It is instructive to view the scientific revolution from the point of view of Robert Boyle’s distinction between intermediate and ultimate causes. From this point of view, the scientific revolution involved the identification of intermediate causes and their investigation by way of experiment as opposed to the specification of ultimate causes of the kind involved in the corpuscular matter theories of the mechanical philosophers. The merits of this point of view are explored in this paper by focussing on the hydrostatics (...) of Pascal and Boyle, understood as the experimental investigation of the action of the intermediate causes weight and pressure. The distinctive features of this new science are highlighted by comparing it with two alternative versions of hydrostatics, that of Stevin and that of Descartes. (shrink)

In a number of papers and in his recent book, Is Water H₂O? Evidence, Realism, Pluralism (2012), Hasok Chang has argued that the correct interpretation of the Chemical Revolution provides a strong case for the view that progress in science is served by maintaining several incommensurable “systems of practice” in the same discipline, and concerning the same region of nature. This paper is a critical discussion of Chang's reading of the Chemical Revolution. It seeks to establish, first, that Chang's assessment (...) of Lavoisier's and Priestley's work and character follows the phlogistonists' “actors' sociology”; second, that Chang simplifies late-eighteenth-century chemical debates by reducing them to an alleged conflict between two systems of practice; third, that Chang's evidence for a slow transition from phlogistonist theory to oxygen theory is not strong; and fourth, that he is wrong to assume that chemists at the time did not have overwhelming good reasons to favour Lavoisier's over the phlogistonists' views. (shrink)

Why do some epistemic objects persist despite undergoing serious changes, while others go extinct in similar situations? Scientists have often been careless in deciding which epistemic objects to retain and which ones to eliminate; historians and philosophers of science have been on the whole much too unreflective in accepting the scientists’ decisions in this regard. Through a re-examination of the history of oxygen and phlogiston, I will illustrate the benefits to be gained from challenging and disturbing the commonly accepted continuities (...) and discontinuities in the lives of epistemic objects. I will also outline two key consequences of such re-thinking. First, a fresh view on the (dis)continuities in key epistemic objects is apt to lead to informative revisions in recognized periods and trends in the history of science. Second, recognizing sources of continuity leads to a sympathetic view on extinct objects, which in turn problematizes the common monistic tendency in science and philosophy; this epistemological reorientation allows room for more pluralism in scientific practice itself. (shrink)

Chemistry is the study of the structure and transformation of matter. When Aristotle founded the field in the 4th century BCE, his conceptual grasp of the nature of matter was tailored to accommodate a relatively simple range of observable phenomena. In the 21st century, chemistry has become the largest scientific discipline, producing over half a million publications a year ranging from direct empirical investigations to substantial theoretical work. However, the specialized interest in the conceptual issues arising in chemistry, hereafter Philosophy (...) of Chemistry, is a relatively recent addition to philosophy of science. Philosophy of chemistry has two major parts. In the first, conceptual issues arising within chemistry are carefully articulated and analyzed. Such questions which are internal to chemistry include the nature of substance, atomism, the chemical bond, and synthesis. In the second, traditional topics in philosophy of science such as realism, reduction, explanation, confirmation, and modeling are taken up within the context of chemistry. (shrink)

I argue and demonstrate in this essay that interconnected systems of science and technology, or technoscience, existed long before the late nineteenth century, and that eighteenth-century chemistry was such an early form of technoscience. Based on recent historical research on the early development of carbon chemistry from the late 1820s until the 1840s—which revealed that early carbon chemistry was an experimental expert culture that was largely detached from the mundane industrial world—I further examine the question of the internal preconditions within (...) the expert culture of carbon chemistry that contributed to its convergence with the synthetic-dye industry in the late 1850s. I argue that the introduction of new types and techniques of organic-chemical reactions and organic substances in this experimental expert culture, along with the application of chemical formulae as paper tools for modeling reactions as well as the chemical constitution and structure of substances, enabled academic chemists to make specific, novel contributions to chemical technology and industry in the second half of the nineteenth century. (shrink)

The paper illustrates how organic chemists dramatically altered their practices in the middle part of the twentieth century through the adoption of analytical instrumentation — such as ultraviolet and infrared absorption spectroscopy and nuclear magnetic resonance spectroscopy — through which the difficult process of structure determination for small molecules became routine. Changes in practice were manifested in two ways: in the use of these instruments in the development of ‘rule-based’ theories; and in an increased focus on synthesis, at the expense (...) of chemical analysis. These rule-based theories took the form of generalizations relating structure to chemical and physical properties, as measured by instrumentation. This ‘Instrumental Revolution’ in organic chemistry was two-fold: encompassing an embrace of new tools that provided unprecedented access to structures, and a new way of thinking about molecules and their reactivity in terms of shape and structure. These practices suggest the possibility of a change in the ontological status of chemical structures, brought about by the regular use of instruments. The career of Robert Burns Woodward provides the central historical examples for the paper. Woodward was an organic chemist at Harvard from 1937 until the time of his death. In 1965, he won the Nobel Prize in Chemistry. (shrink)

The paper studies various functions of Berzelian formulas in European organic chemistry prior to the mid-nineteenth century from a semiotic, historical and epistemological perspective. I argue that chemists applied Berzelian formulas as productive ‘paper tools’ for creating a chemical order in the ‘jungle’ of organic chemistry. Beginning in the late 1820s, chemists applied chemical formulas to build models of the binary constitution of organic compounds in analogy to inorganic compounds. Based on these formula models, they constructed new classifications of organic (...) substances. They further applied Berzelian formulas in a twofold way to experimentally investigate organic chemical reactions: as tools which supplemented laboratory tools and as tools for constructing interpretive models of organic reactions. The scrutiny of chemists' performances with chemical formulas on paper also reveals a dialectic which contributed considerably to the formation of the new experimental culture of synthetic carbon chemistry that emerged between the late 1820s and the early 1840s. In an unintended and unforeseen way, the tools reacted back on the goals of their users and contributed to conceptual development and a shift of scientific objects and practices which transcended the originally intended chemical order. (shrink)

This paper studies European chemists’ shifting ontologies of materials by comparing the ways in which they classified materials. The focus is on plant materials, their different identities, and the changing ways chemists sorted out and ordered plant materials in the eighteenth and early nineteenth centuries. The main goals of the paper are to follow the development of plant materials from ordinary, everyday materials and commodities in the early eighteenth century to purified carbon compounds and organic substances familiar only to experts (...) in the 1830s, and to reconstruct chemists’ ways of classifying these objects in different practical and intellectual contexts.The study of changes in European chemists’ ways of classifying plant materials over more than a century brings to the foreground a trajectory of ontological shifts that is ‘punctuated’ in the 1750s, the 1790s, and the 1830s. Early eighteenth-century plant materials, which were commodities of the apothecary trade and other arts and crafts, were elevated epistemically as compound components or ‘proximate principles’ of plants in the 1750s, reduced to organic compounds in the 1790s, and replaced by carbon compounds in the 1830s. The last, third transformation of the epistemic constitution of materials and the mode of their classification was accompanied by a deep transformation of the material culture of plant chemistry. After the late 1830s, many of the eighteenth-century vegetable commodities disappeared from chemists’ agenda or were split into different substances individuated and identified in new ways. Coal tar products, and new organic artefacts containing chlorine or bromine, entered the chemical laboratory in the 1820s and became fused with the purified rest of the previous plant and animal substances. The material objects of the new culture of organic chemistry became detached from the materials applied in the extant arts and crafts. It was only in the late 1850s, with the rise of the synthetic dye industry, that a great number of these laboratory substances became involved in industrial production.Keywords: Commodities and scientific objects; Historical ontology; Classification; Plant chemistry; Organic chemistry. (shrink)

Based upon the demarcation between Elementalism and Atomism Chemistry from the perspective of the long-term history of chemistry, the authors re-examine the Berthollet-Proust controversy on the three types of chemical compounds, pointing out that Berthollet proposed the law of indefinite proportions by deduction, while Proust proposed the law of definite proportions by induction. The controversy is beyond the framework of affinity chemistry and entail a synthesis of meta-chemical thinking and experiments. Proust’s discovery of the law of definite proportions not only (...) function as Bacon’s “instances of lamp” to invoke Dalton and other atomism chemists to envision atomism, but also served as a bridge linking the two meta-chemistries. John Dalton, the third choice, envisioned his atomism by abduction. The case study on “the Berthollet-Proust controversy and Dalton’s resolution” mandates a reinvestigation of the crucial role of the system of experiments and the evolution of chemistry according to the demarcation between the established branches of Elementalism and Atomism Chemistry. (shrink)

Review article of Hasok Chang, Is Water H2O?: Evidence, Realism and Pluralism, Springer, Dordrecht, 2012.

The article takes the term "technoscience" literally and investigates a conception of science that takes it not only as practice, but as production in the sense of a material labor process. It will explore in particular the material connection between science and ordinary production. It will furthermore examine how the historical development of science as a social enterprise was shaped by its technoscientific character. In this context, in an excursus, the prevailing notion will be questioned that social relations must be (...) conceived of as pure interactions. Finally, the article will go into the relationship between the epistemic dimension of science and its technoscientific character. (shrink)

The multiple environmental crises our planet is experiencing forces us to change the ways we engage with it, especially the ones developed by scientific disciplines such as toxicology. In particular, widespread degradation should lead us to develop scientific practices that take environmental ruination as a framework condition, not only as an object of analysis. In doing so, we should take into account the practice of science at laboratories located in the peripheries of global science, institutions that have coexisted with extensive (...) environmental and material decay from their very onset. Contributing to this task, this paper analyzes the case of Centro Nacional del Medio Ambiente, an environmental chemistry laboratory located in Santiago, Chile. Established in mid-1990s, decades of continual budget cuts left it in a state of almost terminal ruin. In its struggle to remain relevant, CENMA developed an alternative kind of scientific practice, ruination science. Although always precarious, ruination science also tends to be well adapted to engage with impurity, resilient but fragile, and ethically entangled, prioritizing attachment and compromises over the application of certain standard recipes or procedures. Beyond its particularities, CENMA’s ruination science provides us with several valuable keys to better deal with worlds facing multiple kinds of anthropogenic degradation. (shrink)

Quine, taking the molecular constitution of matter as a paradigmatic example, offers an account of the relation between theory confirmation and ontology. Elsewhere, he deploys a similar ontological methodology to argue for the existence of mathematical objects. Penelope Maddy considers the atomic/molecular theory in more historical detail. She argues that the actual ontological practices of science display a positivistic demand for “direct observation,” and that fulfillment of this demand allows us to distinguish molecules and other physical objects from mathematical abstracta. (...) However, the confirmation of the atomic/molecular theory and the development of scientists’ ontological attitudes towards atoms was more complicated and subtle than even Maddy supposes. The present paper argues that the history of the theory in fact supports neither Quine’s and Maddy’s accounts of scientific ontology. There was no general demand from scientists to “see” atoms before they were reckoned to be real; but neither did the indispensable appearance of atoms in the best theory of chemical combination suffice to convince scientists of their reality. (shrink)

Humeans and non-Humeans reasonably agree that there may be necessary connections between entities that are identical or merely partly distinct—between, e.g., sets and their individual members, fusions and their individual parts, instances of determinates and determinables, members of certain natural kinds and certain of their intrinsic properties, and (especially among physicalists) certain physical and mental states. Humeans maintain, however, that as per “Hume’s Dictum”, there are no necessary connections between entities that are wholly distinct;1 and in particular, no necessary causal (...) connections between such entities (even when the background conditions requisite for causation are in place). The Humean’s differential treatment appears principled, in reflecting that commonly accepted necessary connections involve constitutional relations, whereas wholly distinct entities (notably, causes and effects) do not constitute each other. I’ll argue, however, that the appearance of principle is not genuine, as per the following conditional: Constitutional→Causal: If one accepts certain constitutional necessities, one should accept certain causal necessities. This result provides needed leverage in assessing the two main frameworks in the metaphysics of science, treating natural kinds, causes, laws of nature, and the like. These frameworks differ primarily on whether Hume’s Dictum is taken as a working constraint on theorizing; and it has proved difficult for either side to criticize the other without presupposing their preferred stance on the dictum, hence talking past one another. The arguments for Constitutional→Causal are based, however, in general and independent considerations about what facts in the world might plausibly warrant our beliefs in certain constitutional necessities involving broadly scientific entities. The Humean can respond to these arguments, which reveal a deep tension in their view, at attendant costs of implausibilty and adhocery. The non-Humean framework doesn’t face any such tension between constitutional and causal necessities, however, and so in this respect comes out ahead. (shrink)

In this article, we provide a detailed discussion of Hasok Chang’s analysis of the Chemical Revolution. Our focus lies on his use of the framework of systems of practice and his claim that the abandonment of the phlogiston theory was irrational. We argue that his framework runs into problems when applied to the chemical revolution because of its static view on the aims of the historical actors and we suggest using Nicholas Jardine’s concept of the reality of questions instead as (...) a more flexible historiographical tool. We show how Chang’s claim regarding the irrational aspects of the chemical revolution follows from his strictly individualistic epistemology, leading him to see institutional and social aspects that impact the determination of aims as external to scientific rationality. We argue that a viable pragmatist and pluralist philosophy of science needs to embrace ‘academic politics’ as an explicit part of its view of rationality. (shrink)

Philosophers have often debated the truth of microstructural essentialism about chemical substances: whether or not the structure of a chemical substance at the molecular scale is what makes it the substance it is. Oddly they have tended to pursue this debate without identifying what a structure is, and with some confusion and about what a chemical substance is. In this paper I draw on chemistry to rectify those omissions, providing a pluralist account of structure, clarifying what (according to chemistry) a (...) chemical substance is and defending microstructural essentialism, as I understand that position. I then give an account of the existence of composite substances and objects in chemistry, an issue that goes back to Aristotle. (shrink)

This undergraduate textbook introduces some fundamental issues in philosophy of science for students of philosophy and science students. The book is divided into two parts. Part 1 deals with knowledge and values. Chap. 1 presents the classical conception of knowledge as initiated by the ancient Greeks and elaborated during the development of science, introducing the central concepts of truth, belief and justification. Aspects of the quest for objectivity are taken up in the following two chapters. Moral issues are broached in (...) Chap. 4, which discusses some aspects of the use and abuse of science, taking up the responsibilities of scientists in properly conducting their business and decision-makers in their concerns with the import of science for society. Part 2 contrasts the view of scientific progress as the rejecting of old hypotheses and theories and replacing them with new ones, represented by Karl Popper, with the conception of progress as accumulating knowledge, saving as much as possible from older theories, represented by Pierre Duhem. A concluding chapter defends the natural attitude of taking the theories of modern science to be literally true, i.e. realism, in the face of arguments drawn partly from the history of scientific progress in criticism of this stance. (shrink)

Using the concept of purity to reflect on the relationship between chemical practice and the philosophy of science, this article considers the philosophical significance of the chemical manipulations that aim to purify or otherwise transform matter. Starting from a consideration of the nature and role of pure (or idealised) examples in philosophy of science, the article underlines the temptation towards abstraction and theory for both scientists and philosophers. The article goes on to argue that chemistry, despite its increasing theoretical sophistication, (...) is a science that remains particularly close to laboratory manipulations. This point is made in reference to the work of Gaston Bachelard on the production of purity and with the aid of historical examples, notably exploring the interplay between techniques of purification and the definition of elements, with special attention paid to Lavoisier’s definition of elements as the final limit of analysis. The closing section concerns the manufacture of steel from iron ore in the eighteenth century, illustrating this process using texts by Pierre-Joseph Macquer and Denis Diderot. Steel production is used to illustrate the kinds of philosophical question that are raised by paying attention to the details of chemical practice rather than jumping straight to chemical theory and also suggests how scientific theory can emerge from this practice itself. (shrink)

The first principle of chemical composition is that elements are actually present in their compounds. It is a golden thread running through the history of compositional thinking in chemistry since before the chemical revolution. Opposed to this principle, which I call Actually Present Elements (APE), is the idea that elements are merely potentially present in their compounds: although not actually present, it is possible to recover them. In this paper I follow that golden thread, and then discuss the status of (...) APE itself: is it true? What arguments were there for it, and when? I argue that APE is a metaphysical principle, albeit at a lower level of generality and abstraction than the term ‘metaphysical’ usually suggests. I critically examine a range of different views on how metaphysical principles might be involved in research programmes in empirical science, and conclude by endorsing Elie Zahar’s view that metaphysical principles such as APE are to be found at the very heart of science. Moreover, they can be recipients of empirical support just like other parts of scientific theory. (shrink)

Contribution to a symposium on Alan Chalmer's The Scientist’s Atom and the Philosopher’s Stone: How Science Succeeded and Philosophy Failed to Gain Knowledge of Atoms (Springer, Dordrecht, 2009).

Although Boyle has been regarded as a champion of the seventeenth century Cartesian mechanical philosophy, I defend the position that Boyle’s views conciliate between a strictly mechanistic conception of fundamental matter and a non-reductionist conception of chemical qualities. In particular, I argue that this conciliation is evident in Boyle’s ontological distinction between fundamental corpuscles endowed with mechanistic properties and higher-level corpuscular concretions endowed with chemical properties. Some of these points have already been acknowledged by contemporary scholars, and I actively engage (...) with their ideas in this paper. However I attempt to contribute to the debate over Boyle’s mechanical philosophy by arguing that Boyle’s writings suggest an emergentist, albeit still mechanistic, notion of chemical properties. I contrast Boyle’s views against those of strict reductionist mechanical philosophers, focusing on the famous debate with Spinoza over the redintegration of niter, and argue that Boyle’s complex chemical ontology provides a more satisfactory understanding of chemical phenomena than is provided by a strictly reductionist and Cartesian mechanical philosophy. (shrink)

In this paper I investigate the relationship between vernacular kind terms and specialist scientific vocabularies. Elsewhere I have developed a defence of realism about the chemical elements as natural kinds. This defence depends on identifying the epistemic interests and theoretical conception of the elements that have suffused chemistry since the mid-eighteenth century. Because of this dependence, it is a discipline-specific defence, and would seem to entail important concessions to pluralism about natural kinds. I argue that making this kind of concession (...) does not imply that vernacular kind terms have independent application conditions. Nor does it preclude us saying that chemists, with their particular epistemic interests, have discovered the underlying nature of water, the stuff that is named and thought about in accordance with the practical interests of everyday life. There are limits to pluralism. (shrink)

Scientific progress remains one of the most significant issues in the philosophy of science today. This is not only because of the intrinsic importance of the topic, but also because of its immense difficulty. In what sense exactly does science makes progress, and how is it that scientists are apparently able to achieve it better than people in other realms of human intellectual endeavour? Neither philosophers nor scientists themselves have been able to answer these questions to general satisfaction.

: The increasing attention on experiment in the last two decades has led to important insights into its material, cultural and social dimensions. However, the role of experiment as a tool for generating knowledge has been comparatively poorly studied. What questions are asked in experimental research? How are they treated and eventually resolved? And how do questions, epistemic situations, and experimental activity cohere and shape each other? In my paper, I treat these problems on the basis of detailed studies of (...) research practice. After presenting several cases from the history of electricity—Dufay, Ampère, and Faraday—I discuss a specific type of experiment—the "exploratory experiment"—and analyze how it works in concept formation. I argue that a fuller understanding of experiment can only be achieved by intertwining historical and philosophical perspectives in such a way that the very separation of the two become questioable. (shrink)

Ursula Klein has argued that Geoffroy’s table of chemical affinities, published in 1718, marked the emergence of the concepts of chemical compound and chemical combination central to chemistry. In this paper her position is summarised and then modified to render it immune to criticism that has been levelled against it. The essentials of Geoffroy’s chemistry are clarified and adapted to Klein’s picture by way of a detailed comparison of it with Boyle’s corpuscular chemistry that proceeded Geoffroy’s by over half a (...) century. The idea that Geoffroy’s notion of chemical combination marked a significant turning point in the emergence of modern chemistry is defended against the charge that it is Whiggish. (shrink)

In a recent essay review of William R. Newman, Atoms and Alchemy (2006), Ursula Klein defends her position that philosophically informed corpuscularian theories of matter contributed little to the growing knowledge of "reversible reactions" and robust chemical species in the early modern period. Newman responds here by providing further evidence that an experimental, scholastic tradition of alchemy extending well into the Middle Ages had already argued extensively for the persistence of ingredients during processes of "mixture" (e.g. chemical reactions), and that (...) this corpuscular alchemical tradition bore important fruit in the work of early modern chymists such as Daniel Sennert and Robert Boyle. (shrink)

In this paper I present a historiography of the recent emergence of philosophy of chemistry. Special attention is given to the interest in this domain in Eastern Europe before the collapse of the USSR. It is shown that the initial neglect of the philosophy of chemistry is due to the unanimous view in philosophy and philosophy of science that only physics is a proper science (to put in Kant's words). More recently, due to the common though incorrect assumption that chemistry (...) can in principle be reduced to physics, the neglect continued, even when interest in sciences such as biology and psychology entered more strongly in philosophy of science. It is concluded that chemistry is an autonomous science and is perhaps a more typical science than physics. (shrink)

The ArgumentThe overall portrayal of early modern experimentation as a new method of securing assent within a philosophical discourse sketched in many of the recent studies on the historical origin of experimentation is questioned by the analysis of the experimental practice of chemistry at the Paris Academy. Chemical experimentation at the Paris Academy in the late seventeenth and early eighteenth century originated in a different tradition than the philosophical. It continued and developed the material culture of the chemical work shops (...) of the sixteenth and seventeenth centuries, and explored epistemic objects which had rather loose connections to philosophy. On the other hand, I argue against the classical dichotomy between the work of the mind that of the hand, and for an epistemology of experimentation that acknowledges that experimental manipulation goes hand in hand with reflexion. In particuler, I argue against the view that chemists at the Paris Academy were “pragmatists” who merely gathered experimental facts and classified substances and operations without perplexing themselves over general conceptions. I claim that the chemists at the Paris Academy constructed a general conception framework which shaped the significance of their experiments. This conception that I call conception of the chemical combination, compound and reaction was rather quickly reified into an experimental fact. Despite its generality it was a genuine chemical conception rather independent of philosophy. (shrink)

The paper examines differences of styles of experimentation in the history of science. It presents arguments for a historization of our historial and philosophical notion of "experimentation," which question the common view that "experimental philosophy" was the only style of experimentation in the eighteenth and early nineteenth centuries. It argues, in particular, that "experimental history" and technological inquiry were accepted styles of academic experimentation at the time. These arguments are corroborated by a careful analysis of a case study, which is (...) embedded in a comparative historical overview. (shrink)

The bulk of Duhem's writing which bears on the understanding of mixtures suggests he adopted an Aristotelian position which he opposed only to the atomic view. A third view from antiquity-that of the Stoics-seems not to be taken into account. But his lines of thought are not always as explicit as could be wished. The Stoic view is considered here from a perspective which Duhem might well have adopted. This provides a background against which his somewhat unorthodox Aristotelianism might be (...) understood. (shrink)

This paper uses scientific perspectivism as a lens for understanding acid experiments from the Chemical Revolution. I argue that this account has several advantages over several recent interpretations of this period, interpretations that do not neatly capture some of the historical experiments on acids. The perspectival view is distinctive in that it avoids discontinuity, allows for the rational resolution of disagreement, and is sensitive to the historical epistemic context.