In the sixth section of his light quantum paper of 1905, Einstein presented the miraculous argument, as I shall call it. Pointing out an analogy with ideal gases and dilute solutions, he showed that the macroscopic, thermodynamic properties of high-frequency heat radiation carry a distinctive signature of finitely many, spatially localized, independent components and so inferred that it consists of quanta. I describe how Einstein's other statistical papers of 1905 had already developed and exploited the idea that the ideal gas (...) law is another macroscopic signature of finitely many, spatially localized, independent components and that these papers in turn drew on his first two, "worthless" papers of 1901 and 1902 on intermolecular forces. However, while the ideal gas law was a secure signature of independence, it was harder to use as an indicator that there are finitely many components and that they are spatially localized. Further, since his analysis of the ideal gas law depended on the assumption that the number of components was fixed, its use was precluded for heat radiation, whose component quanta vary in number in most processes. So Einstein needed and found another, more powerful signature of discreteness applicable to heat radiation and which indicated all these properties. It used one of the few processes, volume fluctuation, in which heat radiation does not alter the number of quanta. © 2005 Elsevier Ltd. All rights reserved. (shrink)

In the sixth section of his light quantum paper of 1905, Einstein presented the miraculous argument, as I shall call it. Pointing out an analogy with ideal gases and dilute solutions, he showed that the macroscopic, thermodynamic properties of high frequency heat radiation carry a distinctive signature of finitely many, spatially localized, independent components and so inferred that it consists of quanta. I describe how Einstein’s other statistical papers of 1905 had already developed and exploited the idea that the ideal (...) gas law is another macroscopic signature of finitely many, spatially localized, independent components and that these papers in turn drew on his first two, “worthless” papers of 1901 and 1902 on intermolecular forces. However, while the ideal gas law was a secure signature of independence, it was harder to use as an indicator that there are finitely many components and that they are spatially localized. Further, since his analysis of the ideal gas law depended on the assumption that the number of components was fixed, its use was precluded for heat radiation, whose component quanta vary in number in most processes. So Einstein needed and found another, more powerful signature of discreteness applicable to heat radiation and which indicated all these properties. It used one of the few processes, volume fluctuation, in which heat radiation does not alter the number of quanta. (shrink)

This is the only book to chart the history and development of modern probability theory. It shows how in the first thirty years of this century probability theory became a mathematical science. The author also traces the development of probabilistic concepts and theories in statistical and quantum physics. There are chapters dealing with chance phenomena, as well as the main mathematical theories of today, together with their foundational and philosophical problems. Among the theorists whose work is treated at some length (...) are Kolmogorov, von Mises and de Finetti. The principal audience for the book comprises philosophers and historians of science, mathematicians concerned with probability and statistics, and physicists. The book will also interest anyone fascinated by twentieth-century scientific developments because the birth of modern probability is closely tied to the change from a determinist to an indeterminist world-view. (shrink)

This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.

Excerpt from Die Prinzipien der Mechanik in Neuem Zusammenhange Dargestellt Wahl eines Berufs entschliefsen mufste, wahlte er den des Ingenieurs. Es scheint, dafs die auch in spateren Jahren als ein charakteristischer Grundzug seines Wesens hervor tretende Bescheidenheit ihn an seiner Begabung fur theore tische Wissenschaft zweifeln liefs, und dafs er sich bei der Beschaftigung mit seinen geliebten mechanischen Arbeiten des Erfolges sicherer fuhlte, weil er deren Tragweite schon damals ausreichend verstand. Vielleicht hat ihn auch die in seiner Vaterstadt herrschende, mehr (...) dem Praktischen zugeneigte Sinnesweise beeinflufst. Ubrigens beobachtet man nicht selten diese Art zaghafter Bescheidenheit gerade bei jungen Leuten von hervorragenden Anlagen. Sie haben wohl eine deutliche Vorstellung von den Schwierigkeiten, die vor der Erreichung des ihnen vorschwebenden hohen Zieles zu uberwinden sind, und mussen ihre Krafte erst praktisch erprobt haben, ehe sie das zu ihrem schweren Werke notige Selbstvertrauen ge winnen. Aber auch in ihrer spateren Entwickelung pflegen reich veranlagte Naturen um so unzufriedener mit ihren eigenen Werken zu sein je hoher ihre Fahigkeiten und ihre Ideale reichen. Die Begabtesten erreichen offenbar nur des halb das Hochste, weil sie am empfindlichsten gegen jede Un vollkommenheit sind, und am unermudlichsten an deren Beseitigung arbeiten. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works. (shrink)

The energetics controversy is understood variously as energy vs. atoms, thermodynamics vs. statistical mechanics, phenomenalism vs. realism, equations vs. pictures, and especially Ostwald vs. Boltzmann. It is generally thought that at Lübeck in 1895 Boltzmann and Planck demolished energetics, but while its momentum was slowed, energetics in one or more of the above senses still retained supporters as late as the great physics conference at the St. Louis World’s Fair in 1904. Indeed, after Ostwald himself abandoned it in 1908, Ernst (...) Mach began for the first time to defend it. The main emphasis in this paper, however, is on Georg Helm (1851–1923) who had been invited to Lübeck to be the main speaker on energetics. He had adopted his position earlier than Ostwald and his views avoided many of the errors and oversights in Ostwald’s approach. Indeed, Helm could be called the strongest defender of energetics, even if Ostwald was Boltzmann’s main target. Helm was largely Machist in philosophy at that time and did not reify energy. (shrink)

It is generally accepted that, around the turn of the century, GIBBS and EINSTEIN independently developed two equivalent formulations of statistical mechanics. GIBBS version is taken as genuine and rigorous, while EINSTEINs, despite some features which are characteristic of him, is usually considered a not totally satisfactory attempt.It will be shown in the present work that such a picture is oversimplified and requires further nuancing. In fact, there are significant differences, with important implications which have not been sufficiently examined, between (...) the two formulations. Several issues relating to the impact of the two versions will also be addressed. (shrink)

Bohr and Heisenberg suggested that the thermodynamical quantities of temperature and energy are complementary in the same way as position and momentum in quantum mechanics. Roughly speaking their idea was that a definite temperature can be attributed to a system only if it is submerged in a heat bath, in which case energy fluctuations are unavoidable. On the other hand, a definite energy can be assigned only to systems in thermal isolation, thus excluding the simultaneous determination of its temperature. Rosenfeld (...) extended this analogy with quantum mechanics and obtained a quantitative uncertainty relation in the form ΔU Δ(1/T) ≥ k, where k is Boltzmann's constant. The two “extreme” cases of this relation would then characterize this complementarity between isolation (U definite) and contact with a heat bath (T definite). Other formulations of the thermodynamical uncertainty relations were proposed by Mandelbrot (1956, 1989), Lindhard (1986), and Lavenda (1987, 1991). This work, however, has not led to a consensus in the literature. It is shown here that the uncertainty relation for temperature and energy in the version of Mandelbrot is indeed exactly analogous to modern formulations of the quantum mechanical uncertainty relations. However, his relation holds only for the canonical distribution, describing a system in contact with a heat bath. There is, therefore, no complementarily between this situation and a thermally isolated system. (shrink)