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Ursula Klein has argued that Geoffroy’s table of chemical affinities, published in 1718, marked the emergence of the concepts of chemical compound and chemical combination central to chemistry. In this paper her position is summarised and then modified to render it immune to criticism that has been levelled against it. The essentials of Geoffroy’s chemistry are clarified and adapted to Klein’s picture by way of a detailed comparison of it with Boyle’s corpuscular chemistry that proceeded Geoffroy’s by over half a (...) |
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It is instructive to view the scientific revolution from the point of view of Robert Boyle’s distinction between intermediate and ultimate causes. From this point of view, the scientific revolution involved the identification of intermediate causes and their investigation by way of experiment as opposed to the specification of ultimate causes of the kind involved in the corpuscular matter theories of the mechanical philosophers. The merits of this point of view are explored in this paper by focussing on the hydrostatics (...) |
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We can distinguish ‘mechanical’ in the strict sense of the mechanical philosophers from ‘mechanical’ in the common sense. My claim is that Boyle's experimental science owed nothing to, and offered no support for, the mechanical philosophy in the strict sense. The attempts by my critics to undermine my case involve their interpreting ‘mechanical’ in something like the common sense. I certainly accept that Boyle's experimental science was productively informed by mechanical analogies, where ‘mechanical’ is interpreted in a common sense. But (...) |
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This paper argues that, contrary to the claims of Alan Chalmers, Boyle understood his experimental work to be intimately related to his mechanical philosophy. Its central claim is that the mechanical philosophy has a heuristic structure that motivates and gives direction to Boyle's experimental programme. Boyle was able to delimit the scope of possible explanations of any phenomenon by positing both that all qualities are ultimately reducible to a select group of mechanical qualities and that all explanations of natural phenomena (...) |
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Robert Boyle thought that his scientific achievements in pneumatics and chemistry depended on, and thus provided support for, his mechanical philosophy. In a recent article in this journal, Alan Chalmers has challenged this view. This paper consists of a reply to Chalmers on two fronts. First it tries to specify precisely what ‘the mechanical philosophy’ meant for Boyle. Then it goes on to defend, against Chalmers, the view that Boyle's science does support his natural philosophy.Keywords: Robert Boyle; Mechanical philosophy; Reductionism. |
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The ArgumentMost historians of science share the conviction that the incorporation of the corpuscular theory into seventeenth-century chemistry was the beginning of modern chemistry. My thesis in this paper is that modern chemisty started with the concept of the chemicl compound, which emerged at the end of the seventeenth and the beginning of the eighteenth century, without any signifivant influence of the corpuscular theory. Rather the historical reconstruction of the emergence of this concept shows that it resulted from the reflection (...) |
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In chemistry one observes different relationships [rapports] between different bodies, which act such that they unite easily with one another. These relationships have their degrees and their laws. One observes their different insofar as, among several materials are confounded and that have some disposition to unite together, one perceives that one of these substances always unites constantly with a certain other [substance] preferably to all others. |
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