the ontological reduction of chemistry independently of intertheoretic reduction. We argue, firstly, that the argument he envisages applies only to a small part of chemistry, and that there is no obvious way to extend it. We argue, secondly, that the argument cannot establish the reduction of chemistry, properly so called.

In The Philosophy of Philosophy, Tim Williamson has offered a sophisticated account of thought experiments and of modal epistemology. More recently, he has also engaged in a variant of the so-called ‘expertise defence’ of traditional philosophical methodology. In this paper I argue that if Williamson’s account of thought experiments and of modal epistemology is right, this seriously undermines his version of the expertise defence.

This paper aims to show that there is a lot of philosophy in the philosophy of chemistry—not only in the problems and questions specific to chemistry, which this science brings up in philosophical discussions, but also in the topics of wider interest like reductionism and emergence, for which chemistry proves to be an ideal case study. The fact that chemical entities and properties are amenable to a quantitative understanding, to measurement and experiment to a greater extent than those in psychology (...) or biology, makes chemistry an ideal case study for those interested in reductionism and emergence. (shrink)

This article, which is intended both as a position paper in the philosophical debate on natural kinds and as the guest editorial to this thematic issue, takes up the challenge posed by Ian Hacking in his paper, “Natural Kinds: Rosy Dawn, Scholastic Twilight.” Whereas a straightforward interpretation of that paper suggests that according to Hacking the concept of natural kinds should be abandoned, both in the philosophy of science and in philosophy more generally, we suggest that an alternative and less (...) fatalistic reading is also possible. We argue that abandoning the concept of natural kinds would be premature, as it still can do important work. Our concern is with the situation in the (philosophy of the) life sciences. Against the background of this concern we attempt to set something of an agenda for future research on the topic of natural kinds in the (philosophy of the) life sciences. (shrink)

The bulk of Duhem's writing which bears on the understanding of mixtures suggests he adopted an Aristotelian position which he opposed only to the atomic view. A third view from antiquity-that of the Stoics-seems not to be taken into account. But his lines of thought are not always as explicit as could be wished. The Stoic view is considered here from a perspective which Duhem might well have adopted. This provides a background against which his somewhat unorthodox Aristotelianism might be (...) understood. (shrink)

Are acids natural kinds? Or are they merely relevant kinds? Although acidity has been one of the oldest and most important concepts in chemistry, surprisingly little ink has been spilled on the natural kind question. I approach the question from the perspective of microstructural essentialism. After explaining why both Brønsted acids and Lewis acids are considered functional kinds, I address the challenges of multiple realization and multiple determination. Contra Manafu and Hendry, I argue that the stereotypical properties of acids are (...) not multiply realized. Instead, given the equivalence between the proton-donating and electron-accepting mechanisms of Brønsted and Lewis, respectively, I show that acidity as a property type can be identified with a unique microstructural property, namely the presence of a LUMO or other low energy empty orbital. In doing so, I defend the view that the Lewis theory encompasses Brønsted–Lowry, and that all Brønsted acids are also Lewis acids. Contra Hacking and Chang, I thus maintain that the different concepts of acidity do not crosscut, and that the hierarchy requirement is met. Finally, by characterizing natural kinds as powerful objects and by adopting a dispositional view of functions, I illustrate how the microessentialist can make sense of the latent and relational character of most acids. In sum, I contend that acids are genuine natural kinds, even for the microstructural essentialist. (shrink)

In this paper I raise a difficulty for Joseph LaPorte's account of chemical kind terms. LaPorte has argued against Putnam that H₂O content is neither necessary nor sufficient to fix the reference of the kind term 'water' and that we did not discover that water is H₂O. To this purpose, he revisits Putnam's Twin Earth story with the fictional scenario of Deuterium Earth, whose ocean consists of 'dwater', to conclude that we did not discover that deuterium oxide is (a kind (...) of) water (usually called 'heavy water'). Instead, according to LaPorte, by including deuterium oxide in the extension of the term 'water', we simply refined our vague use of the term 'water'. But we could have decided to exclude deuterium oxide from the extension of the term 'water'. Let us call this the thesis of semantic stipulation. I raise two problems for LaPorte's Deuterium Earth story. First, I show that 'dwater' (i.e. deuterium oxide not as a kind of water) does not have the same scientific credibility of 'heavy water' (i.e. deuterium oxide as a kind of water). Second, I argue that for the thesis of semantic stipulation to go through one would need to show that 'dwater' is semantically on a par with 'heavy water'. Namely, one would need to show that 'dwater' is a projectible kind term, capable of supporting inductive inferences. But, in fact, it is not, because the term is vulnerable to an unwelcome Goodmanian scenario, unless one surreptitiously reintroduces some Putnamian assumptions about D₂O content being necessary and sufficient to fix the reference of the term. (shrink)

This essay critically considers the issue of natural kind essentialism. More specifically, the essay critically probes the philosophical use of chemical examples to support realism about natural kinds. My simple contention is that the natural kind debate can be understood in terms of two different cultures of academic production. These two cultures will be conceptualized using Thomas Kasulis’s distinction between intimacy and integrity as cultural orientations. Acknowledging Kasulis’s contention that, “What is foreground in one culture may be background in another”, (...) it may very well be the case that philosophers writing about chemistry place chemical practice in the background, thereby adopting the orientation of integrity. Chemists and philosophers of chemistry, on the other hand, place chemical practice at the foreground of their work, thereby adopting the orientation of intimacy. Because the intimacy orientation is grounded in chemical practice, it is preferable to the integrity orientation. Understanding the natural kinds debate from this perspective highlights the fact that the misuse of chemical examples by certain philosophers is informed by an orientation of detachment from actual chemical practice. This underscores the importance of an intimate understanding of chemical practice when deploying chemical examples in the context of philosophical discussions about ontology and metaphysics. (shrink)

In this thesis I argue that we should break with the dominant Kripkean tradition concerning natural kind terms and theoretical identity. I claim that there is just no interesting connection between the metaphysics and semantics of natural kind terms, and demonstrate this by constructing a version of descriptivism that is combined with the same metaphysics – that is, a nontrivial version of essentialism – found in Kripke, but which effectively avoids all of the standard criticisms. With my version of descriptivism (...) in place, I present what I take to be the most reasonable version of metaphysical essentialism, positing only what I call 'thin' essences. I claim that thin essences are perfectly adequate to underpin scientific realism, and moreover that they are sufficient to support the version of descriptivism developed here. In effect, what I offer here is an error theory of the Kripkean tradition: Kripke is right to think that there are interesting things to say about meaning and essence, but just wrong about what those things are. Thus whilst Kripke thinks that it is possible to make discoveries about the meanings of natural kind terms, I think, rather, that we make empirical discoveries that lead to revisions in meaning. Furthermore, whilst Kripke thinks there is a dichotomy between de re and de dicto necessity, and that theoretical identities are necessary de re, I think this distinction is both misleading and inaccurate, and that the necessity of theoretical identities is neither entirely de re nor entirely de dicto. By separating and insulating questions concerning meaning from questions concerning essence I show that whilst scientific discoveries are contingent and a posteriori, the definition of scientific terms are both necessary and a priori. (shrink)

The Aristotelian distinction between actual and potential presence of a substance in a mixture forms part of a conception of mixture which stands in contrast to atomist and Stoic theories as propounded by the ancients. But the central ideas on which these theories are built need not be combined and opposed to one another in precisely the ways envisaged by these ancient theories. This is well illustrated by Duhem, who maintained the Aristotelian idea that the original ingredients are only potentially, (...) and not actually, present in a mixture, but who sided with the Stoics and against Aristotle on the possibility of co-occupancy. I have argued that the Stoic theory cannot dispense with some such notion as the Aristotelian conception of potentiality in allowing the elements to be actually present in a mixture. Here I suggest that some such Aristotelian notion must be at work in a more modern atomic conception of matter if this is to allow elemental substances to be actually present in compounds, which I think is how compounds are usually understood. Analogous issues arise regarding the status of solutions and their components. (shrink)

In a recent critique of the doctrine of emergentism championed by its classic advocates up to C. D. Broad, Jaegwon Kim (Philosophical Studies 63:31–47, 1999) challenges their view about its applicability to the sciences and proposes a new account of how the opposing notion of reduction should be understood. Kim is critical of the classic conception advanced by Nagel and uses his new account in his criticism of emergentism. I question his claims about the successful reduction achieved in the sciences (...) and argue that his new account has not improved on Nagel’s and that the critique of emergentism he bases on it is question-begging in important respects. (shrink)

In the addenda to his Naming and Necessity, Kripke provides an account of how necessary aposteriori statements are possible. In such a case, there is an apriori general principle telling us that it is necessary if true at all. Though straightforward in its broad compass, this account faces two obvious questions in its application: in each case of necessary aposteriori statements, what is the underlying principle and how is it established apriori? I treat these questions with respect to theoretical identity (...) statements concerning chemical substances, such as ‘water is H2OH2O’. I argue that the general principle underlying the necessity of the statements is that if a chemical substance has a certain chemical composition, then it could not have had any other chemical composition. Then I defend the view that the principle is a conceptual truth by providing a novel derivation of it from the theoretical concept of chemical substance with a sufficient level of formal rigor. The logical principles required for the derivation will also be stated and defended. (shrink)

Despite many attempts to achieve an adequate definition of living systems by means of a set of necessary and sufficient conditions, the opinion that such an enterprise is inexorably destined to fail is increasingly gaining support. However, we believe options do not just come down to either having faith in a future success or endorsing skepticism. In this paper, we aim to redirect the discussion of the problem by shifting the focus of attention from strict definitions towards a philosophical framework (...) that allows conceiving of living systems as a natural kind, but whereby natural kinds are not to be defined by fixed necessary and sufficient conditions. We argue for a property-cluster kind approach according to which living systems constitute a natural kind with vague boundaries, capable of changing, and whose members do not need to instantiate every property. We draw from Boyd’s homeostatic property-cluster theory and introduce two modifications, one regarding homeostatic mechanisms and another related to the scientific role of kinds. Thus, our view overcomes some difficulties of Boyd’s theory and we are able to account for the natural kindhood of living things. We also emphasize the most appealing features of our approach for specific research fields and address three objections to this sort of approach. (shrink)

From organic synthesis to quantum chemical calculation, chemists interact with chemical substances in a wide variety of ways. But what even is a chemical substance? My aim is to propose a notion of chemical substance that is consistent with the way in which chemical substances are individuated in chemistry, addressing gaps in previous conceptions of chemical substance. Water is employed as a case study to develop the account, not only because it is a familiar example of a chemical substance, but (...) also because its structural peculiarities make it an ideal test case for drawing out potential issues and limitations. Examining four distinct views of chemical substance—the microstructural, thermodynamic, purification, and a functional/relational account—I conclude that each has considerable drawbacks when used as a standalone concept. However, these accounts are not rendered obsolete, but are combined into a semi-pluralist conceptual patchwork. My interactive account of chemical substance is consistent with existing substance descriptions and chemical practice. (shrink)

In this essay I critically examine the role of entropy of mixing in articulating a macroscopic criterion for the sameness and difference of chemical substances. Consider three cases of mixing in which entropy change occurs: isotopic variants, spin isomers, and populations of atoms in different orthogonal quantum states. Using these cases I argue that entropy of mixing tracks differences between physical states, differences that may or may not correspond to a difference of substance. It does not provide a criterion for (...) the sameness and difference of substance that is appropriate to chemistry. (shrink)

Filipe Drapeau Vieira Contim,Pascal Ludwig | : La plupart des théoriciens de l’identité des types souscrivent à un physicalisme a posteriori à l’égard des propriétés phénoménales. Selon cette conception, les énoncés d’identité esprit/cerveau peuvent être justifiés par une inférence à la meilleure explication (IME) partant du fait empirique des corrélations esprit/cerveau. Nous soutenons que la théorie de l’identité ne peut pas s’appuyer sur cette méthodologie abductive. Nous montrons tout d’abord que l’on ne peut pas justifier les énoncés d’identité esprit/cerveau au (...) moyen d’une IME partant des corrélations esprit/cerveau car cette stratégie conduit à un dilemme : ou bien les corrélations ne sont pas des explananda, ou bien les identités esprit/cerveau doivent être admises comme des faits bruts au même titre que les lois dualistes. Nous montrons ensuite que ces énoncés d’identité peuvent être néanmoins justifiés par une IME partant du pouvoir causal des états phénoménaux. Cette seconde stratégie n’est toutefois d’aucune aide pour la forme a posteriori de théorie de l’identité ici discutée dans la mesure où elle débouche sur un physicalisme de type a priori. | : Most type identity theorists endorse a posteriori physicalism about phenomenal properties. On such a view, mind/brain identity statements can be justified by an inference to the best explanation (IBE) starting from the empirical premise of mind/brain correlations. We contend that Identity Theory cannot be based on such an abductive methodology. First, we argue that mind/brain identity statements cannot be justified by an IBE from correlations as it leads to the following dilemma : either correlations are trivial facts that cannot pretend to the status of explananda, or mind/brain identities must be admitted as brute facts, just like dualist laws. Second, we show that these identity statements can still be justified by an IBE starting from the premise of mental causation. However, this strategy is of no help for the a posteriori brand of Identity Theory here challenged since the same premise forces one to embrace a priori physicalism. (shrink)