Abstract: In this work, polystyrene/waste tires composites were prepared using the melt-mixing method. The viscoelastic properties of PS and PS/composite have been evaluated and compared. These properties were studied using ARES-Rheometer under nitrogen atmosphere in parallel plate geometry with diameter 8 mm. The measurements are carried out over a wide range of temperatures ranged from 120°C to 220°C and frequencies from 100 to 0.1 radians per second. The dynamic and complex viscosity of the PS composites were studied and compared with (...) those of unfilled PS. The results showed that the frequency,  is shifted from 0.46 to 0.072 radians/s and the value of dynamic viscosity increases from 5.0104 to 1.3105 Pa.s by the addition of the rubber for PS. Zero-shear viscosity, 0 was found to be increased from is 9.5104 for PS/waste tire composite to 4.5104 for PS. The flow activation energy is calculated from 0 by using the rheometric software to be 1.063 105 and 1.46 105 J/mol.K for Ps and PS composite, respectively. (shrink)

In this work, polystyrene/waste tires composites were prepared using the melt-mixing method.. The effect of the preparation conditions of the PS/waste tires composite is investigated in this work by using Gel permeation chromatography (GPC) technique. Stability at elevated temperatures were found to increase with the addition of waste tires to PS as confirmed by the results. GPC results indicate that the preparation conditions of the PS/waste tires composite has no effect on the Ps chains as indicated by GPC technique. The (...) signals of the GPC for unfilled and filled PS are similar. That evidences no thermo-mechanical chain degradation is taken place during the addition of the waste tires under the conditions of the melt-mixing process . (shrink)

Abstract— Waste Polyvinyl chloride-bitumen composites were prepared in the molten state by addition waste PVC pipes to commercial bitumen in different concentrations. The original material of the pure bitumen and bitumen composites are rheologically characterized. The viscoelastic properties such as shear compliance, torque and viscosity were measured and compared. These properties were studied using an ARES- Rheometer (Rheometric Scientific, Co.) equipment. The measurements were performed in the dynamic mode, plate-plate geometry of 25 mm diameter over the temperature range from –10 (...) to 60°C and angular frequency, varied from 102 to10-1 radian/s. The results are compared at reference temperatures10 and 60°C over a wide range of . The results evidence that the incorporation of the waste PVC into bitumen enhances the dynamic viscosity. The results evidence that the incorporation of the waste PVC into bitumen enhances the torque and the viscosity. So, the stability of the bitumen composites is more noticeable at 60°C. (shrink)

Abstract: The dynamic viscoelastic properties of Polyvinylacetate with molecular weight 83000g/mol (PVA 83K ) were determined by using a Rheometer operated in the dynamic mode and 8 mm parallel plate over a wide range of temperature as a function of frequency. The measurements were performed successively in the parallel plate geometry using 8 mm plate instead of 25 mm. The glass plateau regime is clearly observed because we could measure PVA 83K sample successively under its glass temperature. The rheological properties (...) of polydisperse PVA 83K were completely studied. The storage and loss compliance and the relaxation spectrum are evaluated. (shrink)

Abstract— Polystyrene/waste tires composites were prepared in this study by incorporating shredded waste tires into polydisperse polystyrene in a melt-mixing method. The dynamic mechanical properties of PS and PS/composite have been evaluated and compared. These properties were studied using ARES-Rheometer under nitrogen atmosphere in parallel plate geometry with diameter 8 mm. The measurements are carried out over a wide range of temperatures ranged from 120°C to 220°C and frequencies from 100 to 0.1 radians per second. The shear creep stress J(t) (...) and loss factor were studied and compared with those of unfilled PS. The dynamic mechanical properties and stability at elevated temperatures were found to increase with the addition of waste tires to PS as confirmed by the results. From the results, the value of J(t) modulus for PS/waste tire is higher than this for the original material of PS. The incorporation of the rubber to the PS changes the value of J(t) at 0.001 second from 5.610-6 to 3.710-6 Pa-1 for PS and PS/waste tire, respectively and this difference increases with time. This confirmed that PS/waste tire composite exhibits higher stability at 180°C for a long time than the original unfilled PS. At frequency  = 6.7102 radians/s , the value of tan increases about 20% by the incorporation of the rubber filler, due to the increase in the G'' modulus particularly at low frequencies in the flow regime. (shrink)

Abstract: Polystyrene/waste tires composites were prepared in this study by incorporating small particles of waste tires into polydisperse commercial polystyrene (PS) in a melt-mixing method. The dynamic mechanical properties of PS and PS/composite were studied using ARES-Rheometer under nitrogen atmosphere in parallel plate geometry with diameter 8 mm. The measurements were carried out over a wide range of temperatures ranged from 120°C to 220°C and frequencies from 100 to 0.1 radians per second. The shear compliance of PS composite were studied (...) and compared with those of unfilled PS. The shear compliance were studied and evaluated. Where the values of J' at  = 0.06 radians/s are 110-4 and 5.310-5 Pa-1 for PS and PS composite, respectively At  = 0.1 radians/s the addition of the rubber alters the value of J'' from 1.610-4 to 8.410-5 Pa-1. That means the stability of PS is enhanced by the incorporation of the rubber. (shrink)

Waste polyethylene (PE) bags were reused in the modification of commercially available bitumen. The bitumen/PE blend was prepared by mixing homogenously commercial bitumen with waste PE in the molten state. The samples of bitumen blend and bitumen base were rheologically analyzied. The rheological properties such as complex modulus, shear compliance, torque and complex viscosity of bitumen and bitumen blend were studied using an ARES- Rheometer (Rheometric Scientific, Co.) in the dynamic mode, plate-plate geometry with diameter 8 mm. The measurements were (...) performed over a wide range of temperatures ranged from-10°C to 60°C and frequencies from 100 to 0.1 radians per second. The results evidence that the complex modulus, shear compliance, torque and viscosity are improved by the incorporation of the waste PE into bitumen. The flow activation energy for neat bitumen and bitumen-9%PE are calculated from 0 by using the rheometric software. (shrink)

Abstract: Waste polyvinylchloride (PVC) pipes were reused in the modification of commercially available bitumen. Waste PVC/ bitumen blends were prepared by melt-mixing method. Rheological characteristics of the neat bitumen and bitumen blends samples were investigated. The rheological properties were determined using an ARES- Rheometer (Rheometric Scientific, Co.) under nitrogen atmosphere in parallel plate geometry with diameter 25 mm. The measurements were performed over a wide range of temperatures ranged from -10°C to 60°C and frequencies from 100 to 0.1 radians per (...) second. Improvement in rheological properties. (shrink)

The dynamic viscoelastic properties of Polyvinylacetate with molecular weight 83000g/mol (PVA 83K) were determined by using a Rheometer operated in the dynamic mode and 8 mm parallel plate over a wide range of temperature as a function of frequency. The measurements were performed successively in the parallel plate geometry using 8 mm plate instead of 25 mm. The glass plateau regime is clearly observed because we could measure PVA 83K sample successively under its glass temperature. The rheological properties of polydisperse (...) PVA 83K were completely studied and the experimental data were analyzed using the Winter model. (shrink)

Abstract: In this work, polystyrene/waste tires composites were prepared by incorporating of waste tires into polydisperse commercial polystyrene in a melt-mixing method. The rheological characterization of PS and PS/composite have been studied and compared. These properties were studied using ARES-Rheometer under nitrogen atmosphere in parallel plate geometry with diameter 8 mm. The measurements are carried out over a wide range of temperatures ranged from 120°C to 220°C and frequencies from 100 to 0.1 radians per second. The complex modulus (G*) were (...) evaluated and compared with those of unfilled PS. The dynamic mechanical properties and stability at elevated temperatures were found to increase with the addition of waste tires to PS as confirmed by the results. The results showed that the value of G* at  = 1.0 radian/s is 1.8104 and 4.4104 Pa for PS and PS/waste tires, respectively. This difference rises at low frequencies-branch to be the value of G* at  = 0.06 radian/s is 8.8102 and 7.8103 Pa for PS and PS/waste tires, respectively. Generally G* increases by the addition of rubber as filler for PS . (shrink)

Abstract— Waste Polyvinyl chloride-bitumen composites were prepared in the molten state by addition waste PVC pipes to commercial bitumen in different concentrations. The original material of the pure bitumen and bitumen composites are rheologically characterized. The viscoelastic properties such as shear compliance, torque and viscosity were measured and compared. These properties were studied using an ARES- Rheometer (Rheometric Scientific, Co.) equipment. The measurements were performed in the dynamic mode, plate-plate geometry of 25 mm diameter over the temperature range from –10 (...) to 60°C and angular frequency, varied from 102 to10-1 radian/s. The results are compared at reference temperatures10 and 60°C over a wide range of . The results evidence that the incorporation of the waste PVC into bitumen enhances the dynamic mechanical moduli and the viscosity. The moduli were found to rise with increasing the waste PVC content. The stability of the bitumen blends is more noticeable at 60°C as confirmed by the results. (shrink)