Thermodynamics and Statistical Mechanics are related to one another through the so-called "thermodynamic limit'' in which, roughly speaking the number of particles becomes infinite. At critical points (places of physical discontinuity) this limit fails to be regular. As a result, the "reduction'' of Thermodynamics to Statistical Mechanics fails to hold at such critical phases. This fact is key to understanding an argument due to Craig Callender to the effect that the thermodynamic limit leads to mistakes in Statistical Mechanics. I discuss (...) this argument and argue that the conclusion is misguided. In addition, I discuss an analogous example where a genuine physical discontinuity---the breaking of drops---requires the use of infinite idealizations. (shrink)

This paper concerns what Jerry Fodor calls a 'metaphysical mystery': How can there by macroregularities that are realized by wildly heterogeneous lower level mechanisms? But the answer to this question is not as mysterious as many, including Jaegwon Kim, Ned Block, and Jerry Fodor might think. The multiple realizability of the properties of the special sciences such as psychology is best understood as a kind of universality, where 'universality' is used in the technical sense one finds in the physics literature. (...) It is argued that the same explanatory strategy used by physicists to provide understanding of universal behavior in physics can be used to explain how special science properties can be heterogeneously multiply realized. (shrink)

The orthodox characterization of spontaneous symmetry breaking in statistical mechanics appeals to novel properties of systems with infinite degrees of freedom, namely, the existence of multiple equilibrium states. This raises the same puzzles about the status of the thermodynamic limit fueling recent debates about phase transitions. I argue that there are prospects of explaining the success of the standard approach to SSB in terms of the properties of large finite systems. Consequently, despite initial appearances, the need to account for SSB (...) phenomena does not offer decisive support to claims about the explanatory and representational indispensability of the thermodynamic limit. (shrink)

I present a novel approach to the scholarly debate that has arisen with respect to the philosophical import one should infer from scientific accounts of phase transitions by appealing to a distinction between representation understood as denotation, and faithful representation understood as a type of guide to ontology. It is argued that the entire debate is misguided, for it stems from a pseudo-paradox that does not license the type of claims made by scholars and that what is really interesting about (...) phase transitions is the manner by which they force us to rethink issues regarding scientific representation, idealizations, and realism. (shrink)

This paper looks at emergence in physical theories and argues that an appropriate way to understand socalled “emergent protectorates” is via the explanatory apparatus of the renormalization group. It is argued that mathematical singularities play a crucial role in our understanding of at least some well-defined emergent features of the world.

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

This paper examines the justifications for using infinite systems to ‘recover’ thermodynamic properties, such as phase transitions, critical phenomena, and irreversibility, from the micro-structure of matter in bulk. Section 2 is a summary of such rigorous methods as in taking the thermodynamic limit to recover PT and in using renormalization group approach to explain the universality of critical exponents. Section 3 examines various possible justifications for taking TL on physically finite systems. Section 4 discusses the legitimacy of applying TL to (...) the problem of irreversibility and assesses the repercussions for its legitimacy on its home turf. (shrink)

This is a companion to another paper. Together they rebut two widespread philosophical doctrines about emergence. The first, and main, doctrine is that emergence is incompatible with reduction. The second is that emergence is supervenience; or more exactly, supervenience without reduction.In the other paper, I develop these rebuttals in general terms, emphasising the second rebuttal. Here I discuss the situation in physics, emphasising the first rebuttal. I focus on limiting relations between theories and illustrate my claims with four examples, each (...) of them a model or a framework for modelling, from well-established mathematics or physics.I take emergence as behaviour that is novel and robust relative to some comparison class. I take reduction as, essentially, deduction. The main idea of my first rebuttal will be to perform the deduction after taking a limit of some parameter. Thus my first main claim will be that in my four examples (and many others), we can deduce a novel and robust behaviour, by taking the limit N→∞ of a parameter N.But on the other hand, this does not show that the N=∞ limit is “physically real”, as some authors have alleged. For my second main claim is that in these same examples, there is a weaker, yet still vivid, novel and robust behaviour that occurs before we get to the limit, i.e. for finite N. And it is this weaker behaviour which is physically real.My examples are: the method of arbitrary functions (in probability theory); fractals (in geometry); superselection for infinite systems (in quantum theory); and phase transitions for infinite systems (in statistical mechanics). (shrink)

This article examines ontological/dynamical aspects of emergence, specifically the micro-macro relation in cases of universal behavior. I discuss superconductivity as an emergent phenomenon, showing why microphysical features such as Cooper pairing are not necessary for deriving characteristic properties such as infinite conductivity. I claim that the difficulties surrounding the thermodynamic limit in explaining phase transitions can be countered by showing how renormalization group techniques facilitate an understanding of the physics behind the mathematics, enabling us to clarify epistemic and ontological aspects (...) of emergence. I close with a discussion of the impact of these issues for questions concerning natural kinds. (shrink)

In another paper, one of us argued that emergence and reduction are compatible, and presented four examples illustrating both. The main purpose of this paper is to develop this position for the example of phase transitions. We take it that emergence involves behaviour that is novel compared with what is expected: often, what is expected from a theory of the system's microscopic constituents. We take reduction as deduction, aided by appropriate definitions. Then the main idea of our reconciliation of emergence (...) and reduction is that one makes the deduction after taking a limit of an appropriate parameter $N$. Thus our first main claim will be that in some situations, one can deduce a novel behaviour, by taking a limit $N\to\infty$. Our main illustration of this will be Lee-Yang theory. But on the other hand, this does not show that the $N=\infty$ limit is physically real. For our second main claim will be that in such situations, there is a logically weaker, yet still vivid, novel behaviour that occurs before the limit, i.e. for finite $N$. And it is this weaker behaviour which is physically real. Our main illustration of this will be the renormalization group description of cross-over phenomena. (shrink)

This paper looks at the nature of idealizations and representational structures appealed to in the context of the fractional quantum Hall effect, specifically, with respect to the emergence of anyons and fractional statistics. Drawing on an analogy with the Aharonov–Bohm effect, it is suggested that the standard approach to the effects— the topological approach to fractional statistics—relies essentially on problematic idealizations that need to be revised in order for the theory to be explanatory. An alternative geometric approach is outlined and (...) endorsed. Roles for idealizations in science, as well as consequences for the debate revolving around so-called essential idealizations, are discussed. (shrink)

According to standard (quantum) statistical mechanics, the phenomenon of a phase transition, as described in classical thermodynamics, cannot be derived unless one assumes that the system under study is infinite. This is naturally puzzling since real systems are composed of a finite number of particles; consequently, a well‐known reaction to this problem was to urge that the thermodynamic definition of phase transitions (in terms of singularities) should not be “taken seriously.” This article takes singularities seriously and analyzes their role by (...) using the well‐known distinction between data and phenomena , in an attempt to better understand the origin of the puzzle. *Received April 2009; revised July 2009. †To contact the author, please write to: University of Cambridge, Department of History and Philosophy of Science, Free School Lane, Cambridge CB2 3RH, United Kingdom; e‐mail: [email protected]. (shrink)

This paper examines the justifications for using infinite systems to 'recover' thermodynamic properties, such as phase transitions (PT), critical phenomena (CP), and irreversibility, from the micro-structure of matter in bulk. Section 2 is a summary of such rigorous methods as in taking the thermodynamic limit (TL) to recover PT and in using renormalization (semi-) group approach (RG) to explain the universality of critical exponents. Section 3 examines various possible justifications for taking TL on physically finite systems. Section 4 discusses the (...) legitimacy of applying TL to the problem of irreversibility and assesses the repercussions for its legitimacy on its home turf. (shrink)

Phase transitions are well-understood phenomena in thermodynamics (TD), but it turns out that they are mathematically impossible in finite SM systems. Hence, phase transitions are truly emergent properties. They appear again at the thermodynamic limit (TL), i.e., in infinite systems. However, most, if not all, systems in which they occur are finite, so whence comes the justification for taking TL? The problem is then traced back to the TD characterization of phase transitions, and it turns out that the characterization is (...) the result of serious idealizations which under suitable circumstances approximate actual conditions. (shrink)