Leibniz proposed the ‘Most Determined Path Principle’ in seventeenth century. According to it, ‘ease’ of travel is the end purpose of motion. Using this principle and his calculus method he demonstrated Snell’s Laws of reflection and refraction. This method shows that light follows extremal (local minimum or maximum) time path in going from one point to another, either directly along a straight line path or along a broken line path when it undergoes reflection or refraction at plane or spherical (concave (...) or convex) surfaces. The extremal time path avoided the criticism that Fermat’s least time path was subjected to, by Cartesians who cited examples of reflections at spherical surfaces where light took the path of longest time. Thereby it became the standard method of demonstration of Snell’s Laws. Ptolemy’s theorem is a fundamental theorem in geometry. A special case of it offers a method of finding the minimum sum of the two distances of a point from two given fixed points. We show in this paper that Leibniz’s calculus proof of Snell’s Laws violates Ptolemy’s theorem, whereby Leibniz’s proof becomes invalid. (shrink)