Two inter-linked theses are defended in this paper. One is the Duhemian theme that a rigid distinction between physical and chemical properties cannot be upheld. Duhem maintained this view not because the latter are reducible to the former, but because if physics is to remain consistent with chemistry it must prove possible to expand it to accommodate new features, and a rigid distinction would be a barrier to this process. The second theme is that naturally occurring isotopic variants of water (...) are in fact distinct substances, and naturally occurring samples of water are mixtures of these substances. For most practical purposes it is convenient to treat protium oxide, deuterium oxide, and so on, as the same chemical substance, but to insist on this as a matter of principle would stand in conflict with the first thesis. (shrink)

Does chemistry reduce to physics? If this means ‘Can we derive the laws of chemistry from the laws of physics?’, recent discussions suggest that the answer is ‘no’. But sup posing that kind of reduction—‘epistemological reduction’—to be impossible, the thesis of ontological reduction may still be true: that chemical properties are determined by more fundamental properties. However, even this thesis is threatened by some objections to the physicalist programme in the philosophy of mind, objections that generalize to the chemical case. (...) Two objections are discussed: that physicalism is vacuous, and that nothing grounds the asymmetry of dependence which reductionism requires. Although it might seem rather surprising that the philosophy of chemistry is affected by shock waves from debates in the philosophy of mind, these objections show that there is an argumentative gap between, on the one hand, the theoretical connection linking chemical properties with properties at the sub-atomic level, and, on the other, the philosophical thesis of ontological reduction. The aim of this paper is to identify the missing premises (among them a theory of physical possibility) that would bridge this gap. Introduction: missing elements and the mystery of discreteness The refutation of physicalism A combinatorial theory of physical possibilia Combinatorialism and the Bohr model Objections The missing premises and a disanalogy with mind. (shrink)

§30. Significance of Desargues's theorem . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 CHAPTER VI. PASCAL'S THEOREM. §31. ...

Duhem is often described as an anti-realist or instrumentalist. A contrary view has recently been expressed by Martin (1991) (Pierre Duhem: Philosophy and History in the Work of a Believing Physicist (La Salle, IL: Open Court)), who suggests that this interpretation makes it difficult to understand the vantage point from which Duhem argues in La science allemande (1915) that deduction, however impeccable, cannot establish truths unless it begins with truths. In the same spirit, the present paper seeks to establish that (...) Duhem is at any rate not the kind of anti-realist he is often presented as being, and that his views are like those Quine sees fit to call realist. An interpretation of Duhem's views on explanation and precision in science, and their bearing on the epistemological status of theory, is advanced which leads naturally into his critique of conventionalism. His attitude towards atomism, which should not be judged from a post-1925 perspective, is considered part of the unified view he strove after and appropriately called Duhem's physicalism, standing in contrast to the kind of reductionist conception usually associated with atomism. (shrink)

In the problem of the relationship between chemistry and physics, many authors take for granted the ontological reduction of the chemical world to the world of physics. The autonomy of chemistry is usually defended on the basis of the failure of epistemological reduction: not all chemical concepts and laws can be derived from the theoretical framework of physics. The main aim of this paper is to argue that this line of argumentation is not strong enough for eliminate the idea of (...) a hierarchical dependence of chemistry with respect to physics. The rejection of the secondary position of chemistry and the defense of the legitimacy of the philosophy of chemistry require a radically different philosophical perspective that denies not only epistemological reduction but also ontological reduction. Only on the basis of a philosophically grounded ontological pluralism it is possible to accept the ontological autonomy of the chemical world and, with this, to reverse the traditional idea of the ‘superiority’ of physics in the context of natural sciences. (shrink)

In Mind in a Physical World (1998), Jaegwon Kim has recently extended his ongoing critique of `non-reductive materialist' positions in philosophy of mind by arguing that Nagel's model of reduction is the wrong paradigm in terms of which to contest the issue of psychophysical reduction, and that an altogether different model of scientific reduction – a functional model of reduction – is needed. In this paper I argue, first, that Kim's conception of the Nagelian model is substantially impoverished and potentially (...) misleading; second, that his own functional model is problematic in several respects; and, third, that the basic idea underlying his functional model can well be accommodated within a properly reinterpreted Nagelian model. I conclude with some reflections on the issue of psychophysical reduction. (shrink)

In a recent critique of the doctrine of emergentism championed by its classic advocates up to C. D. Broad, Jaegwon Kim (Philosophical Studies 63:31–47, 1999) challenges their view about its applicability to the sciences and proposes a new account of how the opposing notion of reduction should be understood. Kim is critical of the classic conception advanced by Nagel and uses his new account in his criticism of emergentism. I question his claims about the successful reduction achieved in the sciences (...) and argue that his new account has not improved on Nagel’s and that the critique of emergentism he bases on it is question-begging in important respects. (shrink)

In this article we critically evaluate Robin Le Poidevin's recent attempt to set out an argument for the ontological reduction of chemistry independently of intertheoretic reduction. We argue, firstly, that the argument he envisages applies only to a small part of chemistry, and that there is no obvious way to extend it. We argue, secondly, that the argument cannot establish the reduction of chemistry, properly so called.

Central to many issues surrounding reduction in science is the relation between a physical system and its components. In this article we examine how thermodynamic theory relates properties of whole systems to properties of their components. In order to keep the analysis general, we focus our study on universal properties like volume, heat capacity, energy and temperature. In the cases examined we find that scientific explanation requires appeal to properties of components that are spatially as extensive as the whole system. (...) We discuss some implications of our study for the purported paradigmatic reductions of heat and temperature to molecular motion. We conclude that while macro systems reduce ontologically to micro components, epistemologically the reduction of theoretical concepts in general fails. (shrink)