Entropy is ubiquitous in physics, and it plays important roles in numerous other disciplines ranging from logic and statistics to biology and economics. However, a closer look reveals a complicated picture: entropy is defined differently in different contexts, and even within the same domain different notions of entropy are at work. Some of these are defined in terms of probabilities, others are not. The aim of this chapter is to arrive at an understanding of some of the most important notions (...) of entropy and to clarify the relations between them, After setting the stage by introducing the thermodynamic entropy, we discuss notions of entropy in information theory, statistical mechanics, dynamical systems theory and fractal geometry. (shrink)

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central concepts. (...) The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

In (Weaver 2021), I showed that Boltzmann’s H-theorem does not face a significant threat from the reversibility paradox. I argue that my defense of the H-theorem against that paradox can be used yet again for the purposes of resolving the recurrence paradox without having to endorse heavy-duty statistical assumptions outside of the hypothesis of molecular chaos. As in (Weaver 2021), lessons from the history and foundations of physics reveal precisely how such resolution is achieved.

This paper describes a version of type identity physicalism, which we call Flat Physicalism, and shows how it meets several objections often raised against identity theories. This identity theory is informed by recent results in the conceptual foundations of physics, and in particular clar- ifies the notion of ‘physical kinds’ in light of a conceptual analysis of the paradigmatic case of reducing thermody- namics to statistical mechanics. We show how Flat Physi- calism is compatible with the appearance of multiple realisation (...) in the special sciences, and how and in what sense the special sciences laws are autonomous from the laws of physics, despite the full reductive picture of Flat Physicalism. We compare our view with a recent proposal by William Bechtel that accounts for the appearance of levels in mechanistic explanations. (shrink)

Statistical mechanics is often taken to be the paradigm of a successful inter-theoretic reduction, which explains the high-level phenomena (primarily those described by thermodynamics) by using the fundamental theories of physics together with some auxiliary hypotheses. In my view, the scope of statistical mechanics is wider since it is the type-identity physicalist account of all the special sciences. But in this chapter, I focus on the more traditional and less controversial domain of this theory, namely, that of explaining the thermodynamic (...) phenomena.What are the fundamental theories that are taken to explain the thermodynamic phenomena? The lively research into the foundations of classical statistical mechanics suggests that using classical mechanics to explain the thermodynamic phenomena is fruitful. Strictly speaking, in contemporary physics, classical mechanics is considered to be false. Since classical mechanics preserves certain explanatory and predictive aspects of the true fundamental theories, it can be successfully applied in certain cases. In other circumstances, classical mechanics has to be replaced by quantum mechanics. In this chapter I ask the following two questions: I) How does quantum statistical mechanics differ from classical statistical mechanics? How are the well-known differences between the two fundamental theories reflected in the statistical mechanical account of high-level phenomena? II) How does quantum statistical mechanics differ from quantum mechanics simpliciter? To make our main points I need to only consider non-relativistic quantum mechanics. Most of the ideas described and addressed in this chapter hold irrespective of the choice of a (so-called) interpretation of quantum mechanics, and so I will mention interpretations only when the differences between them are important to the matter discussed. (shrink)

Statistical mechanics is a strange theory. Its aims are debated, its methods are contested, its main claims have never been fully proven, and their very truth is challenged, yet at the same time, it enjoys huge empirical success and gives us the feeling that we understand important phenomena. What is this weird theory, exactly? Statistical mechanics is the name of the ongoing attempt to apply mechanics, together with some auxiliary hypotheses, to explain and predict certain phenomena, above all those described (...) by thermodynamics. This paper shows what parts of this objective can be achieved with mechanics by itself. It thus clarifies what roles remain for the auxiliary assumptions that are needed to achieve the rest of the desiderata. Those auxiliary hypotheses are described in another paper in this journal, Foundations of statistical mechanics: The auxiliary hypotheses. (shrink)

I argue against the common and influential view that non-trivial chances arise only when the fundamental laws are indeterministic. The problem with this view, I claim, is not that it conflicts with some antecedently plausible metaphysics of chance or that it fails to capture our everyday use of ‘chance’ and related terms, but rather that it is unstable. Any reason for adopting the position that non-trivial chances arise only when the fundamental laws are indeterministic is also a reason for adopting (...) a much stronger, and far less attractive, position. I suggest an alternative account, according to which chances are probabilities that play a certain explanatory role: they are probabilities that explain associated frequencies. (shrink)

We often use symmetries to infer outcomes’ probabilities, as when we infer that each side of a fair coin is equally likely to come up on a given toss. Why are these inferences successful? I argue against answering this with an a priori indifference principle. Reasons to reject that principle are familiar, yet instructive. They point to a new, empirical explanation for the success of our probabilistic predictions. This has implications for indifference reasoning in general. I argue that a priori (...) symmetries need never constrain our probability attributions, even when it comes to our initial credences. (shrink)

From its first significant appearance in physics, the notion of probability has been linked in the minds of physicists with the notion of uncertainty. But the link may prove to be tenuous, if quantum mechanics, construed in terms of the Everett interpretation, is anything to go by.

We discuss Boltzmann’s probabilistic explanation of the second law of thermodynamics providing a comprehensive presentation of what is called today the typicality account. Countering its misconception as an alternative explanation, we examine the relation between Boltzmann’s H-theorem and the general typicality argument demonstrating the conceptual continuity between the two. We then discuss the philosophical dimensions of the concept of typicality and its relevance for scientific reasoning in general, in particular for understanding the reduction of macroscopic laws to microscopic laws. Finally, (...) we reply to various common criticisms of the typicality account. (shrink)

It is commonly thought that before the introduction of quantum mechanics, determinism was a straightforward consequence of the laws of mechanics. However, around the nineteenth century, many physicists, for various reasons, did not regard determinism as a provable feature of physics. This is not to say that physicists in this period were not committed to determinism; there were some physicists who argued for fundamental indeterminism, but most were committed to determinism in some sense. However, for them, determinism was often not (...) a provable feature of physical theory, but rather an a priori principle or a methodological presupposition. Determinism was strongly connected with principles of causality and continuity and the principle of sufficient reason; this thesis examines the relevance of these principles in the history of physics. Moreover, the history of determinism in this period shows that there were essential changes in the relation between mathematics and physics: whereas in the eighteenth century, there were metaphysical arguments which lent support to differential calculus, by the early twentieth century the development of rigorous foundations of differential calculus led to concerns about its applicability in physics. The thesis consists of six papers. In the first paper, "On the origins and foundations of Laplacian determinism", I argue that Laplace, who is usually pointed out as the first major proponent of scientific determinism, did not derive his statement of determinism directly from the laws of mechanics; rather, his determinism has a background in eighteenth century Leibnizian metaphysics, and is ultimately based on the law of continuity and the principle of sufficient reason. These principles also provided a basis for the idea that one can find laws of nature in the form of differential equations which uniquely determine natural processes. In "The Norton dome and the nineteenth century foundations of determinism", I argue that an example of indeterminism in classical physics which has attracted attention in philosophy of physics in recent years, namely the Norton come, was already discussed during the nineteenth century. However, the significance which this type of indeterminism had back then is very different from the significance which the Norton dome currently has in philosophy of physics. This is explained by the fact that determinism was conceived of in an essentially different way: in particular, the nineteenth century authors who wrote about this type of indeterminism regarded determinism as an a priori principle rather than as a property of the equations of physics. In "Vital instability: life and free will in physics and physiology, 1860-1880", I show how Maxwell, Cournot, Stewart and Boussinesq used the possibility of unstable or indeterministic mechanical systems to argue that the will or a vital principle can intervene in organic processes without violating the laws of physics, so that a strictly dualist account of life and the mind is possible. Moreover, I show that their ideas can be understood as a reaction to the law of conservation of energy and to the way it was used in physiology to exclude vital and mental causes. In "The nineteenth century conflict between mechanism and irreversibility", I show that in the late nineteenth century, there was a widespread conflict between the aim of reducing physical processes to mechanics and the recognition that certain processes are irreversible. Whereas the so-called reversibility objection is known as an objection that was made to the kinetic theory of gases, it in fact appeared in a wide range of arguments, and was susceptible to very different interpretations. It was only when the project of reducing all of physics to mechanics lost favor, in the late nineteenth century, that the reversibility objection came to be used as an argument against mechanism and against the kinetic theory of gases. In "Continuity in nature and in mathematics: Boltzmann and Poincaré", I show that the development of rigorous foundations of differential calculus in the nineteenth century led to concerns about its applicability in physics: through this development, differential calculus was made independent of empirical and intuitive notions of continuity and was instead based on mathematical continuity conditions, and for Boltzmann and Poincaré, the applicability of differential calculus in physics depended on whether these continuity conditions could be given a foundation in intuition or experience. In the final paper, "Determinism around 1900", I briefly discuss the implications of the developments described in the previous two papers for the history of determinism in physics, through a discussion of determinism in Mach, Poincaré and Boltzmann. I show that neither of them regards determinism as a property of the laws of mechanics; rather, for them, determinism is a precondition for science, which can be verified to the extent that science is successful. (shrink)

In our book The Road to Maxwell’s Demon (RMD) (Cambridge University Press 2012) we proposed a new outline for a reductive account of statistical mechanics in which thermodynamics is reduced to classical mechanics. In a recent review Valia Allori says that we misunderstood Boltzmann’s account of statistical mechanics with respect to two issues: (1) the nature of typicality considerations in Boltzmann’s explanation of the Second Law - and here she provides no argument whatsoever; and (2) Boltzmann’s notion of probability. As (...) to the second issue, unfortunately, there are flaws in her presentation of Boltzmann’s work as well as of ours. In this paper we briefly explain the difference between Boltzmann’s notion of probability and our notion, how the latter in fact complements Boltzmann’s ideas, and Allori’s flaws on these issues. (shrink)

The so-called ergodic hierarchy (EH) is a central part of ergodic theory. It is a hierarchy of properties that dynamical systems can possess. Its five levels are egrodicity, weak mixing, strong mixing, Kolomogorov, and Bernoulli. Although EH is a mathematical theory, its concepts have been widely used in the foundations of statistical physics, accounts of randomness, and discussions about the nature of chaos. We introduce EH and discuss how its applications in these fields.

The reversibility problem (better known as the reversibility objection) is usually taken to be an internal problem in the kinetic theory of gases, namely the problem of how to account for the second law of thermodynamics within this theory. Historically, it is seen as an objection that was raised against Boltzmann's kinetic theory of gases, which led Boltzmann to a statistical approach to the kinetic theory, culminating in the development of statistical mechanics. In this paper, I show that in the (...) late nineteenth century, the reversibility problem had a much broader significance - it was widely discussed and certainly not only as an objection to Boltzmann's kinetic theory of gases. In this period, there was a conflict between mechanism and irreversibility in physics which was tied up with central issues in philosophy of science such as materialism, empiricism and the need for mechanistic foundations of physical theories, as well as with concerns about the heat death of the universe. I discuss how this conflict was handled by the major physicists of the period, such as Maxwell, Kelvin, Duhem, Poincaré, Mach and Planck, as well as by a number of lesser-known authors. (shrink)

Responding to Hasok Chang’s vision of the history and philosophy of science as the continuation of science by other means, I illustrate the methods of HPS and their utility through a historico-critical examination of the problem of “time’s arrow‘, that is to say, the problem posed by the claim by Boltzmann and others that the temporal asymmetry of many physical processes and indeed the very possibility of identifying each of the two directions we distinguish in time must have a ground (...) in the laws of nature. I claim that this problem has proved intractable chiefly because the standard mathematical representation of time employed in the formulation of the laws of nature “forgets‘ one of the connotations of the word ”time’ as it is used in ordinary language and in experimental physics. (shrink)

Information, entropy, probability: these three terms are closely interconnected in the prevalent understanding of statistical mechanics, both when this field is taught to students at an introductory level and in advanced research into the field’s foundations. This paper examines the interconnection between these three notions in light of recent research in the foundations of statistical mechanics. It disentangles these concepts and highlights their differences, at the same time explaining why they came to be so closely linked in the literature. In (...) the literature the term ‘information’ is often linked to entropy and probability in discussions of Maxwell’s Demon and its attempted exorcism by the Landauer-Bennett thesis, and in analyses of the spin echo experiments. The direction taken in the present paper is a different one. Here we discuss the statistical mechanical underpinning of the notions of probability and entropy, and this constructive approach shows that information plays no fundamental role in these concepts, although it can be conveniently used in a sense that we shall specify. (shrink)

Ludwig Boltzmann is one of the foremost responsible for the development of modern atomism in thermodynamics. His proposition was revolutionary not only because it brought a new vision for Thermodynamics, merging a statistical approach with Newtonian physics, but also because he produced an entirely new perspective on the way of thinking about and describing physical phenomena. Boltzmann dared to flirt with constructivism and realism simultaneously, by hypothesizing the reality of atoms and claiming an inherent probabilistic nature related to many particles (...) systems. Boltzmann faced criticism from the positivists, who rejected the hypothesis of the atom as a matter of principle, and also from physicists, who rejected the idea of a classical bounded system that does not follow deterministic mechanical laws. We consider that Boltzmann thermodynamics has emerged as a systemic theory that deals with macroscopic bodies using collective variables; it was reformulated to a kinetic theory of gases, and subsequently to statistical mechanics. From the theoretical physical point of view, Boltzmann advocates an approach to thermodynamics based on mechanics and was one of the founders of statistical mechanics, together with ideas by Maxwell, Clausius and Gibbs. Subsequently, statistical mechanics has also influenced the development of quantum mechanics and information theory. Using an evolutionary epistemological perspective as a metaphor to describe the physical entities claimed in Boltzmann propositions, we interpret his work as a selected theory that gained attributes of reality and “survived” during a scientific-contextual competition to be more adapted, in the sense that it was able to better explain physical phenomena, and also generated “descendants”. (shrink)

We introduce ‘model migration’ as a species of cross-disciplinary knowledge transfer whereby the representational function of a model is radically changed to allow application to a new disciplinary context. Controversies and confusions that often derive from this phenomenon will be illustrated in the context of econophysics and phylogeographic linguistics. Migration can be usefully contrasted with concept of ‘imperialism’, that has been influentially discussed in the context of geographical economics. In particular, imperialism, unlike migration, relies upon extension of the original model (...) via an expansion of the domain of phenomena it is taken to adequately described. The success of imperialism thus requires expansion of the justificatory sanctioning of the original idealising assumptions to a new disciplinary context. Contrastingly, successful migration involves the radical representational re-interpretation of the original model, rather than its extension. Migration thus requires ‘re-sanctioning’ of new ‘counterpart idealisations’ to allow application to an entirely different class of phenomena. Whereas legitimate scientific imperialism should be based on the pursuit of some form of ontological unification, no such requirement is need to legitimate the practice of model migration. The distinction between migration and imperialism will thus be shown to have significant normative as well as descriptive value. (shrink)

The celebrated Dreimännerarbeit by Born, Heisenberg and Jordan contains a matrix-mechanical derivation by Jordan of Planck’s formula for blackbody fluctuations. Jordan appears to have considered this to be one of his finest contributions to quantum theory, but the status of his derivation is puzzling. In our Dreimenschenarbeit, we show how to understand what Jordan was doing in the double context of a Boltzmannian approach to statistical mechanics and of the early ‘statistical interpretation’ of matrix mechanics.

In a recent critique of the doctrine of emergentism championed by its classic advocates up to C. D. Broad, Jaegwon Kim (Philosophical Studies 63:31–47, 1999) challenges their view about its applicability to the sciences and proposes a new account of how the opposing notion of reduction should be understood. Kim is critical of the classic conception advanced by Nagel and uses his new account in his criticism of emergentism. I question his claims about the successful reduction achieved in the sciences (...) and argue that his new account has not improved on Nagel’s and that the critique of emergentism he bases on it is question-begging in important respects. (shrink)

Econophysics is a new and exciting cross-disciplinary research field that applies models and modelling techniques from statistical physics to economic systems. It is not, however, without its critics: prominent figures in more mainstream economic theory have criticized some elements of the methodology of econophysics. One of the main lines of criticism concerns the nature of the modelling assumptions and idealizations involved, and a particular target are ‘kinetic exchange’ approaches used to model the emergence of inequality within the distribution of individual (...) monetary income. This article will consider such models in detail, and assess the warrant of the criticisms drawing upon the philosophical literature on modelling and idealization. Our aim is to provide the first steps towards informed mediation of this important and interesting interdisciplinary debate, and our hope is to offer guidance with regard to both the practice of modelling inequality, and the inequality of modelling practice. _1_ Introduction _1.1_ Econophysics and its discontents _1.2_ Against burglar economics _2_ Modelling Inequality _2.1_ Mainstream economic models for income distribution _2.2_ Econophysics models for income distribution _3_ Idealizations in Kinetic Exchange Models _3.1_ Binary interactions _3.2_ Conservation principles _3.3_ Exchange dynamics _ 4 _ Fat Tails and Savings _ 5 _ Evaluation. (shrink)

Special sciences (such as biology, psychology, economics) describe various regularities holding at some high macroscopic level. One of the central questions concerning these macroscopic regularities is how they are related to the laws of physics governing the underlying microscopic physical reality. In this paper we show how a macroscopic regularity may emerge from an underlying micro- scopic structure, and how the appearance of multiple realizability of the special sciences by physics comes about in a reductionist-physicalist framework. On this basis we (...) explain how complexity at the high level can arise due to a sort of harmony between the microscopic dynamics and observer-dependent macroscopic properties. We show that observer-dependent properties, which underlie the emergence of macroscopic properties and of macroscopic complexity, are objective physical facts. We argue that such physical properties remove the mystery from the multiple realizability of special sciences’ kinds, since the latter are grounded in shared physical properties. Finally we explain how and in what sense in our reductive physicalist approach the special sciences are still autonomous after all. (shrink)

This thesis makes the issue of reconciling the existence of thermodynamically irreversible processes with underlying reversible dynamics clear, so as to help explain what philosophers mean when they say that an aim of nonequilibrium statistical mechanics is to underpin aspects of thermodynamics. Many of the leading attempts to reconcile the existence of thermodynamically irreversible processes with underlying reversible dynamics proceed by way of discussions that attempt to underpin the following qualitative facts: (i) that isolated macroscopic systems that begin away from (...) equilibrium spontaneously approach equilibrium, and (ii) that they remain in equilibrium for incredibly long periods of time. These attempts standardly appeal to phase space considerations and notions of typicality. This thesis considers and evaluates leading typicality accounts, and, in particular, highlights their limitations. Importantly, these accounts do not underpin a large and important set of facts. They do not, for example, underpin facts about the rates in which systems approach equilibrium, or facts about the kinds of states they pass through on their way to equilibrium, or facts about fluctuation phenomena. To remedy these and other shortfalls, this thesis promotes an alternative, and arguably more important, line of research: understanding and accounting for the success of the techniques and equations physicists use to model the behaviour of systems that begin away from equilibrium. Accounting for their success would help underpin not just the qualitative facts the literature has focused on, but also many of the important quantitative facts that typicality accounts cannot. This thesis also takes steps in this promising direction. It outlines and examines a technique commonly used to model the behaviour of an interesting and important kind of system: a Brownian particle that's been introduced to an isolated homogeneous fluid at equilibrium. As this thesis highlights, the technique returns a wealth of quantitative and qualitative information. This thesis also attempts to account for the success of the model and technique, by identifying and grounding the technique's key assumptions. (shrink)

Despite all the criticism showered on Nagel’s classic account of reduction, it meets a fundamental desideratum in an analysis of reduction that is difficult to question, namely of providing for a proper identification of the reducing theory. This is not clearly accommodated in radically different accounts. However, the same feature leads me to question Nagel’s claim that the reducing theory can be separated from the putative bridge laws, and thus to question his notion of heterogeneous reduction. A further corollary to (...) the requirement that all the necessary conditions be incorporated in an adequate formulation of the putative reducing theory is that the standard example of gas temperature is not reducible to average molecular kinetic energy. As originally conceived, Nagel’s conception of reduction takes no account of approximate reasoning and this failure has certainly restricted its applicability, perhaps to the point of making it unrealistic as a model of reduction in science. I suggest approximation can be accommodated by weakening the original requirement of deduction without jeopardizing the fundamental desideratum. Finally, I turn to briefly consider the idea sometimes raised of the ontological reducibility of chemistry. (shrink)

Prompted by Hasok Chang’s conception of the history and philosophy of science (HPS) as the continuation of science by other means, I examine the possibility of obtaining scientific knowledge through philosophical criticism and reflection, in the light of four historical cases, concerning (i) the role of absolute space in Newtonian dynamics, (ii) the purported contraction of rods and retardation of clocks in Special Relativity, (iii) the reality of the electromagnetic ether, and (iv) the so-called problem of time’s arrow. In all (...) four cases it is clear that a better understanding of such matters can be achieved —and has been achieved— through conceptual analysis. On the other hand, however, it would seem that this kind of advance has more to do with philosophical questions in science than with narrowly scientific questions. Hence, if HPS in effect continues the work of science by other means, it could well be doing it for other ends than those that working scientists ordinarily have in mind. (shrink)