This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

It is argued that certain recent advances in the construction of a theory of the collapses of Quantum Mechanical wave functions suggest the possibility of new and improved foundations for statistical mechanics, foundations in which epistemic considerations play no role.

We introduce a simple model for so-called spin-echo experiments. We show that the model is a mincing system. On the basis of this model we study fine-grained entropy and coarse-grained entropy descriptions of these experiments. The coarse-grained description is shown to be unable to provide an explanation of the echo signals, as a result of the way in which it ignores dynamically generated correlations. This conclusion is extended to the general debate on the foundations of statistical mechanics. We emphasize the (...) need for an appropriate mechanism to explain the gradual suppression over time of the correlations in a thermodynamic system. We argue that such a mechanism can only be provided by the interventionist approach, in which the interaction of the system with its environment is taken into account. Irreversible behavior is then seen to arise not as a result of limited measurement accuracy , but as a result of the fact that thermodynamic systems are limited systems which interact with their environment. A detailed discussion is given of recent objections to the interventionist approach in the literature. (shrink)

We discuss a recent proposal by Albert (1994a; 1994b; 2000, ch. 7) to recover thermodynamics on a purely dynamical basis, using the quantum theory of the collapse of the wave function by Ghirardi, Rimini, and Weber (1986). We propose an alternative way to explain thermodynamics within no-collapse interpretations of quantum mechanics. Our approach relies on the standard quantum mechanical models of environmental decoherence of open systems (e.g., Joos and Zeh 1985; Zurek and Paz 1994). This paper presents the two approaches (...) and discusses their advantages. The problems faced by both approaches will be discussed in a sequel (Hemmo and Shenker 2003). (shrink)

Can we explain the laws of thermodynamics, in particular the irreversible increase of entropy, from the underlying quantum mechanical dynamics? Attempts based on classical dynamics have all failed. Albert (1994a,b; 2000) proposed a way to recover thermodynamics on a purely dynamical basis, using the quantum theory of the collapse of the wavefunction of Ghirardi, Rimini and Weber (1986). In this paper we propose an alternative way to explain thermodynamics within no-collapse interpretations of quantum mechanics. Our approach relies on the standard (...) quantum mechanical models of environmental decoherence of open systems, e.g. Joos and Zeh (1985) and Zurek and Paz (1994). (shrink)

An important contemporary version of Boltzmannian statistical mechanics explains the approach to equilibrium in terms of typicality. The problem with this approach is that it comes in different versions, which are, however, not recognized as such and not clearly distinguished. This article identifies three different versions of typicality‐based explanations of thermodynamic‐like behavior and evaluates their respective successes. The conclusion is that the first two are unsuccessful because they fail to take the system's dynamics into account. The third, however, is promising. (...) I give a precise formulation of the proposal and present an argument in support of its central contention. †To contact the author, please write to: Department of Philosophy, Logic, and Scientific Method, London School of Economics, Houghton Street, London WC2A 2AE, England; e‐mail: [email protected]. (shrink)