The "usual story" regarding molecular chemistry is that it is roughly an application of quantum mechanics. That is to say, quantum mechanics supplies everything necessary and sufficient, both ontologically and epistemologically, to reduce molecular chemistry to quantum mechanics. This is a reductive story, to be sure, but a key explanatory element of molecular chemistry, namely molecular structure, is absent from the quantum realm. On the other hand, typical characterizations of emergence, such as the unpredictability or inexplicability of molecular structure based (...) on quantum mechanics, do not characterize the relationship between molecular chemistry and quantum mechanics well either. A different scheme for characterizing reduction and emergence is proposed that accommodates the relationship between quantum mechanics and molecular chemistry and some initial objections to the scheme are considered. (shrink)

This paper considers definitions of classical dynamical chaos that focus primarily on notions of predictability and computability, sometimes called algorithmic complexity definitions of chaos. I argue that accounts of this type are seriously flawed. They focus on a likely consequence of chaos, namely, randomness in behavior which gets characterized in terms of the unpredictability or uncomputability of final given initial states. In doing so, however, they can overlook the definitive feature of dynamical chaos--the fact that the underlying motion generating the (...) behavior exhibits extreme trajectory instability. I formulate a simple criterion of adequacy for any definition of chaos and show how such accounts fail to satisfy it. (shrink)

There has been a long-standing debate about the relationship of predictability and determinism. Some have maintained that determinism implies predictability while others have maintained that predictability implies determinism. Many have maintained that there are no implication relations between determinism and predictability. This summary is, of course, somewhat oversimplified and quick at least in the sense that there are various notions of determinism and predictability at work in the philosophical literature. In this essay I will focus on what I take to (...) be the Laplacean vision for determinism and predictability. While many forms of predictability are inconsistent with this vision, I argue that a suitably restricted notion of predictability, consistent with the practice of physicists, is implied by the Laplacean notion of determinism. It is argued that limitations on predictability are of an in principle nature in the Appendix. (shrink)

Kellert (In the Wake of Chars, University of Chicago press, Chicago, 1993) has argued that Laplacean determinism in classical physics is actually a layered concept, where various properties or layers composing this form of determinism can be peeled away. Here, I argue that a layered conception of determinism is inappropriate and that we should think in terms of different deterministic models applicable to different kinds of systems. The upshot of this analysis is that the notion of state is more closely (...) tied to the kind of system being investigated than is usually considered in discussions of determinism. So when investigating determinism corresponding changes to the appropriate notion of state – and, perhaps, the state space itself – also need to be considered. (shrink)

Laplacean determinism remains a popular theory among philosophers and scientists alike, in spite of the fact that the Copenhagen Interpretation of quantum mechanics, with which it is inconsistent, has been around for more than fifty years. There are a number of reasons for its continuing popularity. One, recently articulated by Honderich, is that there are too many possible interpretations of quantum mechanics, and the subject is too controversial even among physicists to be an adequate basis for overturning determinism. Nevertheless, quantum (...) mechanics is an enormously successful theory, considering the quantity and variety of its predictions which have been verified under conditions never dreamt of by its originators; and the Copenhagen Interpretation is the only widely accepted interpretation of it. Although a hidden variable theory consistent with the results of quantum mechanics is not impossible, one of its major advocates admits that it is highly speculative, and far from adequately developed. Yet such a theory would be needed to reconcile Laplacean determinism with quantum mechanics; most of the controversies alluded to by Honderich are irrelevant. (shrink)