In 1904 Joachim published an influential paper dealing with 'Aristotle's Conception of Chemical Combination' which has provided the basis of much more recent studies. About the same time, Duhem developed what he regarded as an essentially Aristotelian view of chemistry, based on his understanding of phenomenological thermodynamics. He does not present a detailed textual analysis, but rather emphasises certain general ideas. Joachim's classic paper contains obscurities which I have been unable to fathom and theses which do not seem to be (...) fully explained, or which at least seem difficult for the modern reader to understand. An attempt is made here to provide a systematic account of the Aristotelian theory of the generation of substances by the mixing of elements by reconsidering Joachim's treatment in the light of the sort of points which most interested Duhem.The work described in this paper was undertaken with a view to providing a basis for presenting, evaluating and criticising Duhem's understanding of what was for him modern chemistry. This latter project will be taken up on another occasion. I hope the present paper will be of some value to a broader philosophical readership in so far as it provides a fairly clear conception of matter which might be called Aristotelian, even if it is not precisely Aristotle's, and raises certain clear problems of interpretation. It may also be of interest to historians of chemistry in suggesting an analysis of the old chemical notion of a mixt independent of atomic theories. (shrink)

Sans proposer une simple histoire de la chimie, cet ouvrage de Gaston Bachelard se propose de developper, a l'occasion des progres de la chimie moderne, une lecture philosophique de cette evolution, autour d'une idee articulant dialectiquement deux directions distinctes : la pensee du chimiste semble osciller entre le pluralisme d'une part et la reduction de la pluralite d'autre part. C'est dire que Bachelard se propose ici de caracteriser le soubassement philosophique de la pensee epistemologique promue par la recente evolution de (...) la chimie moderne. Si la decouverte scientifique est liee, dans le cas de la chimie, a la mise au jour de nouvelles substances, et ainsi au developpement d'un pluralisme des substances, la tache du philosophe consiste des lors a montrer que derriere tout pluralisme on peut reconnaitre un systele de coherence. C'est cette these majeure que deploie cet ouvrage dans une progression qui, du probleme philosophique du divers, mene, en passant par une analyse detaillee de l'apport considerable de Mendeleiev a la chimie moderne, a l'idee philosophique d'une harmonie substantielle. (shrink)

I argue and demonstrate in this essay that interconnected systems of science and technology, or technoscience, existed long before the late nineteenth century, and that eighteenth-century chemistry was such an early form of technoscience. Based on recent historical research on the early development of carbon chemistry from the late 1820s until the 1840s—which revealed that early carbon chemistry was an experimental expert culture that was largely detached from the mundane industrial world—I further examine the question of the internal preconditions within (...) the expert culture of carbon chemistry that contributed to its convergence with the synthetic-dye industry in the late 1850s. I argue that the introduction of new types and techniques of organic-chemical reactions and organic substances in this experimental expert culture, along with the application of chemical formulae as paper tools for modeling reactions as well as the chemical constitution and structure of substances, enabled academic chemists to make specific, novel contributions to chemical technology and industry in the second half of the nineteenth century. (shrink)

Comment penser les nouvelles technologies? Après avoir enquêté dans plusieurs entreprises, Bernadette Bensaude-Vincent met à jour une vérité paradoxale : le meilleur moyen d'élaborer la philosophie des matériaux nouveaux est de reprendre les interrogations fondatrices de la pensée antique et, notamment, la notion de mixte qui permettait de comprendre ensemble, l'unité et la variété, le même et l'autre. En effet, les nouveaux matériaux (composites à fibres de carbone, kevlar, etc.) requièrent des techniques de conception et de fabrication inédites qui mélangent (...) des éléments hétérogènes sur le modèle du monde vivant. Cette originale confrontation entre le monde industriel d'aujourd'hui et la philosophie ancienne invite le lecteur à repenser la nature et l'artifice, à reconsidérer le mixte, au-delà d'une pensée pauvre de l'identique et du différent. (shrink)

In diesem Beitrag lege ich dar, dass in der zweiten Hälfte des 20. Jahrhunderts das Konzept von Werkstoffen (materials) als charakteristischer ontologischer Typus eines neuen Forschungs- und Wissenschaftsstils aufkam. Das soll nicht heißen, dass Werkstoffe niemals zuvor wissenschaftlich bearbeitet worden wären. Zweifellos hatten sich zahlreiche wissenschaftliche Disziplinen mit den Eigenschaften einer ganzen Reihe von Werkstoffen befasst. Doch wurden dabei Werkstoffe nicht als generische, also alle Arten von Stoffen umfassende, Entität betrachtet.Ziel dieses Aufsatzes ist zu verstehen, wie Werkstoffe als Gattungseinheit entstanden (...) sind und zu Objekten einer Wissenschaft wurden, die so unterschiedliche Dinge wie Papier, Holz, Metalle, Beton, Keramik, Polymere, Halbleiter und Kohlenstoff-Nanoröhren umfasst. Im Bemühen, die historischen Begleitumstände des Auftretens von Werkstoffen zu bestimmen, werde ich diese zunächst in historischer und ontologischer Hinsicht einordnen. Wie war es möglich, all diese Dinge in einer einzigen Gattung zu vereinigen? Dann wende ich mich dem sich verändernden Status von Werkstoffen zu, ein Resultat der erfolgreichen Materialforschung. Werkstoffe sind nicht länger die Vorbedingungen, die dem Entwurfsprozess Beschränkungen auferlegen, sondern werden nun selbst spezifisch entworfen. Solche materials by design sind echte, individuell zugeschnittene Schöpfungen und nicht nur einfach Handelsprodukte. Zudem birgt der Wandel ihres ontologischer Status ein Paradox mit seiner Tendenz zur Entmaterialisierung von Technik. (shrink)

William Newman construes the Scientific Revolution as a change in matter theory, from a hylomorphic, Aristotelian to a corpuscular, mechanical one. He sees Robert Boyle as making a major contribution to that change by way of his corpuscular chemistry. In this article it is argued that it is seriously misleading to identify what was scientific about the Scientific Revolution in terms of a change in theories of the ultimate structure of matter. Boyle showed, especially in his pneumatics, how empirically accessible, (...) intermediate causes, as opposed to ultimate, mechanical ones can be explored and identified by experiment. Newman is right to observe that Boyle constantly sought intimate links between chemistry and the mechanical philosophy. However, by doing so he did not thereby significantly aid the cause of attaining experimental knowledge of chemical phenomena and the support that Boyle’s chemistry provided for the mechanical philosophy was weaker than both Boyle and Newman imply. Boyle was intent on articulating and defending a strict, mechanical account of the ultimate structure of matter to be sure, but his contributions to the new experimental science in general, and chemistry in particular, are best seen as distinct from that endeavour.Keywords: Chemistry; Mechanical philosophy; Corpuscular philosophy; Experiment; Robert Boyle; William Newman. (shrink)

In a publication of 1831 later seen as a milestone in the development of chemistry, Justus Liebig announced a new apparatus for the analysis of organic compounds and provided analytical results for fifteen substances. In this paper we used the detailed descriptions published by Liebig in 1837 to reconstruct his apparatus and methods for hydrogen, carbon and nitrogen analysis. Our replications of his analyses of racemic acid, cinchonine, narcotine, and urea reveal that his two pieces of apparatus give excellent results (...) for carbon and hydrogen content, but erratic results for nitrogen. The results corroborate the assessments of Liebig and his contemporaries, and show that the analytical method for carbon and hydrogen analysis was remarkably accurate. We offer this case, with its convincing replicability, not only to clarify the nature of Liebig's innovations, but also as a new model for understanding broader contested issues in the philosophy and sociology of science. Our analysis suggests that the great shift in science from gentlemanly avocation to professional vocation was tightly linked to laboratory practice, and not just to social networks and context. It also provides the basis for a critique of H. M. Collins's theory of the 'experimenters' regress'. (shrink)

"Entre la connaissance commune et la connaissance scientifique, la rupture nous paraît si nette que ces deux types de connaissance ne sauraient avoir la même philosophie. L'empirisme est la philosophie qui convient à la connaissance commune. Au contraire, la connaissance scientifique est solidaire du rationalisme et, qu'on le veuille ou non, le rationalisme est lié à la science, le rationalisme réclame des buts scientifiques. Par l'activité scientifique, le rationalisme connaît une activité dialectique qui enjoint une extension constante des méthodes". Voici (...) un livre sur l'activité rationaliste du chimiste contemporain. On y voit à l'oeuvre une "phénoménotechnique" qui construit ses multiples substances en éliminant progressivement l'irrationnel. Souligner l'engagement de pensée qui se manifeste dans cette activité, telle est la volonté de Bachelard inscrite dans son projet général d'attirer "l'attention des philosophes sur le caractère spécifique de la pensée et du travail de la science moderne". (shrink)