Along with exploring some of the necessary conditions for the chemistry of our world given what we know about quantum mechanics, I will also discuss a different reductionist challenge than is usually considered in debates on the relationship of chemistry to physics. Contrary to popular belief, classical physics does not have a reductive relationship to quantum mechanics and some of the reasons why reduction fails between classical and quantum physics are the same as for why reduction fails between chemistry and (...) quantum physics. However, a neoreductionist can accept that classical physics has some amount of autonomy from quantum mechanics, but still try to maintain that classical+quantum physics taken as a whole reduces chemistry to physics. I will explore some of the obstacles lying in the neoreductionist’s path with respect to quantum chemistry and thereby hope to shed more light on the conditions necessary for the chemistry of our world. (shrink)

Some have argued that chaos, with its characteristic feature of sensitive dependence on initial conditions, should be sensitive to quantum events (Hobbs 1991; Kellert 1993). The upshot of these arguments is that classical chaos would then be indeterministic, but such a conclusion is dependent on which versions of quantum theory and solutions to the measurement problem are adopted (Bishop and Kronz 1999). In this essay, the relationship between quantum mechanics and sensitive dependence is placed in the general context of nonlinear (...) dynamics and is investigated in detail, revealing further limitations and quali…cations on these sensitive dependence arguments. (shrink)

The discovery of sensitive dependence on initial conditions (SDIC) in nonlinear models runs counter to the textbook vision of CM, a vision guided by an almost exclusive focus on linear systems. Therefore, it is important to clearly distinguish between linear and nonlinear systems along with establishing some basic terminology (§I). The notions of SDIC and chaos also need clarification, since they play crucial roles in sensitive dependence (SD) arguments. This will require some discussion of Lyapunov exponents as well as the (...) relationship between nonlinear dynamics and chaos (§II and Appendix). For the sake of concreteness, it will also be useful to focus on the Laplacean vision for classical particle mechanics (e.g., Bishop 2002b, 2003 and 2005a), particularly the crucial notion of unique evolution (§III). The SD argument can then be stated in a clear form and its defenses, criticisms and limitations assessed in the more general context of nonlinear dynamics (§IV). Concluding remarks follow (§V). (shrink)

Recent developments in nonlinear dynamics have found wide application in many areas of science from physics to neuroscience. Nonlinear phenomena such as feedback loops, inter-level relations, wholes constraining and modifying the behavior of their parts, and memory effects are interesting candidates for emergence and downward causation. Rayleigh–Bénard convection is an example of a nonlinear system that, I suggest, yields important insights for metaphysics and philosophy of science. In this paper I propose convection as a model for downward causation in classical (...) mechanics, far more robust and less speculative than the examples typically provided in the philosophy of mind literature. Although the physics of Rayleigh–Bénard convection is quite complicated, this model provides a much more realistic and concrete example for examining various assumptions and arguments found in emergence and philosophy of mind debates. After reviewing some key concepts of nonlinear dynamics, complex systems and the basic physics of Rayleigh–Bénard convection, I begin that examination here by (1) assessing a recently proposed definition for emergence and downward causation, (2) discussing some typical objections to downward causation and (3) comparing this model with Sperry’s examples. (shrink)

Contextual emergence was originally proposed as an inter-level relation between different levels of description to describe an epistemic notion of emergence in physics. Here, we discuss the ontic extension of this relation to different domains or levels of physical reality using the properties of temperature and molecular shape as detailed case studies. We emphasize the concepts of stability conditions and multiple realizability as key features of contextual emergence. Some broader implications contextual emergence has for the foundations of physics and cognitive (...) and neural sciences are given in the concluding discussion. Relevant facts about algebras of observables are found in the appendices along with an abstract definition of Kubo-Martin-Schwinger states. (shrink)

A los cristales se los describe como a una red de átomos que puede vibrar alrededor de su posición de equilibrio. Sin embargo, el hecho de que la energía de estas ondas esté cuantificada sugiere una analogía con el campo electromagnético. En analogía con el fotón se define al fonón. Generalmente se concibe al fonón como a una cuasi-partícula, es decir, como a un instrumento matemático útil en los cálculos pero sin una existencia propia. En este trabajo estudiamos el estatuto (...) ontológico del fonón y argumentaremos en favor de la idea de considerarlo como una partícula real. (shrink)

Physics and chemistry underlie the nature of all the world around us, including human brains. Consequently some suggest that in causal terms, physics is all there is. However, we live in an environment dominated by objects embodying the outcomes of intentional design (buildings, computers, teaspoons). The present day subject of physics has nothing to say about the intentionality resulting in existence of such objects, even though this intentionality is clearly causally effective. This paper examines the claim that the underlying physics (...) uniquely causally determines what happens, even though we cannot predict the outcome. It suggests that what occurs is the contextual emergence of complexity: the higher levels in the hierarchy of complexity have autonomous causal powers, functionally independent of lower level processes. This is possible because top-down causation takes place as well as bottom-up action, with higher level contexts determining the outcome of lower level functioning and even modifying the nature of lower level constituents. Stored information plays a key role, resulting in non-linear dynamics that is non-local in space and time. Brain functioning is causally affected by abstractions such as the value of money and the theory of the laser. These are realised as brain states in individuals, but are not equivalent to them. Consequently physics per se cannot causally determine the outcome of human creativity, rather it creates the possibility space allowing human intelligence to function autonomously. The challenge to physics is to develop a realistic description of causality in truly complex hierarchical structures, with top-down causation and memory effects allowing autonomous higher levels of order to emerge with genuine causal powers. (shrink)

This book explores whether physics points to a reductive or an emergent structure of the world and proposes a physics-motivated conception of emergence that leaves behind many of the problematic intuitions shaping the philosophical conceptions. Examining several detailed case studies reveals results that point to stability conditions playing a crucial though underappreciated role in the physics of emergence. This contextual emergence has thought-provoking consequences for physics and beyond.

Nonreductive physicalism faces serious problems regarding causal exclusion, causal heterogeneity, and the nature of realization. In this paper I advance solutions to each of those problems. The proposed solutions all depend crucially on embracing modal counterpart theory. Hence, the paper’s thesis: counterpart theory saves nonreductive physicalism. I take as my inspiration the view that mental tokens are constituted by physical tokens in the same way statues are constituted by lumps of clay. I break from other philosophers who have pursued this (...) line, however, in that I hold that constitution is identity. Much of the value of the comparison to statues and lumps is that it calls to mind the resources used to defend constitution-as-identity, most notably that of counterpart theory. Along the way, I discuss the virtues of a trope ontology, modal objections to token identity theories, the prospects of conditional analyses of causal powers, the subset account of realization, and the grounding problem. I also endorse a novel, empirical argument in favor of counterpart theory. (shrink)

The aim of the present paper is to analyze the problem of the relationship between chemistry and physics, by focusing on the widely discussed case of the atomic orbitals. We will begin by remembering the difference between the physical and the chemical interpretation of the concept of orbital. Then, we will refer to the claim made in 1999 that atomic orbitals have been directly imaged for the first time. On this basis, we will analyze the problem from a new approach, (...) by comparing the concept of orbital used in physics with the concept of orbital used in chemistry. Such an analysis will allow us to argue for an ontological pluralism that admits the coexistence of different ontologies without priorities or metaphysical privileges. From this philosophical framework, the concepts of chemical orbital and physical orbital correspond to two different ontologies. As a consequence, chemical orbitals are real entities belonging to the ontology of molecular chemistry, and can be observed like any other entity not belonging to the quantum mechanical ontology. DOI:10.5007/1808-1711.2010v14n3p309. (shrink)

Complexity arises from interaction dynamics, but its forms are co-determined by the operative constraints within which the dynamics are expressed. The basic interaction dynamics underlying complex systems is mostly well understood. The formation and operation of constraints is often not, and oftener under appreciated. The attempt to reduce constraints to basic interaction fails in key cases. The overall aim of this paper is to highlight the key role played by constraints in shaping the field of complex systems. Following an introduction (...) to constraints, the paper develops the roles of constraints in specifying forms of complexity and illustrates the roles of constraints in formulating the fundamental challenges to understanding posed by complex systems. (shrink)

Mental and neural states are related to one another by vertical interlevel relations and by horizontal intralevel relations. For particular choices of such relations, problems arise if causal efficacy is ascribed to mental states. In a series of influential papers and books, Kim has presented his much discussed “supervenience argument,” which ultimately amounts to the dilemma that mental states either are causally inefficacious or they hold the threat of overdetermining neural states. Forced by this disjunction, Kim votes in favor of (...) overdetermination and, ultimately, reduction. We propose a perspective on mental causation that dissolves the assumption of a tension between horizontal and vertical determination. For mental states to be causally efficacious, they must be dynamically stable. This important requirement can be implemented by combining a key idea of supervenience, multiple realization, with the recently introduced vertical interlevel relation of contextual emergence. Both together deflate Kim's dilemma and reflate the causal efficacy of mental states. 2012 APA, all rights reserved). (shrink)

Perhaps the hottest topic in the philosophy of chemistry is that of the relationship between chemistry and physics. The problem finds one of its main manifestations in the debate about the nature of molecular structure, given by the spatial arrangement of the nuclei in a molecule. The traditional strategy to address the problem is to consider chemical cases that challenge the definition of molecular structure in quantum–mechanical terms. Instead of taking that top-down strategy, in this paper we face the problem (...) of the reduction of molecular structure to quantum mechanics from a bottom-up perspective: our aim is to show how the theoretical peculiarities of quantum mechanics stand against the possibility of molecular structure, defined in terms of the spatial relations of the nuclei conceived as individual localized objects. We will argue that, according to the theory, quantum “particles” are not individuals that can be identified as different from others and that can be reidentified through time; therefore, they do not have the ontological stability necessary to maintain the relations that can lead to a spatially definite system with an identifiable shape. On the other hand, although quantum chemists use the resources supplied by quantum mechanics with successful results, this does no mean reduction: their “approximations” add certain assumptions that are not justified in the context of quantum mechanics or are even inconsistent with the very formal structure of the theory. (shrink)

The modal-Hamiltonian interpretation belongs to the modal family of interpretations of quantum mechanics. By endowing the Hamiltonian with the role of selecting the subset of the definite-valued observables of the system, it accounts for ideal and non-ideal measurements, and also supplies a criterion to distinguish between reliable and non-reliable measurements in the non-ideal case. It can be reformulated in an explicitly invariant form, in terms of the Casimir operators of the Galilean group, and the compatibility of the MHI with the (...) theory of decoherence has been proved. Nevertheless, perhaps its main advantage in the eyes of a scientist is given by its several applications to well-known physical situations, leading to results compatible with experimental evidence. The purpose of this paper is to add a new application to the list: the case of optical isomerism, which is a central issue for the philosophy of physics and of chemistry since it points to the core of the problem of the relationship between physics and chemistry. Here it will be shown that the MHI supplies a direct and physically natural solution to the problem, a solution that does not require putting classical assumptions in “by hand.”. (shrink)

There has been much controversy over weak and strong emergence in physics and biology. As pointed out by Phil Anderson in many papers, the existence of broken symmetries is the key to emergence of properties in much of solid state physics. By carefully distinguishing between different types of symmetry breaking and tracing the relation between broken symmetries at micro and macro scales, I demonstrate that the emergence of the properties of semiconductors is a case of strong emergence. This is due (...) to the existence of quasiparticles such as phonons. Furthermore time dependent potentials enable downward causation as in the case of digital computers. Additionally I show that the processes of evolutionary emergence of living systems is also a case of strong emergence, as is the emergence of properties of life out of the underlying physics. A useful result emerges: standard physics theories and the emergent theories arising out of them are all effective theories that are equally valid. (shrink)

Intra-molecular connectivity (that is, chemical structure) does not emerge from computations based on fundamental quantum-mechanical principles. In order to compute molecular electronic energies (of C 3 H 4 hydrocarbons, for instance) quantum chemists must insert intra-molecular connectivity “by hand.” Some take this as an indication that chemistry cannot be reduced to physics: others consider it as evidence that quantum chemistry needs new logical foundations. Such discussions are generally synchronic rather than diachronic —that is, they neglect ‘historical’ aspects. However, systems of (...) interest to chemists generally are metastable . In many cases chemical systems of a given elemental composition may exist in any one of several different metastable states depending on the history of the system. Molecular structure generally depends on contingent historical circumstances of synthesis and separation, rather than solely or mainly on relative energies of alternative stable states, those energies in turn determined by relationships among components. Chemical structure is usually ‘kinetically-determined’ rather than ‘thermodynamically-determined.’ For instance, cyclical hydrocarbon ring-systems (as in cyclopropene) are produced only in special circumstances. Adequate theoretical treatments must take account of the persistent effects of such contingent historical events whenever they are relevant—as they generally are in chemistry. (shrink)

Neste artigo, discuto o problema das propriedades emergentes, começando por apresentar uma concepção tradicional de acordo com a qual estas propriedades exibem três características definidoras: elas dependem de propriedades e relações físicas, mas constituem, em relação a estas, uma novidade e, como tal, não são delas deduzíveis. Em primeiro lugar, discuto algumas das razões gerais que explicam o facto de tradicionalmente se supor que este tipo de novidade – e.g. causal ou qualitativa – parece exigir que as propriedades emergentes não (...) se encontram, de todo, fisicamente fundadas, não podendo ser deduzidas das suas bases físicas. Portanto, a dependência física das propriedades emergentes não pode ser explicada, o que é normalmente tido como misterioso. Recorrendo a uma concepção funcionalista de dedutibilidade, discuto de seguida, com mais detalhe, a relação entre a novidade e a não-dedutibilidade, realçando o modo como os diferentes tipos de não-dedutibilidade conduzem a diferentes tipos de novidade e, como tal, a diferentes formas de emergência. Finalmente, considero algumas abordagens científicas modernas que rejeitam a não-dedutibilidade enquanto condição necessária da emergência. Segundo tais abordagens, o tipo de novidade associado às propriedades emergentes é compatível com uma fundação física, o que, por sua vez, faz desvanecer o mistério e confere respeitabilidade científica à noção de emergência. Concluirei estabelecendo comparações entre estas abordagens e o hilomorfismo neo-Aristotélico. (shrink)

Recent discussions about the microstructure of materials generally focus on the ontological aspects of the molecular structure. However, there are many types of substances that cannot be studied by means of the concept of molecule, for example, salts. For the quantum treatment of these substances, a new particle, called phonon, is introduced. Phonons are generally conceived as a pseudo-particle, that is, a mathematical device necessary to perform calculations but which does not have a "real" existence. In this context, the aim (...) of this paper will be to analyze the ontological status of phonons. For such purposes we will critically analyze the arguments that would account for the presumed nonexistence of phonons. Finally, having already demonstrated that there are not enough reasons to consider phonons as non-existing entities, we will explore some possibilities that allow us to elucidate their ontological status. (shrink)

Despite its recent popularity, Emergence is still a field where philosophers and physicists often talk past each other. In fact, while philosophical discussions focus mostly on ontological emergence, physical theory is inherently limited to the epistemological level and the impossibility of its conclusions to provide direct evidence for ontological claims is often underestimated. Nevertheless, the emergentist philosopher’s case against reductionist theories of how the different levels of reality are related to each other can still gain from the assessment of paradigmatic (...) examples of discontinuity between models in physics, even though their implications must be handled with care. (shrink)

Though some influentially critical objections have been raised during the ‘classical’ pre-computational simulation philosophy of science tradition, suggesting a more nuanced methodological category for experiments, it safe to say such critical objections have greatly proliferated in philosophical studies dedicated to the role played by computational simulations in science. For instance, Eric Winsberg suggests that computer simulations are methodologically unique in the development of a theory’s models suggesting new epistemic notions of application. This is also echoed in Jeffrey Ramsey’s notions of (...) “transformation reduction,”—i.e., a notion of reduction of a more highly constructive variety. Computer simulations create a broadly continuous arena spanned by normative and descriptive aspects of theory-articulation, as entailed by the notion of transformation reductions occupying a continuous region demarcated by Ernest Nagel’s logical-explanatory “domain-combining reduction” on the one hand, and Thomas Nickels’ heuristic “domain-preserving reduction,” on the other. I extend Winsberg’s and Ramsey’s points here, by arguing that in the field of computational fluid dynamics as well as in other branches of applied physics, the computer plays a constitutively experimental role—supplanting in many cases the more traditional experimental methods such as flow-visualization, etc. In this case, however CFD algorithms act as substitutes, not supplements when it comes to experimental practices. I bring up the constructive example involving the Clifford-Algebraic algorithms for modeling singular phenomena in CFD by Gerik Scheuermann and Steven Mann & Alyn Rockwood who demonstrate that their algorithms offer greater descriptive and explanatory scope than the standard Navier-Stokes approaches. The mathematical distinction between Navier-Stokes-based and Clifford-Algebraic based CFD has essentially to do with the regularization features exhibited to a far greater extent by the latter, than the former. Hence, CACFD indicate that the utilization of computational techniques can be based on principled reasons, as opposed to merely practical. CACFD hence exhibit a new generative role in the field of fluid mechanics, by offering categories of experimental evidence that are optimally descriptive and explanatory—i.e., pace Batterman can be both ontologically and epistemically fundamental. (shrink)

Philosophers have long debated ‘substrate’ and ‘bundle’ theories as to how properties hold together in objects ― but have neglected to consider that every chemical entity is defined by closure of relationships among components ― here designated ‘Closure Louis de Broglie.’ That type of closure underlies the coherence of spectroscopic and chemical properties of chemical substances, and is importantly implicated in the stability and definition of entities of many other types, including those usually involved in philosophic discourse ― such as (...) roses, statues, and tennis balls. Characteristics of composites are often presumed to ‘supervene on’ properties of components. This assumption does not apply when cooperative interactions among components are significant. Once correlations dominate, then adequate descriptions must involve different entities and relationships than those that are involved in ‘fundamental-level’ description of similar but uncorrelated systems. That is to say, descriptions must involve different semantics than would be appropriate if cooperative interactions were insignificant. This is termed ‘Closure Henri Poincaré. Networks of chemical reactions that have certain types of closure of processes display properties that make other more-complex coherences possible. This is termed ‘Closure Jacques Cauvin.’ Each of these three modes of closure provides a sufficient basis for warranted recognition of causal interaction, thus each of them has epistemological significance. Other modes of epistemologically-important closure probably exist. It is important to recognize that causal efficacy generally depends on closure of relationships of constituents. (shrink)

I argue that the distinctions Robert Batterman (2004) presents between ‘epistemically fundamental’ versus ‘ontologically fundamental’ theoretical approaches can be subsumed by methodologically fundamental procedures. I characterize precisely what is meant by a methodologically fundamental procedure, which involves, among other things, the use of multilinear graded algebras in a theory’s formalism. For example, one such class of algebras I discuss are the Clifford (or Geometric) algebras. Aside from their being touted by many as a “unified mathematical language for physics,” (Hestenes (1984, (...) 1986) Lasenby, et. al. (2000)) Finkelstein (2001, 2004) and others have demonstrated that the techniques of multilinear algebraic ‘expansion and contraction’ exhibit a robust regularizablilty. That is to say, such regularization has been demonstrated to remove singularities, which would otherwise appear in standard field-theoretic, mathematical characterizations of a physical theory. I claim that the existence of such methodologically fundamental procedures calls into question one of Batterman’s central points, that “our explanatory physical practice demands that we appeal essentially to (infinite) idealizations” (2003, 7) exhibited, for example, by singularities in the case of modeling critical phenomena, like fluid droplet formation. By way of counterexample, in the field of computational fluid dynamics (CFD), I discuss the work of Mann & Rockwood (2003) and Gerik Scheuermann, (2002). In the concluding section, I sketch a methodologically fundamental procedure potentially applicable to more general classes of critical phenomena appearing in fluid dynamics. (shrink)

This paper understands reductionism as a relation between explanations, not theories. It argues that knowledge of the micro-level behavior of the components of systems is necessary, but only combined with a full specification of the contingent context sufficient for a full explanation of systems phenomena. The paper takes seriously fundamental principles independent and transcendent of the laws of quantum mechanics that govern most of real-world phenomena. It will conclude in showing how the recent postgenomic revolution, taking seriously the physical principle (...) of organization and collective behavior, can be understood as attempting to complement a reductionist investigative strategy with an antireductionist explanatory strategy. (shrink)

Complexity–nonlinear dynamics for my purposes in this essay–is rich with metaphysical and epistemological implications but is only recently receiving sustained philosophical analysis. I will explore some of the subtleties of causation and constraint in Rayleigh-Bénard convection as an example of a complex phenomenon, and extract some lessons for further philosophical reflection on top-down constraint and causation particularly with respect to causal foundationalism.