Towards the end of the 19th century there were those who wished to see the kinetic theory abandoned. This paper attempts to show that this reaction was primarily due to philosophical objections rather than the result of scientific difficulties encountered by the kinetic theory. First the relevant philosophical background is examined as well as the relation between the kinetic theory and thermodynamics. Next the scientific difficulty known as the specific heats ratio anomaly is discussed and finally Boltzmann's philosophy of science (...) is examined. (shrink)

The influential French chemist Marcelin Berthelot spoke against the use of Dalton's atomic theory and Avogadro's hypothesis in the second half of the nineteenth century. This paper argues that Berthelot conceded that atomism might be acceptable as a system of conventions, but he feared the power of such conventions in constructing a realistic picture of atoms which was not warranted empirically. Equally, Berthelot's anti-atomism was a last-ditch effort to assert the place of chemistry within the tradition of natural history and (...) to deny the possible reduction of chemical science to the laws of nineteenth-century physics. (shrink)

An exposition of Pierre Duhem’s formulation of the structure of chemical substances as expressed by their formulas is given, presenting it as a development of his essentially Aristotelian view of mixtures. Duhem’s masterly development of the subject displays an eye for logical clarity familiar from his work in thermodynamics but applied here to the extraction of what he regarded as true from the history of chemistry. Though no longer defensible, the account has a conceptual interest in its own right and (...) illuminates a less frequently discussed side of Duhem’s views. (shrink)

Late nineteenth‐century opponents of atomism questioned whether the evidence required any notion of an atom. In this spirit, Duhem developed an account of the import of chemical formulas that is clearly neutral on the atomic question rather than antiatomistic. The argument is supplemented with specific inadequacies of atomic theories of chemical combination and considerably strengthened by the theory of chemical combination provided by thermodynamics. Despite possible counterevidence available at the time, which should have tempered some of Duhem's concluding remarks, there (...) was no atomic theory of chemical combination, which is wholly a product of the twentieth century. †To contact the author, please write to: Department of Philosophy, University of Stockholm, SE‐106 91 Stockholm, Sweden; e‐mail: [email protected]. (shrink)

Philosophers frequently cite Dalton's chemical atomism, and its nineteenth century developments, as a prime example of inference to the best explanation. This was a controversial issue in its time. But the critics are dismissed as positivist‐inspired antirealists with no interest in explanation. Is this a reasonable assessment?

Nancy Cartwright has drawn attention to how explanations are actually given in mathematical sciences. She argues that these procedures support an antirealist thesis that fundamental explanatory laws are not true. Moreover, she claims to be be essentially following Duhem's line of thought in developing this thesis. Without wishing to detract from the importance of her observations, it is suggested that they do not necessarily require the antirealist thesis. The antirealist interpretation of Duhem is also disputed. It is argued that Duhemian (...) points, often understood antirealistically, bear a realist construal, and that antirealist interpretations of Duhem typically run into problems of consistency or of reducing his position to absurdity. (shrink)

This article was first published as “Notation atomique et hypothèses atomistiques”, Revue des questions scientifiques, 31 (1892), 391– 457. It is the second of a series of articles Duhem was to publish in the Catholic journal Revue des questions scientifiques, in which he presents his understanding of what can justifiably be said about the structure of chemical substances as captured by chemical formulas. The argument unfolds following a broadly historical development of events throughout the course of the century which was (...) coming to a close as he wrote. He later reflected in his classic The Aim and Structure of Physical Theories – based in large part on articles which had appeared in the Revue – that “To give the history of a physical principle is at the same time to make a logical analysis of it” (p. 269). Logical analysis clearly dominates in the present article. The historical context was elaborated considerably in a later work, Le mixte et la combinaison chimique: Essai sur l’évolution d’une idée, which did not lead him to retract any aspect of his earlier position but provided a broader setting in which it could be elaborated. In particular, the Aristotelian influence, which is only hinted at here in some of the formulations (see especially the beginning of section VII) without mentioning Aristotle by name, is explicit in the later work, making Duhem’s own ontological conception a little clearer. A discussion of stereoisomerism, conspicuously absent in the present article, is also integrated into the later book. The same holds for Avogadro’s hypothesis. (shrink)

I reject the widely held view that Duhem's 1906 book La Théorie physique is a statement of instrumentalistic conventionalism, motivated by the scientific crisis at the end of the nineteenth century. By considering Duhem's historical context I show that his epistemological views were already formed before the crisis occured; that he consistently supported general thermodynamics against the new atomism; and that he rejected the epistemological views of the latter's philosophical supporters. In particular I show that Duhem rejected Poincaré's account of (...) scientific language, Le Roy's view that laws are definitions, and the conventionalist's use of simplicity as the criterion of theory choice. Duhem regarded most theory choices as decidable on empirical grounds, but made historical context the main determining factor in scientific change. (shrink)

Duhem's discussion of physical theories as natural classifications is neither antithetical nor incidental to the main thrust of his philosophy of science. Contrary to what is often supposed, Duhem does not argue that theories are better thought of as economically organizing empirical laws than as providing information concerning the nature of the world. What he is primarily concerned with is the character and justification of the scientific method, not the logical status of theoretical entities. The crucial point to notice is (...) that he took the principle of the autonomy of physics to be of paramount importance and he developed the conception of natural classification in opposition to accounts of physical theories that contravened it. (shrink)

Sometimes a theory is interpreted realistically--i.e., as literally true--whereas sometimes a theory is interpreted instrumentalistically--i.e., as merely a convenient device for summarizing, systematizing, deducing, etc., a given body of observable facts. This paper is part of a program aimed at determining the basis on which scientists decide on which of these interpretations to accept a theory. I proceed by examining one case: the nineteenth-century debates about the existence of atoms. I argue that there was a gradual transition from an instrumentalist (...) to a realistic acceptance of the atomic theory, because of gradual increases in its predictive power, the "testedness" of its hypotheses, the "determinateness" of its quantities, and because of resolutions of doubts about the acceptability of its basic explanatory concepts. (shrink)