This article is a translation into english of a lecture given by paneth in 1931. The content of the work is described by the section titles: (1) the need for epistemological clarification of the fundamental concepts of chemistry, (2) the concept of substance in chemistry, (3) the epistemological standpoint of the ancient atomists, (4) the epistemological position of the concept of element introduced by lavoisier, (5) the double meaning of the chemical concept of element: 'basic substance' and 'simple substance', And (...) (6) the double meaning of other chemical concepts. Sections (4)-(6) are published in the following number of this journal. (staff). (shrink)

A variety of recent philosophical discussions, particularly on topics relating to complexity, have begun to reemploy the concept of 'emergence'. Although multiple concepts of 'emergence' are available, little effort has been made to systematically distinguish them. In this paper, I provide a taxonomy of higher-order properties that (inter alia) distinguishes three classes of emergent properties: (1) ontologically basic properties of complex entities, such as the mythical vital properties, (2) fully configurational properties, such as mental properties as they are conceived of (...) by functionalists and computationalists, and (3) highly configurational/holistic properties, such as the higher-level patterns characteristic of complex dynamical systems. Or more simply: emergence as ontological liberality, emergence as multiple realizability, and emergence as interactive complexity. (shrink)

Summary Opinion is divided as to whether chemistry is reducible to physics. The problem can be given a satisfactory solution provided three conditions are met: that a science not be identified with its theories; that several notions of theory dependence be distinguished; and that quantum chemistry, rather than classical chemistry, be compared with physics. This paper proposes to perform all three tasks. It does so by analyzing the methodological concepts concerned as well as by examining the way a chemical rate (...) constant is derivable with the help of the quantum atomic theory. The conclusion is that chemistry, and in particular quantum chemistry, is not a part of physics although it is certainly based on the latter. (shrink)

Differing views on reduction are briefly reviewed and a suggestion is made for a working definition of 'approximate reduction'. Ab initio studies in quantum chemistry are then considered, including the issues of convergence and error bounds. This includes an examination of the classic studies on CH2 and the recent work on the Si2C molecule. I conclude that chemistry has not even been approximately reduced.