This chapter will review selected aspects of the terrain of discussions about probabilities in statistical mechanics (with no pretensions to exhaustiveness, though the major issues will be touched upon), and will argue for a number of claims. None of the claims to be defended is entirely original, but all deserve emphasis. The first, and least controversial, is that probabilistic notions are needed to make sense of statistical mechanics. The reason for this is the same reason that convinced Maxwell, Gibbs, and (...) Boltzmann that probabilities would be needed, namely, that the second law of thermodynamics, which in its original formulation says that certain processes are impossible, must, on the kinetic theory, be replaced by a weaker formulation according to which what the original version deems impossible is merely improbable. Second is that we ought not take the standard measures invoked in equilibrium statistical mechanics as giving, in any sense, the correct probabilities about microstates of the system. We can settle for a much weaker claim: that the probabilities for outcomes of experiments yielded by the standard distributions are effectively the same as those yielded by any distribution that we should take as a representing probabilities over microstates. Lastly, (and most controversially): in asking about the status of probabilities in statistical mechanics, the familiar dichotomy between epistemic probabilities (credences, or degrees of belief) and ontic (physical) probabilities is insufficient; the concept of probability that is best suited to the needs of statistical mechanics is one that combines epistemic and physical considerations. (shrink)

It is proposed that we use the term “approximation” for inexact description of a target system and “idealization” for another system whose properties also provide an inexact description of the target system. Since systems generated by a limiting process can often have quite unexpected, even inconsistent properties, familiar limit systems used in statistical physics can fail to provide idealizations, but are merely approximations. A dominance argument suggests that the limiting idealizations of statistical physics should be demoted to approximations.

This is one of two papers about emergence, reduction and supervenience. It expounds these notions and analyses the general relations between them. The companion paper analyses the situation in physics, especially limiting relations between physical theories. I shall take emergence as behaviour that is novel and robust relative to some comparison class. I shall take reduction as deduction using appropriate auxiliary definitions. And I shall take supervenience as a weakening of reduction, viz. to allow infinitely long definitions. The overall claim (...) of this paper will be that emergence is logically independent both of reduction and of supervenience. In particular, one can have emergence with reduction, as well as without it; and emergence without supervenience, as well as with it. Of the subsidiary claims, the four main ones are: : I defend the traditional Nagelian conception of reduction ; : I deny that the multiple realizability argument causes trouble for reductions, or ``reductionism'' ; : I stress the collapse of supervenience into deduction via Beth's theorem ; : I adapt some examples already in the literature to show supervenience without emergence and vice versa. (shrink)

This paper looks at emergence in physical theories and argues that an appropriate way to understand socalled “emergent protectorates” is via the explanatory apparatus of the renormalization group. It is argued that mathematical singularities play a crucial role in our understanding of at least some well-defined emergent features of the world.

Professor Hilary Putnam has been one of the most influential and sharply original of recent American philosophers in a whole range of fields. His most important published work is collected here, together with several new and substantial studies, in two volumes. The first deals with the philosophy of mathematics and of science and the nature of philosophical and scientific enquiry; the second deals with the philosophy of language and mind. Volume one is now issued in a new edition, including an (...) essay on the philosophy of logic first published in 1971. (shrink)

Approaches to explanation -- Causal and explanatory relevance -- The kairetic account of /D making -- The kairetic account of explanation -- Extending the kairetic account -- Event explanation and causal claims -- Regularity explanation -- Abstraction in regularity explanation -- Approaches to probabilistic explanation -- Kairetic explanation of frequencies -- Kairetic explanation of single outcomes -- Looking outward -- Looking inward.

Robert Batterman examines a form of scientific reasoning called asymptotic reasoning, arguing that it has important consequences for our understanding of the scientific process as a whole. He maintains that asymptotic reasoning is essential for explaining what physicists call universal behavior. With clarity and rigor, he simplifies complex questions about universal behavior, demonstrating a profound understanding of the underlying structures that ground them. This book introduces a valuable new method that is certain to fill explanatory gaps across disciplines.

This paper examines the justifications for using infinite systems to 'recover' thermodynamic properties, such as phase transitions (PT), critical phenomena (CP), and irreversibility, from the micro-structure of matter in bulk. Section 2 is a summary of such rigorous methods as in taking the thermodynamic limit (TL) to recover PT and in using renormalization (semi-) group approach (RG) to explain the universality of critical exponents. Section 3 examines various possible justifications for taking TL on physically finite systems. Section 4 discusses the (...) legitimacy of applying TL to the problem of irreversibility and assesses the repercussions for its legitimacy on its home turf. (shrink)

Thermodynamics and Statistical Mechanics are related to one another through the so-called "thermodynamic limit'' in which, roughly speaking the number of particles becomes infinite. At critical points (places of physical discontinuity) this limit fails to be regular. As a result, the "reduction'' of Thermodynamics to Statistical Mechanics fails to hold at such critical phases. This fact is key to understanding an argument due to Craig Callender to the effect that the thermodynamic limit leads to mistakes in Statistical Mechanics. I discuss (...) this argument and argue that the conclusion is misguided. In addition, I discuss an analogous example where a genuine physical discontinuity---the breaking of drops---requires the use of infinite idealizations. (shrink)

Phase transitions are well-understood phenomena in thermodynamics (TD), but it turns out that they are mathematically impossible in finite SM systems. Hence, phase transitions are truly emergent properties. They appear again at the thermodynamic limit (TL), i.e., in infinite systems. However, most, if not all, systems in which they occur are finite, so whence comes the justification for taking TL? The problem is then traced back to the TD characterization of phase transitions, and it turns out that the characterization is (...) the result of serious idealizations which under suitable circumstances approximate actual conditions. (shrink)

This paper examines the role of mathematical idealization in describing and explaining various features of the world. It examines two cases: first, briefly, the modeling of shock formation using the idealization of the continuum. Second, and in more detail, the breaking of droplets from the points of view of both analytic fluid mechanics and molecular dynamical simulations at the nano-level. It argues that the continuum idealizations are explanatorily ineliminable and that a full understanding of certain physical phenomena cannot be obtained (...) through completely detailed, non-idealized representations. (shrink)

This paper addresses the question of how we should regard the probability distributions introduced into statistical mechanics. It will be argued that it is problematic to take them either as purely ontic, or purely epistemic. I will propose a third alternative: they are almost objective probabilities, or epistemic chances. The definition of such probabilities involves an interweaving of epistemic and physical considerations, and thus they cannot be classified as either purely epistemic or purely ontic. This conception, it will be argued, (...) resolves some of the puzzles associated with statistical mechanical probabilities: it explains how probabilistic posits introduced on the basis of incomplete knowledge can yield testable predictions, and it also bypasses the problem of disastrous retrodictions, that is, the fact the standard equilibrium measures yield high probability of the system being in equilibrium in the recent past, even when we know otherwise. As the problem does not arise on the conception of probabilities considered here, there is no need to invoke a Past Hypothesis as a special posit to avoid it. (shrink)

Batterman has recently argued that fundamental theories are typically explanatorily inadequate, in that there exist physical phenomena whose explanation requires that the conceptual apparatus of a fundamental theory be supplemented by that of a less fundamental theory. This paper is an extended critical commentary on that argument: situating its importance, describing its structure, and developing a line of objection to it. The objection is that in the examples Batterman considers, the mathematics of the less fundamental theory is definable in terms (...) of the mathematics of the fundamental theory and that only the latter need be given a physical interpretation---so we can view the desired explanation as drawing only upon resources internal to the more fundamental physical theory. (The paper also includes an appendix surveying some recent results on quantum chaos.). (shrink)

A traditional view of mathematical modeling holds, roughly, that the more details of the phenomenon being modeled that are represented in the model, the better the model is. This paper argues that often times this ‘details is better’ approach is misguided. One ought, in certain circumstances, to search for an exactly solvable minimal model—one which is, essentially, a caricature of the physics of the phenomenon in question.

I respond to Belot's argument and defend the view that sometimes `fundamental theories' are explanatorily inadequate and need to be supplemented with certain aspects of less fundamental `theories emeritus'.

This paper examines the apparent paradox in the fact that all successful theoretical treatments of phase transitions require an infinite system, yet they are clearly seen to occur in finite systems in the real world. A simple resolution is offered, and the paper ends with a consideration of analogies that can be taken in interpretations of quantum theory.

This thesis gives a philosophical assessment of a contemporary movement, influential amongst physicists, about the status of microscopic and macroscopic properties. The fountainhead for the movement was a short 1972 paper `More is Different', written by the condensed-matter physicist, Philip Anderson. Each of the chapters is concerned with themes mentioned in that paper, or subsequently expounded by Anderson and his followers. In Chapter 1, I aim to locate Anderson's existence claims for `emergent properties' within the metaphysical, epistemological and methodological doctrines (...) that identify themselves as `emergentist'. I argue, against the commentators' consensus, that the New Emergentists make claims about the metaphysical status of physical properties, and should not be read as concerned only with matters of research methodology for physics. In Chapter 2, I look at the physical examples that the New Emergentists appeal to, and propose a way of formulating their main claims within modern analytic metaphysics. I argue that it is possible to view their thesis as an updated version of `British Emergentism' a movement popular in the early years of the twentieth century. I support this contention by comparing examples of emergent properties put forward by the British and the New Emergentists. Chapter 3 is a discussion of the significance of renormalisation techniques. I attack a set of claims by Robert Batterman, who presents renormalisation as an explanatory strategy unrecognised by the philosophy of science. I separate several different methods of renormalisation analysis, and argue that he has conflated them. In Chapter 4, I discuss the theoretical representation of phase transitions in condensed matter physics; in particular, their appeal to the limit of an infinite system. I examine and refute various claims to the effect that the ineliminability of this limit in modelling phase transitions is of great metaphysical significance. I suggest a definition of phase transitions for finite systems that dissolves this illusion, and gives us reason to trust the results of the theories that only apply in the infinite limit. %I then comment on the significance of these results for a suggestion of Laura Ruetsche, that quantum statistical mechanics should be used as a guide to the interpretation of quantum field theory. Chapter 5 revisits the doctrines of the New Emergentists in order to place their views within some wider philosophical debates. I look at how their doctrines bear on issues in the interpretation of quantum mechanics, in the philosophy of mind and the philosophy of science. I close by returning to the context within physics, in which the New Emergentists originally made their presence felt: the controversy over whether elementary particle physics should enjoy greater status than other areas. (shrink)

This paper examines the justifications for using infinite systems to ‘recover’ thermodynamic properties, such as phase transitions, critical phenomena, and irreversibility, from the micro-structure of matter in bulk. Section 2 is a summary of such rigorous methods as in taking the thermodynamic limit to recover PT and in using renormalization group approach to explain the universality of critical exponents. Section 3 examines various possible justifications for taking TL on physically finite systems. Section 4 discusses the legitimacy of applying TL to (...) the problem of irreversibility and assesses the repercussions for its legitimacy on its home turf. (shrink)

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

In another paper, one of us argued that emergence and reduction are compatible, and presented four examples illustrating both. The main purpose of this paper is to develop this position for the example of phase transitions. We take it that emergence involves behaviour that is novel compared with what is expected: often, what is expected from a theory of the system's microscopic constituents. We take reduction as deduction, aided by appropriate definitions. Then the main idea of our reconciliation of emergence (...) and reduction is that one makes the deduction after taking a limit of an appropriate parameter $N$. Thus our first main claim will be that in some situations, one can deduce a novel behaviour, by taking a limit $N\to\infty$. Our main illustration of this will be Lee-Yang theory. But on the other hand, this does not show that the $N=\infty$ limit is physically real. For our second main claim will be that in such situations, there is a logically weaker, yet still vivid, novel behaviour that occurs before the limit, i.e. for finite $N$. And it is this weaker behaviour which is physically real. Our main illustration of this will be the renormalization group description of cross-over phenomena. (shrink)