Despite many attempts to achieve an adequate definition of living systems by means of a set of necessary and sufficient conditions, the opinion that such an enterprise is inexorably destined to fail is increasingly gaining support. However, we believe options do not just come down to either having faith in a future success or endorsing skepticism. In this paper, we aim to redirect the discussion of the problem by shifting the focus of attention from strict definitions towards a philosophical framework (...) that allows conceiving of living systems as a natural kind, but whereby natural kinds are not to be defined by fixed necessary and sufficient conditions. We argue for a property-cluster kind approach according to which living systems constitute a natural kind with vague boundaries, capable of changing, and whose members do not need to instantiate every property. We draw from Boyd’s homeostatic property-cluster theory and introduce two modifications, one regarding homeostatic mechanisms and another related to the scientific role of kinds. Thus, our view overcomes some difficulties of Boyd’s theory and we are able to account for the natural kindhood of living things. We also emphasize the most appealing features of our approach for specific research fields and address three objections to this sort of approach. (shrink)

Natural kind concepts have the function of tracking categories that exist independently of our beliefs and purposes. But not all ways of tracking categories in the natural world involve conceiving of them as natural kinds. Anthropic concepts represent groups of natural, mind‐independent entities that are apt for serving various human interests, goals, and projects. They represent the natural world under a practical mode of presentation, as a set of material resources that can be transformed to further a host of functions (...) and ends. I argue that cross‐cultural studies of traditional ecological knowledge provide evidence that many chemical, mineral, and biological concepts that are frequently taken to be natural kind concepts turn out on closer inspection to be anthropic concepts. Anthropic concepts are distinguished from artifact concepts, and a form of realism about the anthropic kinds that they refer to is defended. (shrink)

The paper presents two objections against Putnam’s Twin Earth argument, which was intended to secure semantic externalism. I first claim that Putnam’s reasoning rests on two assumptions and then try to show why these assumptions are contentious. The first objection is that, given what we know about science, it is unlikely that there are any natural-kind terms whose extension is codetermined by a small set of microstructures required by Putnam’s indexical account of extension determination. The second objection is that there (...) may not be a plausible concept of a speech community whose adoption would classify Oscar and Twin Oscar as members of different speech communities and, at the same time, render Oscar and Twin Oscar as being in the same psychological state. I contend that Putnam’s argument fails because both objections are justified. (shrink)

The article examines the role of natural kinds in semantic theorizing, which has largely been conducted in isolation from relevant work in science, metaphysics, and philosophy of science. We argue that the Kripke–Putnam account of natural kind terms, despite recent claims to the contrary, depends on a certain metaphysics of natural kinds; that the metaphysics usually assumed—micro-essentialism—is untenable even in a ‘placeholder’ version; and that the currently popular homeostatic property cluster theory of natural kinds is correct only to an extent (...) that fails to vindicate the Kripke–Putnam account. This undermines the metasemantics required for anti-descriptivist semantics. _1_ Introduction _2_ From Semantics to Metaphysics _3_ Metaphysics, Part I: The Demise of Micro-essentialism _3.1_ Original micro-essentialism _3.2_ Placeholder essentialism _4_ Metaphysics, Part II: Homeostatic Property Cluster Theory _5_ Prospects for Natural Kind Term Semantics. (shrink)

Following Kripke and Putnam, the received view of chemical kinds has been a microstructuralist one. To be a microstructuralist about chemical kinds is to think that membership in said kinds is conferred by microstructural properties. Recently, the received microstructuralist view has been elaborated and defended, but it has also been attacked on the basis of complexities, both chemical and ontological. Here, I look at which complexities really challenge the microstructuralist view; at how the view itself might be made more complicated (...) in order to accommodate such challenges; and finally, at what this increasingly complicated picture implies for our standard assessment of chemical kindhood—primarily, for the widespread assumption that chemical kinds in general are more neat and tidy than those messy biological ones. _1_ The Received View _2_ A Taxonomy of Chemical Kinds _3_ Atomic Number _4_ H2O, H3O+, OH−, and More _5_ Complicating the Microstructuralist Picture _6_ Concrete and Other Mixtures _7_ Macromolecules, Especially Proteins _8_ Abandoning Sameness of Elemental Composition _9_ Not So Different after All. (shrink)

In robustness analysis, hypotheses are supported to the extent that a result proves robust, and a result is robust to the extent that we detect it in diverse ways. But what precise sense of diversity is at work here? In this paper, I show that the formal explications of evidential diversity most often appealed to in work on robustness – which all draw in one way or another on probabilistic independence – fail to shed light on the notion of diversity (...) relevant to robustness analysis. I close by briefly outlining a promising alternative approach inspired by Horwich’s (1982) eliminative account of evidential diversity. (shrink)

In learning chemistry at the entry level, many learners labor under misconceptions about the subject matter that are so fundamental that they are typically never addressed. A fundamental misconception in chemistry appears to arise from an adding of existing phenomenal concepts to newly-acquired chemical concepts, so that beginning learners think of chemical entities as themselves having the very same ‘macro’ properties that we observe through the senses. Those who teach or practice chemistry never acquire these misconceptions because they were able (...) to naturally pick up the nature of the subject to begin with. But as a result, they remain unaware of the foundational assumptions and understanding that they operate with and that many beginning learners persistently lack. Thus, a systematic picture of the workings of chemical theory as they relate to observable phenomena needs to be elucidated so that the attention of chemical educators is drawn to the fundamental understanding of the subject that they already possess and that beginning learners of chemistry lack, so that beginning learners can be given the opportunity to gain an understanding of how chemical explanations are in general related to observable phenomena. The ‘layered’ way in which chemical and physical entities are related to each other within chemical theory can also be clarified in this way. To afford this picture, the philosophical concepts of supervenience and emergence are explained and applied to chemistry, as philosophers of chemistry have already done. The result provides a model for teaching chemistry that, if consistently applied, has the potential to greatly enhance fundamental understanding of the subject matter. (shrink)

Should religious believers proportion their religious beliefs to their evidence? They should: Religious faith is better, ceteris paribus, when the beliefs accompanying it are evidence-proportioned. I offer two philosophical arguments and a biblical argument. The philosophical arguments conclude that love and trust, two attitudes belonging to faith, are better, ceteris paribus, when accompanied by evidence-proportioned belief, and that so too is the faith in question. The biblical argument concludes that beliefs associated with faith, portrayed in the Hebrew Bible and the (...) New Testament, are typically, and normatively, exhorted on the basis of evidence. I hope to convince religious believers and nonbelievers alike that religious beliefs should be evidence-proportioned. (shrink)

Science depends on judgments of the bearing of evidence on theory. Scientists must judge whether an observation or the result of an experiment supports, disconfirms, or is simply irrelevant to a given hypothesis. Similarly, scientists may judge that, given all the available evidence, a hypothesis ought to be accepted as correct or nearly so, rejected as false, or neither. Occasionally, these evidential judgments can be made on deductive grounds. If an experimental result strictly contradicts a hypothesis, then the truth of (...) the data deductively entails the falsity of the hypothesis. In the great majority of cases, however, the connection between evidence and hypothesis is non-demonstrative, or inductive. In particular, this is so whenever a general hypothesis is inferred to be correct on the basis of the available data, since the truth of the data will not deductively entail the truth of the hypothesis. It always remains possible that the hypothesis is false even though the data are correct. (shrink)

This article, which is intended both as a position paper in the philosophical debate on natural kinds and as the guest editorial to this thematic issue, takes up the challenge posed by Ian Hacking in his paper, “Natural Kinds: Rosy Dawn, Scholastic Twilight.” Whereas a straightforward interpretation of that paper suggests that according to Hacking the concept of natural kinds should be abandoned, both in the philosophy of science and in philosophy more generally, we suggest that an alternative and less (...) fatalistic reading is also possible. We argue that abandoning the concept of natural kinds would be premature, as it still can do important work. Our concern is with the situation in the (philosophy of the) life sciences. Against the background of this concern we attempt to set something of an agenda for future research on the topic of natural kinds in the (philosophy of the) life sciences. (shrink)

The present paper focuses on essentialism about natural kinds as a case study in order to illustrate this more general point. Saul Kripke and Hilary Putnam famously argued that natural kinds have essences, which are discovered by science, and which determine the extensions of our natural kind terms and concepts. This line of thought has been enormously influential in philosophy, and is often taken to have been established beyond doubt. The argument for the conclusion, however, makes critical use of intuitions, (...) and I note that the intuitions are of the sort had by preschool children, and that they are traceable to a deep-seated cognitive outlook, which is often called “psychological essentialism.” Further, if we did not have such a cognitive outlook or implicit belief set—a belief set which is in fact in place by at least age 4—then we would not have the relevant philosophical intuitions. In light of this, I consider the question of whether natural kinds actually have scientifically discovered or discoverable essences, and whether these putative essences could determine the extensions of our terms and concepts as Kripke, Putnam, and many others have supposed. In fact, a number of philosophers of biology and chemistry have argued that biological and chemical kinds do not have such essences, yet these arguments—particularly in the case of chemistry—have not been assimilated by philosophers more generally. The reason for this poor assimilation is, I suggest, that the Kripke/Putnam view is just so intuitive. But this fact, I argue, is due to a deep-seated cognitive bias, rather than to any special insight into the nature of reality. (shrink)

Some scientific categories seem to correspond to genuine features of the world and are indispensable for successful science in some domain; in short, they are natural kinds. This book gives a general account of what it is to be a natural kind and puts the account to work illuminating numerous specific examples.

I criticize the treatment of natural kinds as some sort of object, advocated in a recent paper by Alexander Bird. The arguments he gives for regimenting an illustrative statement featuring chemical kinds in his preferred manner are not conclusive, and his criticisms of an alternative strategy involving universally quantified sentences fail. This is important because of the widespread but poorly supported assumption that expressions of natural kinds should be treated as singular referring terms.

It is commonly assumed that natural kind terms constitute a distinct semantic category. This idea emerged during the 1970's following Kripke's and Putnam's well-known remarks on natural kind terms. The idea has stayed with us, although it is now recognized that the issues are considerably more complex than initially thought. Thus, it has become clear that much of Kripke's and Putnam's discussions were based on rather simplified views of natural kinds. It also turns out that the semantic issues are less (...) straightforward than assumed - in particular, it is far from clear what it might mean to say that a kind term is rigid. Strikingly, however, these worries have not done much to undermine the confident assumption that natural kind terms form a special semantic category. In the paper I try to shake that confidence. I argue that although natural kind terms are no doubt important (for instance, from an explanatory point of view), we are certainly not warranted in concluding that they form a separate, semantic category among the kind terms. (shrink)

Humeans and non-Humeans reasonably agree that there may be necessary connections between entities that are identical or merely partly distinct—between, e.g., sets and their individual members, fusions and their individual parts, instances of determinates and determinables, members of certain natural kinds and certain of their intrinsic properties, and (especially among physicalists) certain physical and mental states. Humeans maintain, however, that as per “Hume’s Dictum”, there are no necessary connections between entities that are wholly distinct;1 and in particular, no necessary causal (...) connections between such entities (even when the background conditions requisite for causation are in place). The Humean’s differential treatment appears principled, in reflecting that commonly accepted necessary connections involve constitutional relations, whereas wholly distinct entities (notably, causes and effects) do not constitute each other. I’ll argue, however, that the appearance of principle is not genuine, as per the following conditional: Constitutional→Causal: If one accepts certain constitutional necessities, one should accept certain causal necessities. This result provides needed leverage in assessing the two main frameworks in the metaphysics of science, treating natural kinds, causes, laws of nature, and the like. These frameworks differ primarily on whether Hume’s Dictum is taken as a working constraint on theorizing; and it has proved difficult for either side to criticize the other without presupposing their preferred stance on the dictum, hence talking past one another. The arguments for Constitutional→Causal are based, however, in general and independent considerations about what facts in the world might plausibly warrant our beliefs in certain constitutional necessities involving broadly scientific entities. The Humean can respond to these arguments, which reveal a deep tension in their view, at attendant costs of implausibilty and adhocery. The non-Humean framework doesn’t face any such tension between constitutional and causal necessities, however, and so in this respect comes out ahead. (shrink)

Externalism is widely endorsed within contemporary philosophy of mind and language. Despite this, it is far from clear how the externalist thesis should be construed and, indeed, why we should accept it. In this entry I distinguish and examine three central types of externalism: what I call foundational externalism, externalist semantics, and psychological externalism. I suggest that the most plausible version of externalism is not in fact a very radical thesis and does not have any terribly interesting implications for philosophy (...) of mind, whereas the more radical and interesting versions of externalism are quite difficult to support. (shrink)

What are the criteria determining the individuation of chemical kinds? Recent philosophical discussion, which puts too much emphasis on microstructure, seems to presuppose a reductionist conception not motivated by the scientific facts. The present article traces the development of the traditional notion of a substance with the rise of modern chemistry from the end of the 18th century with a view to correcting this speculative distortion.

From organic synthesis to quantum chemical calculation, chemists interact with chemical substances in a wide variety of ways. But what even is a chemical substance? My aim is to propose a notion of chemical substance that is consistent with the way in which chemical substances are individuated in chemistry, addressing gaps in previous conceptions of chemical substance. Water is employed as a case study to develop the account, not only because it is a familiar example of a chemical substance, but (...) also because its structural peculiarities make it an ideal test case for drawing out potential issues and limitations. Examining four distinct views of chemical substance—the microstructural, thermodynamic, purification, and a functional/relational account—I conclude that each has considerable drawbacks when used as a standalone concept. However, these accounts are not rendered obsolete, but are combined into a semi-pluralist conceptual patchwork. My interactive account of chemical substance is consistent with existing substance descriptions and chemical practice. (shrink)

Are acids natural kinds? Or are they merely relevant kinds? Although acidity has been one of the oldest and most important concepts in chemistry, surprisingly little ink has been spilled on the natural kind question. I approach the question from the perspective of microstructural essentialism. After explaining why both Brønsted acids and Lewis acids are considered functional kinds, I address the challenges of multiple realization and multiple determination. Contra Manafu and Hendry, I argue that the stereotypical properties of acids are (...) not multiply realized. Instead, given the equivalence between the proton-donating and electron-accepting mechanisms of Brønsted and Lewis, respectively, I show that acidity as a property type can be identified with a unique microstructural property, namely the presence of a LUMO or other low energy empty orbital. In doing so, I defend the view that the Lewis theory encompasses Brønsted–Lowry, and that all Brønsted acids are also Lewis acids. Contra Hacking and Chang, I thus maintain that the different concepts of acidity do not crosscut, and that the hierarchy requirement is met. Finally, by characterizing natural kinds as powerful objects and by adopting a dispositional view of functions, I illustrate how the microessentialist can make sense of the latent and relational character of most acids. In sum, I contend that acids are genuine natural kinds, even for the microstructural essentialist. (shrink)

Are acids natural kinds? Or are they merely relevant kinds? Although acidity has been one of the oldest and most important concepts in chemistry, surprisingly little ink has been spilled on the natural kind question. I approach the question from the perspective of microstructural essentialism. After explaining why both Brønsted acids and Lewis acids are considered functional kinds, I address the challenges of multiple realization and multiple determination. Contra Manafu and Hendry, I argue that the stereotypical properties of acids are (...) not multiply realized. Instead, given the equivalence between the proton-donating and electron-accepting mechanisms of Brønsted and Lewis, respectively, I show that acidity as a property type can be identified with a unique microstructural property, namely the presence of a LUMO or other low energy empty orbital. In doing so, I defend the view that the Lewis theory encompasses Brønsted--Lowry, and that all Brønsted acids are also Lewis acids. Contra Hacking and Chang, I thus maintain that the different concepts of acidity do not crosscut, and that the hierarchy requirement is met. Finally, by characterizing natural kinds as powerful objects and by adopting a dispositional view of functions, I illustrate how the microessentialist can make sense of the latent and relational character of most acids. In sum, I contend that acids are genuine natural kinds, even for the microstructural essentialist. (shrink)

Some philosophers understand natural kinds to be the categories which are constraints on enquiry. In order to elaborate the metaphysics appropriate to such an account, I consider the complicated history of scurvy, citrus, and vitamin C. It may be tempting to understand these categories in a shallow way (as mere property clusters) or in a deep way (as fundamental properties). Neither approach is adequate, and the case instead calls for middle-range ontology: starting from categories which we identify in the world (...) and elaborating their structure, but not pretending to jump ahead to a complete story about fundamental being. (shrink)

The purpose of this article is to show that the customary understanding of epistemic progress as a kind of belief change is incomplete and that conceptual change has to be acknowledged as a crucial driving force in epistemic progress. The author’s argument for the epistemological relevance of conceptual change proceeds as follows. First, he develops an account of conceptual change that clearly distinguishes conceptual change from belief change. He then takes a closer look at two kinds of conceptual change that (...) are of special interest from an epistemological point of view. He calls them “disclosing” conceptual change and “revisionary” conceptual change. He then shows that the idea of epistemic value that demarcates the realm of epistemological inquiry applies to concepts and conceptual change. (shrink)

Philosophical treatments of natural kinds are embedded in two distinct projects. I call these the philosophy of science approach and the philosophy of language approach. Each is characterized by its own set of philosophical questions, concerns, and assumptions. The kinds studied in the philosophy of science approach are projectible categories that can ground inductive inferences and scientific explanation. The kinds studied in the philosophy of language approach are the referential objects of a special linguistic category—natural kind terms—thought to refer directly. (...) Philosophers may hope for a unified account addresses both sets of concerns. This paper argues that this cannot be done successfully. No single account can satisfy both the semantic objectives of the philosophy of language approach and the explanatory projects of the philosophy of science approach. After analyzing where the tensions arise, I make recommendations about assumptions and projects that are best abandoned, those that should be retained, and those that should go their separate ways. I also recommend adopting the disambiguating terminology of “scientific kinds” and “natural kinds” for the different notions of kinds developed in these different approaches. (shrink)

The new externalist picture of natural kind terms due to Kripke, Putnam, and others has become quite popular in philosophy. Many philosophers of science have remained sceptical. Häggqvist and Wikforss have recently criticised this view severely. They contend it depends essentially on a micro-essentialist view of natural kinds that is widely rejected among philosophers of science, and that a scientifically reasonable metaphysics entails the resurrection of some version of descriptivism. It is argued in this paper that the situation is not (...) quite as dark for the new theory of reference as many critics suggest. There are several distinct questions here which should not be conflated and ought to be dealt with one by one. Descriptivism remains arguably problematic. (shrink)

Alexander Bird (2001; 2002; 2007) offers a powerful argument showing that, regardless of whether necessitarianism or contingentism about laws is true, salt necessarily dissolves in water. The argument is that the same laws of nature that are necessary for the constitution of salt necessitate the solubility of salt. This paper shows that Bird’s argument faces a serious objection if the possibility of emergentism – in particular, C. D. Broad’s account – is taken into account. The idea is (roughly) that some (...) emergent laws in some possible worlds may disrupt the solubility of salt without disrupting its constitution. (shrink)

This paper challenges a popular thesis which we call the explanatory primitiveness thesis (for short, EPT), namely, the thesis that identities leave no logical space wherein explanatory questions may be formulated and explanatory gaps may reside. We argue that while EPT is, in all likelihood, flawless when the relevant domain consists of identity statements flanked by proper names of individuals it is a mistake to hold that the thesis generalizes to cover all identity statements. In particular, we argue that EPT (...) fails decisively with respect to an important class of identity statements, viz., those in which natural kinds are identified across different theoretical levels (i.e., the so-called inter-level type-identities). If correct, our result shows EPT to be much more limited in scope than is usually supposed. Moreover, and perhaps more significantly, it shows that there is no inherent absurdity in the idea that certain type-identity statements, in particular psychophysical type-identity statements, suffer from an explanatory gap. (shrink)

Philosophers have been quarrelling for ages over the correct understanding of the identity relation and its applications, but seldom have they discussed the identity of foods, including beverages under this herd. Taking wine as a working example, the present study shows that foods call attention over unnoticed metaphysical difficulties, most importantly the role of authenticity in ascertaining the identity of an individual and the possibility of identity being determined by a collectivity of people. More in details, the paper examines the (...) relationship between a rank of wines and its specific instances, that is, on what grounds some wine is of a certain rank. A “rank of wines” here stands for wines that are identical under some respect, be it the area of production, the style, the color, the variety, and so forth. Extant wine labels are taken as the best candidates to carve out a class of wine ranks that is metaphysically prior to any other; the analysis focuses on geographic indications because of the extensive discussion they have generated, but the morals here drawn extend also to other classes of wine ranks, such as those utilized by wine experts. After some introductory remarks (§1), the case is made that the identity of wines is established through judgments of authenticity (§2). Issues of authenticity are then discussed through the special case of geographic indications (§3). Two different views on how to justify the attribution of a geographic indication are presented and criticized; those rest respectively on terroir (§3.1) and chemical composition (§3.2). The last section (§4) argues for a conventionalist view on wine identity. Distancing itself from conventionalist proposals advanced to favor industrial wine production, the view defended here ties the identity of a wine to collective expert judgments of authenticity that are based on the extensive pleasure of the product. (shrink)

While philosophers tend to consider a single type of causal history, biologists distinguish between two kinds of causal history: evolutionary history and developmental history. This essay studies the peculiarity of development as a criterion for the individuation of biological traits and its relation to form, function, and evolution. By focusing on examples involving serial homologies and genetic reprogramming, we argue that morphology (form) and function, even when supplemented with evolutionary history, are sometimes insufficient to individuate traits. Developmental mechanisms bring in (...) a novel aspect to the business of classification—identity of process-type—according to which entities are type-identical across individuals and natural kinds in virtue of the fact that they form and develop through similar processes. These considerations bear important metaphysical implications and have potential applications in several areas of philosophy. (shrink)

Paul Needham has claimed in several recent papers that Dalton’s chemical atomism was not explanatory. I respond to his criticism of Dalton by arguing that explanation admits of degrees and that under a view that allows for a spectrum of explanatory value, it is possible to see ample worth in Dalton’s atomistic explanations. Furthermore, I argue that even Duhem, who rejected atomism, acknowledged the explanatory worth of Dalton’s atomism.

It is widely held that the meaning of certain types of terms, such as natural kind terms, is individuated externalistically, in terms of the individual's external environment. Recently a more radical thesis has emerged, a thesis we dub 'a posteriori semantics.' The suggestion is that not only does a term's meaning depend on the external environment, but so does its semantics. One motivation for this is the aim to account for cases where a putative natural kind term fails to pick (...) out a natural kind: The term may have a standard externalist semantics (if it picks out a natural kind) or a more descriptivist one (if it does not). Knowing which semantics applies will therefore require detailed empirical knowledge. This move has also been employed in cases where a singular term, such as a name, fails to have a reference. We argue that a posteriori semantics is inherently implausible, since the type of semantics common terms should be given ought not to be conditional on details of chemistry or physics. A number of difficulties for the position—'metaphysical,' epistemological, and methodological—are articulated. Finally, we suggest that a posteriori semantics misconstrues the way in which semantics is empirical. (shrink)

Two inter-linked theses are defended in this paper. One is the Duhemian theme that a rigid distinction between physical and chemical properties cannot be upheld. Duhem maintained this view not because the latter are reducible to the former, but because if physics is to remain consistent with chemistry it must prove possible to expand it to accommodate new features, and a rigid distinction would be a barrier to this process. The second theme is that naturally occurring isotopic variants of water (...) are in fact distinct substances, and naturally occurring samples of water are mixtures of these substances. For most practical purposes it is convenient to treat protium oxide, deuterium oxide, and so on, as the same chemical substance, but to insist on this as a matter of principle would stand in conflict with the first thesis. (shrink)

This paper discusses whether it can be known a priori that a particular term, such as water, is a natural kind term, and how this problem relates to Putnams claim that natural kind terms require an externalist semantics. Two conceptions of natural kind terms are contrasted: The first holds that whether water is a natural kind term depends on its a priori knowable semantic features. The second.

The present thesis explores some metaphysical issues concerning biochemical kinds and the relations between chemical and biological properties and phenomena. The main result of this thesis is that there is something sui generis about biochemical kinds. This result is motivated by two theoretical steps. The first is characterising biochemical functions as weakly emergent from the chemical structure [Chapter 3, Chapter 6]. The second is via an account for which biochemical kinds are natural categories [Chapter 4, Chapter 7]. The thesis comprises (...) four parts. Part I [Chapter 1, Chapter 2] aims to offer the methodological and conceptual tools that underpin this research. Chapter 1 presents the debate on the unity of science and the motivation of the research. Chapter 2 presents the account of natural kinds that will be used throughout the thesis. Part II [Chapter 3, Chapter 4] offers a detailed metaphysical analysis of the molecular gene. Chapter 3 argues that molecular genes are weakly emergent from nucleic acids. Chapter 4 argues that the category "molecular gene" can be deemed a natural kind, following the account presented in Chapter 2. Part III [Chapter 5, Chapter 6, Chapter 7] explores some of the themes related to biochemical kinds and generalises some of the results from Part II. Chapter 5 considers biochemical functions and how functional attribution should be interpreted for biochemical molecules. Chapter 6 considers the relation between biochemical functions and structure, spelt in terms of weak emergence and explores unity in biochemistry. Chapter 7 considers the topic of biochemical kinds per se and argues that biochemical kinds are natural categories. Part IV [Chapter 8] elucidates the main outcome and the implications that this research can have for future discussion in the philosophy and metaphysics of biochemistry and the unity of science. (shrink)

This essay critically considers the issue of natural kind essentialism. More specifically, the essay critically probes the philosophical use of chemical examples to support realism about natural kinds. My simple contention is that the natural kind debate can be understood in terms of two different cultures of academic production. These two cultures will be conceptualized using Thomas Kasulis’s distinction between intimacy and integrity as cultural orientations. Acknowledging Kasulis’s contention that, “What is foreground in one culture may be background in another”, (...) it may very well be the case that philosophers writing about chemistry place chemical practice in the background, thereby adopting the orientation of integrity. Chemists and philosophers of chemistry, on the other hand, place chemical practice at the foreground of their work, thereby adopting the orientation of intimacy. Because the intimacy orientation is grounded in chemical practice, it is preferable to the integrity orientation. Understanding the natural kinds debate from this perspective highlights the fact that the misuse of chemical examples by certain philosophers is informed by an orientation of detachment from actual chemical practice. This underscores the importance of an intimate understanding of chemical practice when deploying chemical examples in the context of philosophical discussions about ontology and metaphysics. (shrink)

In a recent critique of the doctrine of emergentism championed by its classic advocates up to C. D. Broad, Jaegwon Kim (Philosophical Studies 63:31–47, 1999) challenges their view about its applicability to the sciences and proposes a new account of how the opposing notion of reduction should be understood. Kim is critical of the classic conception advanced by Nagel and uses his new account in his criticism of emergentism. I question his claims about the successful reduction achieved in the sciences (...) and argue that his new account has not improved on Nagel’s and that the critique of emergentism he bases on it is question-begging in important respects. (shrink)

In The Philosophy of Philosophy, Tim Williamson has offered a sophisticated account of thought experiments and of modal epistemology. More recently, he has also engaged in a variant of the so-called ‘expertise defence’ of traditional philosophical methodology. In this paper I argue that if Williamson’s account of thought experiments and of modal epistemology is right, this seriously undermines his version of the expertise defence.

Recently, macroscopic accounts of chemical kind individuation have been proposed as alternatives to the microstructural essentialist account advocated by Kripke, Putnam, and others. These accounts argue that individuation of chemical kinds is based on macroscopic criteria such as reactivity or thermodynamics, and they challenge the essentialism that grounds the Kripke-Putnam view. Using a variety of chemical examples, I argue that microstructure grounds these macroscopic accounts, but that this grounding need not imply essentialism. Instead, kinds are individuated on the basis of (...) similarity of reactivity between substances, and microstructure explains similarity of reactivity. (shrink)

The Aristotelian distinction between actual and potential presence of a substance in a mixture forms part of a conception of mixture which stands in contrast to atomist and Stoic theories as propounded by the ancients. But the central ideas on which these theories are built need not be combined and opposed to one another in precisely the ways envisaged by these ancient theories. This is well illustrated by Duhem, who maintained the Aristotelian idea that the original ingredients are only potentially, (...) and not actually, present in a mixture, but who sided with the Stoics and against Aristotle on the possibility of co-occupancy. I have argued that the Stoic theory cannot dispense with some such notion as the Aristotelian conception of potentiality in allowing the elements to be actually present in a mixture. Here I suggest that some such Aristotelian notion must be at work in a more modern atomic conception of matter if this is to allow elemental substances to be actually present in compounds, which I think is how compounds are usually understood. Analogous issues arise regarding the status of solutions and their components. (shrink)

According to microessentialism, it is necessary to resort to microstructure in order to adequately characterise chemical substances such as water. But the thesis has never been properly supported by argument. Kripke and Putnam, who originally proposed the thesis, suggest that a so-called stereotypical characterisation is not possible, whereas one in terms of microstructure is. However, the sketchy outlines given of stereotypical descriptions hardly support the impossibility claim. On the other hand, what naturally stands in contrast to microscopic description is description (...) in macroscopic terms, and macroscopic characterisations of water are certainly possible. This suffices to counter the claim that microdescriptions are necessary. Whether it counters the impossibility claim depends on whether all macroscopic descriptions are stereotypical (stereotypical descriptions presumably being macroscopic). In so far as systematic import of “stereotypical” can be determined, it would seem not. But some macroscopic characterisations have definite affinity with everyday knowledge, which presumably stands in conflict with the spirit of the impossibility claim. Since what is characterised are properties expressed by predicates like “is water”, the necessity of identity has no bearing here, and matters of interpretation pose problems for claims to the effect that science fixes the extension of “water” as ordinarily understood. (shrink)

In defending semantic externalism, philosophers of language have often assumed that there is a straightforward connection between scientific kinds and the natural kinds recognized by ordinary language users.1 For example, the claim that water is H2O assumes that the ordinary language kind water corresponds to a chemical kind, which contains all the molecules with molecular formula H2O as its members. This assumption about the coordination between ordinary language kinds and scientific kinds is important for the externalist program, because it is (...) what allows us to discover empirically the extensions of ordinary language kind terms. (shrink)

ABSTRACT I propose a division of the literature on natural kinds into metaphysical worries, semantic worries, and methodological worries. I argue that the latter set of worries, which concern how classification influences scientific practices, should occupy centre stage in philosophy of science discussions about natural kinds. I apply this methodological framework to the problems of classifying chemical species and nanomaterials. I show that classification in nanoscience differs from classification in chemistry because the latter relies heavily on compositional identity, whereas the (...) former must consider additional properties, namely, size, shape, and surface chemistry. I use this difference to argue for a scale-dependent theory of scientific classification. _1_ Introduction _2_ The Methodological Problem of Kinds _3_ Chemical Kindhood: Reactivity, Microstructure, and the Structure–Property Paradigm _4_ Scale-Dependence and Nanoscale Kinds _5_ Conclusion. (shrink)

In the addenda to his Naming and Necessity, Kripke provides an account of how necessary aposteriori statements are possible. In such a case, there is an apriori general principle telling us that it is necessary if true at all. Though straightforward in its broad compass, this account faces two obvious questions in its application: in each case of necessary aposteriori statements, what is the underlying principle and how is it established apriori? I treat these questions with respect to theoretical identity (...) statements concerning chemical substances, such as ‘water is H2OH2O’. I argue that the general principle underlying the necessity of the statements is that if a chemical substance has a certain chemical composition, then it could not have had any other chemical composition. Then I defend the view that the principle is a conceptual truth by providing a novel derivation of it from the theoretical concept of chemical substance with a sufficient level of formal rigor. The logical principles required for the derivation will also be stated and defended. (shrink)

In this essay I critically examine the role of entropy of mixing in articulating a macroscopic criterion for the sameness and difference of chemical substances. Consider three cases of mixing in which entropy change occurs: isotopic variants, spin isomers, and populations of atoms in different orthogonal quantum states. Using these cases I argue that entropy of mixing tracks differences between physical states, differences that may or may not correspond to a difference of substance. It does not provide a criterion for (...) the sameness and difference of substance that is appropriate to chemistry. (shrink)

The bulk of Duhem's writing which bears on the understanding of mixtures suggests he adopted an Aristotelian position which he opposed only to the atomic view. A third view from antiquity-that of the Stoics-seems not to be taken into account. But his lines of thought are not always as explicit as could be wished. The Stoic view is considered here from a perspective which Duhem might well have adopted. This provides a background against which his somewhat unorthodox Aristotelianism might be (...) understood. (shrink)

In this article I assess the problems and prospects of a microstructural approach to chemical substances. Saul Kripke and Hilary Putnam famously claimed that to be gold is to have atomic number 79 and to be water is to be H2O. I relate the first claim to the concept of element in the history of chemistry, arguing that the reference of element names is determined by atomic number. Compounds are more difficult: water is so complex and heterogeneous at the molecular (...) level that `water is H2O' seems false under some interpretations. I sketch a response to this problem. (shrink)

Häggqvist and Wikforss argued that in the case of so-called natural kind terms, semantic externalism relies on an untenable metaphysics of kinds: microessentialism. They further claimed that this metaphysics fails, for largely empirical reasons. Focussing on the case of water, Hoefer and Martí European Journal for the Philosophy of Science, 9, rejoin that suitably construed, microessentialism is correct. I argue that their defence of microessentialism fails.