Quantum physics is a linear theory, so it is somewhat puzzling that it can underlie very complex systems such as digital computers and life. This paper investigates how this is possible. Physically, such complex systems are necessarily modular hierarchical structures, with a number of key features. Firstly, they cannot be described by a single wave function: only local wave functions can exist, rather than a single wave function for a living cell, a cat, or a brain. Secondly, the quantum to (...) classical transition is characterised by contextual wave-function collapse shaped by macroscopic elements that can be described classically. Thirdly, downward causation occurs in the physical hierarchy in two key ways: by the downward influence of time dependent constraints, and by creation, modification, or deletion of lower level elements. Fourthly, there are also logical modular hierarchical structures supported by the physical ones, such as algorithms and computer programs, They are able to support arbitrary logical operations, which can influence physical outcomes as in computer aided design and 3-d printing. Finally, complex systems are necessarily open systems, with heat baths playing a key role in their dynamics and providing local arrows of time that agree with the cosmological direction of time that is established by the evolution of the universe. (shrink)

The role of contingent contexts in formulating relations between properties of systems at different descriptive levels is addressed. Based on the distinction between necessary and sufficient conditions for interlevel relations, a comprehensive classification of such relations is proposed, providing a transparent conceptual framework for discussing particular versions of reduction, emergence, and supervenience. One of these versions, contextual emergence, is demonstrated using two physical examples: molecular structure and chirality, and thermal equilibrium and temperature. The concept of stability is emphasized as a (...) basic guiding principle of contextual property emergence. (shrink)

Given the rich diversity of research fields usually ascribed to chemistry in a broad sense, the present paper tries to dig our characteristic parts of chemistry that can be conceptually distinguished from interdisciplinary, applied, and specialized subfields of chemistry, and that may be called chemistry in a very narrow sense, or 'the chemical core of chemistry'. Unlike historical, ontological, and 'anti-reductive' approaches, I use a conceptual approach together with some methodological implications that allow to develop step by step a kind (...) of cognitive architecture for chemistry, which basically contains: (1) systematic chemical knowledge on the experimental level; (2) clarification of chemical species; (3) chemical classification systems; (4) theoretical foundation through the chemical theory of structural formulas. In a succeeding paper the results will be checked for resisting physicalistic reduction. (shrink)

Along with exploring some of the necessary conditions for the chemistry of our world given what we know about quantum mechanics, I will also discuss a different reductionist challenge than is usually considered in debates on the relationship of chemistry to physics. Contrary to popular belief, classical physics does not have a reductive relationship to quantum mechanics and some of the reasons why reduction fails between classical and quantum physics are the same as for why reduction fails between chemistry and (...) quantum physics. However, a neoreductionist can accept that classical physics has some amount of autonomy from quantum mechanics, but still try to maintain that classical+quantum physics taken as a whole reduces chemistry to physics. I will explore some of the obstacles lying in the neoreductionist’s path with respect to quantum chemistry and thereby hope to shed more light on the conditions necessary for the chemistry of our world. (shrink)

Contextual emergence was originally proposed as an inter-level relation between different levels of description to describe an epistemic notion of emergence in physics. Here, we discuss the ontic extension of this relation to different domains or levels of physical reality using the properties of temperature and molecular shape as detailed case studies. We emphasize the concepts of stability conditions and multiple realizability as key features of contextual emergence. Some broader implications contextual emergence has for the foundations of physics and cognitive (...) and neural sciences are given in the concluding discussion. Relevant facts about algebras of observables are found in the appendices along with an abstract definition of Kubo-Martin-Schwinger states. (shrink)

The "usual story" regarding molecular chemistry is that it is roughly an application of quantum mechanics. That is to say, quantum mechanics supplies everything necessary and sufficient, both ontologically and epistemologically, to reduce molecular chemistry to quantum mechanics. This is a reductive story, to be sure, but a key explanatory element of molecular chemistry, namely molecular structure, is absent from the quantum realm. On the other hand, typical characterizations of emergence, such as the unpredictability or inexplicability of molecular structure based (...) on quantum mechanics, do not characterize the relationship between molecular chemistry and quantum mechanics well either. A different scheme for characterizing reduction and emergence is proposed that accommodates the relationship between quantum mechanics and molecular chemistry and some initial objections to the scheme are considered. (shrink)

(1997). Cartesian cut, Heisenberg cut, and the concept of complexity. World Futures: Vol. 49, The Quest for a Unified Theory of Information, pp. 333-355.

The paper addresses a problem for the unification of quantum physics with the new Aristotelianism: the identification of the members of the category of substance. I outline briefly the role that substance plays in Aristotelian metaphysics, leading to the postulating of the Tiling Constraint. I then turn to the question of which entities in quantum physics can qualify as Aristotelian substances. I offer an answer: the theory of thermal substances, and I construct a fivefold case for thermal substances, based on (...) the irreversibility of time, the definition of thermodynamic concepts, spontaneous symmetry breaking, phase transitions, and chemical form. (shrink)