In their paper "Why Gibbs Phase Averages Work--The Role of Ergodic Theory" (1980), David Malament and Sandy Zabell attempt to explain why phase averaging over the microcanonical ensemble gives correct predictions for the values of thermodynamic observables, for an ergodic system at equilibrium. Their idea is to bypass the traditional use of limit theorems, by relying on a uniqueness result about the microcanonical measure--namely, that it is uniquely stationary translation-continuous. I argue that their explanation begs questions about the relationship between (...) thermodynamic equilibrium and statistical equilibrium; I argue in addition that any account which supports their view of the relationship between these two notions of equilibrium will likely use the limit theorems in traditional ways, and thereby bypass the explanation they offer. (shrink)

1929. The course of Gifford Lectures that Eddington delivered in the University of Edinburgh in January to March 1927.

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

In this first part of a two-part paper, we describe efforts in the early decades of this century to restrict the extent of violations of the Second Law of thermodynamics that were brought to light by the rise of the kinetic theory and the identification of fluctuation phenomena. We show how these efforts mutated into Szilard’s proposal that Maxwell’s Demon is exorcised by proper attention to the entropy costs associated with the Demon’s memory and information acquisition. In the second part (...) we will argue that the information theoretic exorcisms of the Demon provide largely illusory benefits. According to the case, they either return a presupposition that can be had without information theoretic consideration or they postulate a broader connection between information and entropy than can be sustained. (shrink)

The aim of this article is to analyse the relation between the second law of thermodynamics and the so-called arrow of time. For this purpose, a number of different aspects in this arrow of time are distinguished, in particular those of time-reversal (non-)invariance and of (ir)reversibility. Next I review versions of the second law in the work of Carnot, Clausius, Kelvin, Planck, Gibbs, Caratheodory and Lieb and Yngvason, and investigate their connection with these aspects of the arrow of time. It (...) is shown that this connection varies a great deal along with these formulations of the second law. According to the famous formulation by Planck, the second law expresses the irreversibility of natural processes. But in many other formulations irreversibility or even time-reversal non-invariance plays no role. I therefore argue for the view that the second law has nothing to do with the arrow of time. (shrink)