The wave-mechanical treatment of the valence bond, by Walter Heitler and Fritz London, and its ensuing foundational importance in quantum chemistry has been traditionally regarded as the basis for the argument that chemistry may be theoretically reduced to physics. Modern analyses of the reductionist claim focuses on the limitations to achieving full reduction in practice because of the approximations used in modern quantum chemical methods, but neglect the historical importance of the chemical bond as a chemical entity. This paper re-examines (...) these arguments with a study of the development of the valence bond by chemist Gilbert Lewis within a chemically autonomous framework, and its extension by Linus Pauling using Heitler and London’s methods. Here, we see that the chemical bond is best described as a theoretical synthesis or physico-chemical entity, to represent its full interdisciplinary importance from the philosophical and historical perspectives.Keywords: Reductionism; Chemical bond; Linus Pauling; Gilbert Lewis; Heitler–London; Chemical. (shrink)

The story of how Perrin’s experimental work established the reality of atoms and molecules has been a staple in (realist) philosophy of science writings (Wesley Salmon, Clark Glymour, Peter Achinstein, Penelope Maddy, …). I’ll argue that how this story is told distorts both what the work was and its significance, and draw morals for the understanding of how theories can be or fail to be empirically grounded.

An amended bootstrapping can avoid Christensen's counterexamples. Earman and Edidin argue that Christensen's examples to bootstrapping rely on his failure to analyze background knowledge. I add an additional condition to bootstrapping that is motivated by Glymour's remarks on variety of evidence. I argue that it avoids the problems that the examples raise. I defend the modification against the charge that it is holistic, and that it collapses into Bayesianism.

This paper makes explicit and takes issue with the bizarre view, which is unfortunately prevalent among social scientists, that causal relations are features of models only. There are some good reasons to represent causal factors with independent variables. But the association between causes and independent variables is only a desideratum in model construction. It is not a criterion for judging which things are causes and which are effects.

Quine, taking the molecular constitution of matter as a paradigmatic example, offers an account of the relation between theory confirmation and ontology. Elsewhere, he deploys a similar ontological methodology to argue for the existence of mathematical objects. Penelope Maddy considers the atomic/molecular theory in more historical detail. She argues that the actual ontological practices of science display a positivistic demand for “direct observation,” and that fulfillment of this demand allows us to distinguish molecules and other physical objects from mathematical abstracta. (...) However, the confirmation of the atomic/molecular theory and the development of scientists’ ontological attitudes towards atoms was more complicated and subtle than even Maddy supposes. The present paper argues that the history of the theory in fact supports neither Quine’s and Maddy’s accounts of scientific ontology. There was no general demand from scientists to “see” atoms before they were reckoned to be real; but neither did the indispensable appearance of atoms in the best theory of chemical combination suffice to convince scientists of their reality. (shrink)

In this paper I argue that Poincaré’s acceptance of the atom does not indicate a shift from instrumentalism to scientific realism. I examine the implications of Poincaré’s acceptance of the existence of the atom for our current understanding of his philosophy of science. Specifically, how can we understand Poincaré’s acceptance of the atom in structural realist terms? I examine his 1912 paper carefully and suggest that it does not entail scientific realism in the sense of acceptance of the fundamental existence (...) of atoms but rather, argues against fundamental entities. I argue that Poincaré’s paper motivates a non-fundamentalist view about the world, and that this is compatible with his structuralism. (shrink)

Figuring prominently in their decisions regarding which theories to pursue are scientists' appeals to the promise or lack of promise of those theories. Yet philosophy of science has had little to say about how one is to assess theory promise. This essay identifies several indices that might be consulted to determine whether or not a theory is promising and worthy of pursuit. Various historical examples of appeals to such indices are introduced.

I offer support for the view that physicalist theories of cognition don't reduce to neurophysiological theories. On my view, the mind-brain relationship is to be explained in terms of evolutionary forces, some of which tug in the direction of a reductionistic mind-brain relationship, and some of which which tug in the opposite direction. This theory of forces makes possible an anti-reductionist account of the cognitive mind-brain relationship which avoids psychophysical anomalism. This theory thus also responds to the complaint which arguably (...) lies behind the Churchlands' strongest criticisms of anti-reductionism — namely the complaint that anti-reductionists fail to supply principled explanations for the character of the mind-brain relationship. While lending support to anti-reductionism, the view defended here also insures a permanent place for mind-brain reduction as an explanatory ideal analogous to Newtonian inertial motion or Aristotelian natural motion. (shrink)

Scientists typically do something other than accept or reject their theories, they pursue them. Throughout the greater part of the nineteenth century numerous chemists devoted their research energy and resources to the development of Daltonian theory, declaring themselves willing to make use of the atomic theory in their research but reluctant or unwilling to accept it. When Frankland, for example, declared that he did not want to be considered a “blind believer” in the atomic theory and could not “accept it (...) as true”, but that he had been—and planned to continue—using it “as a useful ladder”, he had arrived at a decision shared by many of his colleagues that while the theory was not acceptable, it was promising and worthy of pursuit.1 And when Van’t Hoff measured the kinetic-molecular theory by its fruits in the 1880’s, he judged that it barely gave the then-current 4% interest rate, and so was an unpromising theory, unworthy of pursuit (van Nelsen 1960. p. 151). (shrink)

Scientific realism does not view theoretical terms as mere instruments of experimental predictions; it grants referential status to natural kind terms with 'epistemic access' and view scientific theories and terms as corresponding to physical phenomena and entities which exist independently of observation, and as thereby being the source of objective -approximate and not absolute- knowledge of the physical realm. As a result, scientific realism is accused of ontologising the unobservables. Against this charge, scientific realism posits the idea of the dialectical (...) relation between theoretical terms referring to the unobservables and scientific methods. The second argument made by realism is the ‘no miracle’ thesis. These arguments stand challenged by the Copenhagen interpretation of quantum mechanics. The aim of the paper is to examine the relevance of the two arguments of scientific realism in countering the idea that the existence of quantum states in the microphysical world renders realism obsolete. (shrink)

In How the Laws of Physics Lie (1983)2 Cartwright argues for being a realist about theoretical entities but non-realist about theoretical laws. Her reason for this distinction is that only the former involves causal explanation, and accepting causal explanations commits us to the existence of the causal entity invoked. “What is special about explanation by theoretical entity is that it is causal explanation, and existence is an internal characteristic of causal claims. There is nothing similar for theoretical laws.” (p. 93). (...) For, according to Cartwright, the acceptability of a theoretical explanation is a matter of its ability to satisfy such criteria as prganizing and simplifying, and in her view, “success at organizing, predicting, and classifying is never an argument for truth.” (p. 91). In contrast, Cartwright claims, “When I infer from an effect to a cause, I am asking what made the effect occur, what brought it about. (shrink)

In this chapter I investigate the prospects of integrated history and philosophy of science, by examining how philosophical issues raised by “hidden entities”, entities that are not accessible to unmediated observation, can enrich the historical investigation of their careers. Conversely, I suggest that the history of those entities has important lessons to teach to the philosophy of science. Hidden entities have played a crucial role in the development of the natural sciences. Despite their centrality to past scientific practice, however, several (...) of them (e.g., phlogiston, caloric, and the ether) turned out to be fictitious. For this reason, they have figured prominently in recent debates on scientific realism. The issues I explore in this paper are entangled with those debates. I argue that our understanding of hidden entities and their role in experimental practice can be enhanced by adopting an integrated historical-cum-philosophical approach. On the one hand, philosophical reflection on the reality of those entities has a lot to gain by examining historically how they were ntroduced and investigated. On the other hand, the historical reconstruction of the careers of those entities may profit from philosophical reflection on their existence. (shrink)

This paper defends the Quine-Putnam mathematical indispensability argument against two objections raised by Penelope Maddy. The objections concern scientific practices regarding the development of the atomic theory and the role of applied mathematics in the continuum and infinity. I present two alternative accounts by Stephen Brush and Alan Chalmers on the atomic theory. I argue that these two theories are consistent with Quine’s theory of scientific confirmation. I advance some novel versions of the indispensability argument. I argue that these new (...) versions accommodate Maddy’s history of the atomic theory. Counter-examples are provided regarding the role of the mathematical continuum and mathematical infinity in science. (shrink)

Towards the end of the 19th century there were those who wished to see the kinetic theory abandoned. This paper attempts to show that this reaction was primarily due to philosophical objections rather than the result of scientific difficulties encountered by the kinetic theory. First the relevant philosophical background is examined as well as the relation between the kinetic theory and thermodynamics. Next the scientific difficulty known as the specific heats ratio anomaly is discussed and finally Boltzmann's philosophy of science (...) is examined. (shrink)

The realism/antirealism controversy has gone on for centuries, and gives every indication that it will continue to go on for centuries. Dismayed, I take a closer look at it. I find that the question it poses--very roughly, whether scientific knowledge is true (approximately true, put forward as true, etc.) or only useful (empirically adequate, a convenient method of representation, etc.)--actually suppresses socially critical thought and discussion about science (e.g., concerning whether scientific knowledge is sexist or racist or socially harmful in (...) other ways, or whether scientific knowledge is useful for achieving the goals we have or the goals we ought to have). I find, as well, that two of the most important responses to the realism/antirealism controversy--that which construes it as concerned with science's aims and that which construes it as concerned with science's results--fail to make sufficient empirical or normative contact with science. As a consequence, they provide representations of science that either do not help scientists (or nonscientists) make informed decisions about science, or actually hinder these individuals from doing so. I conclude that we should either stop engaging in the realism/antirealism controversy entirely, or else engage in it in a more socially responsible way--by gathering the right kinds of empirical and normative data, and framing more helpful versions of the questions we want to ask. I end by responding to the strong objections sure to be voiced by my colleagues in philosophy of science. (shrink)

The French physicist Jean Baptiste Perrin is widely credited with providing the conclusive argument for atomism. The most well-known part of Perrin’s argument is his description of thirteen different procedures for determining Avogadro’s number (N)–the number of atoms, ions, and molecules contained in a gram-atom, gram-ion, and gram-mole of a substance, respectively. Because of its success in ending the atomism debates Perrin’s argument has been the focus of much philosophical interest. The various philosophers, however, have reached different conclusions, not only (...) about the argument’s general rationale but also the role that the multiple determination of N played in it. This paper emphasizes the historical development of Perrin’s experimental work in order to understand the role that the multiple determination of molecular magnitudes played in his argument for molecular reality. It claims that Perrin used the multiple determination strategy to put forward an exceptionally strong no-coincidence argument to argue for both the correctness of the values for the molecular magnitudes determined and the validity of the auxiliary assumptions upon which the different determinations were based. The historicist approach also allows the identification of the elements responsible for the epistemic strength of Perrin’s no-coincidence argument. (shrink)

This paper aims to cast light on the reasons that explain the shift of opinion—from scepticism to realism—concerning the reality of atoms and molecules in the beginning of the twentieth century, in light of Jean Perrin’s theoretical and experimental work on the Brownian movement. The story told has some rather interesting repercussions for the rationality of accepting the reality of explanatory posits. Section 2 presents the key philosophical debate concerning the role and status of explanatory hypotheses c. 1900, focusing on (...) the work of Duhem, Stallo, Ostwald, Poincaré and Boltzmann. Section 3 examines in detail Perrin’s theoretical account of the molecular origins of Brownian motion, reconstructs the structure and explains the strength of Perrin’s argument for the reality of molecules. Section 4 draws three important lessons for the current debate over scientific realism. (shrink)

In this report on the present state of the discussion about the interpretation of quantum mechanics an attempt is made to provide an idea of the philosophical relevance of the foundations of physics. A simplified model of the measuring process is given which shows the difficulties in the interpretation of quantum mechanics. It is argued against Bohr's solution (also in a version of H. Putnam). Two examples show possible philosophical consequences of quantum mechanics: The variety of quantum logics challenges the (...) foundations of logic, the paradox of Einstein, Podolsky and Rosen (with Bell's inequality) may be interpreted along the lines of holism. Against alleged refutations of realism by means of quantum mechanics, a realist standpoint is maintained. A proper interpretation of quantum mechanics from an epistemological point of view seems still to be lacking. In my childhood the legend was current, that only twelve men in the World understood Einstein's theory. Nowadays, relativity is quite tame; but I shall argue presently thatnobody yet understands the quantum theory. Howard Stein. (shrink)

Pierre Duhem’s (1861-1916) lifelong opposition to 19th century atomic theories of matter traditionally has been attributed to his conventionalist and/or positivist philosophy of science. Relatively recently, the traditional view has been challenged by the new claim that Duhem’s opposition to atomism was due to the precarious state of atomic theories at the beginning of the 20th century. In this paper, I present some of the difficulties with both the traditional and the new interpretation of Duhem’s opposition to atomism, and provide (...) a new framework in which to understand Duhem's rejection of atomic hypotheses. I argue that although not positivist, instrumentalist, or conventionalist, Duhem’s philosophy of physics was not compatible with belief in unobservable atoms and molecules. The key for understanding Duhem’s resistance to atomism during the final phase of his career is the historicist arguments he presented in support of his ideal of physics. (shrink)

In this essay I examine various aspects of the nearcentury-long debate concerning the conceptualfoundations of quantum mechanics and the problems ithas posed for physicists and philosophers fromEinstein to the present. Most crucial here is theissue of realism and the question whether quantumtheory is compatible with any kind of realist orcausal-explanatory account which goes beyond theempirical-predictive data. This was Einstein's chiefconcern in the famous series of exchanges with NielsBohr when he refused to accept the truth orcompleteness of a doctrine (orthodox QM) (...) which ruledsuch questions to be strictly inadmissible. I discussthe later history of quantum-theoretical debate withparticular reference to the issue of nonlocality,i.e., the phenomenon of superluminal(faster-than-light) interaction betweenwidely-separated particles. Then I show how thestandard `Copenhagen' interpretation of QM hasinfluenced current anti-realist orontological-relativist approaches to philosophy ofscience. Indeed, there are clear signs that somephilosophers have retreated from a realist positionvery largely in response to just these problems. So itis important to ask exactly why – on what scientificor philosophical grounds – any preferred alternative(causal-realist) construal should have been ruled outas a matter of orthodox QM wisdom. Moreconstructively, my paper presents various arguments infavour of one such alternative, the `hidden-variables'theory developed since the early 1950s by David Bohmand consistently marginalised by proponents of theCopenhagen doctrine. (shrink)

The logical empiricists knew that scientific theories sometimes arise out of the attempt to reconcile or unify two existing theories. They also thought that, at best, old theories would be retained as approximations to their successors. Kuhn lost both insights when he rejected the logical empiricists' formal approach in favor of an exclusively historical and psychological one. But when Putnam tried to restore such ideas he failed to provide them with the historical support they require. An account of revolutionary unifications (...) is defended as reconciling Putnam's realist ideas about methodology with Kuhn's historical approach. (shrink)

Summary In this report on the present state of the discussion about the interpretation of quantum mechanics an attempt is made to provide an idea of the philosophical relevance of the foundations of physics. A simplified model of the measuring process is given which shows the difficulties in the interpretation of quantum mechanics. It is argued against Bohr's solution (also in a version of H. Putnam). Two examples show possible philosophical consequences of quantum mechanics: The variety of quantum logics challenges (...) the foundations of logic, the paradox of Einstein, Podolsky and Rosen (with Bell's inequality) may be interpreted along the lines of holism. Against alleged refutations of realism by means of quantum mechanics, a realist standpoint is maintained. A proper interpretation of quantum mechanics from an epistemological point of view seems still to be lacking. (shrink)

The author considers the empirical component of physical theories. He studies the origin and development of the theory of physical experiment, the structure and gnoseological hypotheses of the measuring process, as well as the relativity principle concerning the measuring equipment. Examples of modern physical theories are used in order to demonstrate the influence of experimental facts on the formation and development, verification and accepting of these theories in the structure of scientific systems. The role of accidental experimental facts in this (...) process is also the subject. (shrink)