This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

This is a companion to another paper. Together they rebut two widespread philosophical doctrines about emergence. The first, and main, doctrine is that emergence is incompatible with reduction. The second is that emergence is supervenience; or more exactly, supervenience without reduction.In the other paper, I develop these rebuttals in general terms, emphasising the second rebuttal. Here I discuss the situation in physics, emphasising the first rebuttal. I focus on limiting relations between theories and illustrate my claims with four examples, each (...) of them a model or a framework for modelling, from well-established mathematics or physics.I take emergence as behaviour that is novel and robust relative to some comparison class. I take reduction as, essentially, deduction. The main idea of my first rebuttal will be to perform the deduction after taking a limit of some parameter. Thus my first main claim will be that in my four examples (and many others), we can deduce a novel and robust behaviour, by taking the limit N→∞ of a parameter N.But on the other hand, this does not show that the N=∞ limit is “physically real”, as some authors have alleged. For my second main claim is that in these same examples, there is a weaker, yet still vivid, novel and robust behaviour that occurs before we get to the limit, i.e. for finite N. And it is this weaker behaviour which is physically real.My examples are: the method of arbitrary functions (in probability theory); fractals (in geometry); superselection for infinite systems (in quantum theory); and phase transitions for infinite systems (in statistical mechanics). (shrink)

This is one of two papers about emergence, reduction and supervenience. It expounds these notions and analyses the general relations between them. The companion paper analyses the situation in physics, especially limiting relations between physical theories. I shall take emergence as behaviour that is novel and robust relative to some comparison class. I shall take reduction as deduction using appropriate auxiliary definitions. And I shall take supervenience as a weakening of reduction, viz. to allow infinitely long definitions. The overall claim (...) of this paper will be that emergence is logically independent both of reduction and of supervenience. In particular, one can have emergence with reduction, as well as without it; and emergence without supervenience, as well as with it. Of the subsidiary claims, the four main ones are: : I defend the traditional Nagelian conception of reduction ; : I deny that the multiple realizability argument causes trouble for reductions, or ``reductionism'' ; : I stress the collapse of supervenience into deduction via Beth's theorem ; : I adapt some examples already in the literature to show supervenience without emergence and vice versa. (shrink)

In its broadest sense, "universality" is a technical term for something quite ordinary. It refers to the existence of patterns of behavior by physical systems that recur and repeat despite the fact that in some sense the situations in which these patterns recur and repeat are different. Rainbows, for example, always exhibit the same pattern of spacings and intensities of their bows despite the fact that the rain showers are different on each occasion. They are different because the shapes of (...) the drops, and their sizes can vary quite widely due to differences in temperature, wind direction, etc. There are different questions one might ask about such patterns. For instance, one might ask why the particular rainbow... (shrink)

This paper investigates the consequences for our understanding of physical theories as a result of the development of the renormalization group. Kadanoff's assessment of these consequences is discussed. What he called the ``extended singularity theorem'' poses serious difficulties for philosophical interpretation of theories. Several responses are discussed. The resolution demands a philosophical rethinking of the role of mathematics in physical theorizing.

This paper looks at emergence in physical theories and argues that an appropriate way to understand socalled “emergent protectorates” is via the explanatory apparatus of the renormalization group. It is argued that mathematical singularities play a crucial role in our understanding of at least some well-defined emergent features of the world.

Thermodynamics and Statistical Mechanics are related to one another through the so-called "thermodynamic limit'' in which, roughly speaking the number of particles becomes infinite. At critical points (places of physical discontinuity) this limit fails to be regular. As a result, the "reduction'' of Thermodynamics to Statistical Mechanics fails to hold at such critical phases. This fact is key to understanding an argument due to Craig Callender to the effect that the thermodynamic limit leads to mistakes in Statistical Mechanics. I discuss (...) this argument and argue that the conclusion is misguided. In addition, I discuss an analogous example where a genuine physical discontinuity---the breaking of drops---requires the use of infinite idealizations. (shrink)

This book is a defense of modal realism; the thesis that our world is but one of a plurality of worlds, and that the individuals that inhabit our world are only a few out of all the inhabitants of all the worlds. Lewis argues that the philosophical utility of modal realism is a good reason for believing that it is true.

This paper discusses the alleged reduction of Thermodynamics to Statistical Mechanics. It includes an historical discussion of J. Willard Gibbs' famous caution concerning the connections between thermodynamic properties and statistical mechanical properties---his so-called ``Thermodynamic Analogies.'' The reasons for Gibbs' caution are reconsidered in light of relatively recent work in statistical physics on the existence of the thermodynamic limit and the explanation of critical behavior using the renormalization group apparatus. A probabilistic understanding of the renormalization group arguments allows for a kind (...) of unification of Gibbs' approach with contemporary understanding of the reduction problem. (shrink)

We reconsider the Nagelian theory of reduction and argue that, contrary to a widely held view, it is the right analysis of intertheoretic reduction. The alleged difficulties of the theory either vanish upon closer inspection or turn out to be substantive philosophical questions rather than knock-down arguments.

Introduction: Science and Common Sense Long before the beginnings of modern civilization, men ac- quired vast funds of information about their environment. ...

Thomas S. Kuhn's classic book is now available with a new index.

In this essay, I provide an overview of the debate on infinite and essential idealizations in physics. I will first present two ostensible examples: phase transitions and the Aharonov– Bohm effect. Then, I will describe the literature on the topic as a debate between two positions: Essentialists claim that idealizations are essential or indispensable for scientific accounts of certain physical phenomena, while dispensabilists maintain that idealizations are dispensable from mature scientific theory. I will also identify some attempts at finding a (...) middle ground between the essentialists and dispensabilists camps. Finally, I will raise questions for future research on essential and infinite idealizations via the notion of exploration. (shrink)

I analyze the extent to which classical phase transitions, both first order and continuous, pose a challenge for intertheoretic reduction. My contention is that phase transitions are compatible with a notion of reduction that combines Nagelian reduction and what Thomas Nickles called Reduction2. I also argue that, even if the same approach to reduction applies to both types of phase transitions, there is a crucial difference in their physical treatment: in addition to the thermodynamic limit, in continuous phase transitions there (...) is a second infinite limit involved, which marks an important difference in the reduction of first-order and continuous phase transitions. (shrink)

In this paper, I compare the use of the thermodynamic limit in the theory of phase transitions with the infinite-time limit in the explanation of equilibrium statistical mechanics. In the case of phase transitions, I will argue that the thermodynamic limit can be justified pragmatically since the limit behavior also arises before we get to the limit and for values of N that are physically significant. However, I will contend that the justification of the infinite-time limit is less straightforward. In (...) fact, I will point out that even in cases where one can recover the limit behavior for finite t, i.e. before we get to the limit, one cannot recover this behavior for realistic time scales. I will claim that this leads us to reconsider the role that the rate of convergence plays in the justification of infinite limits and calls for a revision of the so-called Butterfield’s principle. (shrink)

It is proposed that we use the term “approximation” for inexact description of a target system and “idealization” for another system whose properties also provide an inexact description of the target system. Since systems generated by a limiting process can often have quite unexpected, even inconsistent properties, familiar limit systems used in statistical physics can fail to provide idealizations, but are merely approximations. A dominance argument suggests that the limiting idealizations of statistical physics should be demoted to approximations.

Abstract.I chart the considerable changes in the status and conception of the Lenz-Ising model from 1920 to 1950 in terms of three phases: In the early 1920s, Lenz and Ising introduced the model in the field of ferromagnetism. Based on an exact derivation, Ising concluded that it is incapable of displaying ferromagnetic behavior, a result he erroneously extended to three dimensions. In the next phase, Lenz and Ising’s contemporaries rejected the model as a representation of ferromagnetic materials because of its (...) conflict with the new quantum mechanics. In the third phase, from the early 1930s to the early 1940s, the model was revived as a model of cooperative phenomena. I provide more detail on this history than the earlier accounts of Brush (1967) and Hoddeson, Schubert, Heims, and Baym (1992) and question some of their conclusions. Moreover, my account differs from these in its focus on the development of the model in its capacity as a model. It examines three aspects of this development: (1) the attitudes on the degree of physical realism of the Lenz-Ising model in its representation of physical phenomena; (2) the various reasons for studying and using it; and (3) the effect of the change in its theoretical basis during the transition from the old to the new quantum mechanics. A major theme of my study is that even though the Lenz-Ising model is not fully realistic, it is more useful than more realistic models because of its mathematical tractability. I argue that this point of view, important for the modern conception of the model, is novel and that its emergence, while perhaps not a consequence of its study, is coincident with the third phase of its development. (shrink)

This article examines ontological/dynamical aspects of emergence, specifically the micro-macro relation in cases of universal behavior. I discuss superconductivity as an emergent phenomenon, showing why microphysical features such as Cooper pairing are not necessary for deriving characteristic properties such as infinite conductivity. I claim that the difficulties surrounding the thermodynamic limit in explaining phase transitions can be countered by showing how renormalization group techniques facilitate an understanding of the physics behind the mathematics, enabling us to clarify epistemic and ontological aspects (...) of emergence. I close with a discussion of the impact of these issues for questions concerning natural kinds. (shrink)

It is well-known that the invocation of `equilibrium processes' in thermodynamics is oxymoronic. However, their prevalence and utility, particularly in elementary accounts, presents a problem. We consider a way in which their role can be played by sets of sequences of processes demarcated by curves carrying the property of accessibility. We also examine the vexed question of whether equilibrium processes are necessarily reversible and the revision of this property in relation to sets of sequences of such processes.

We show that both positive and negative absolute temperatures and monotonically increasing and decreasing entropy in adiabatic processes are consistent with Carathéodory's version of the second law and we explore the modifications of the Kelvin–Planck and Clausius versions which are needed to accommodate these possibilities. We show, in part by using the equivalence of distributions and the canonical distribution, that the correct microcanonical entropy, is the surface (Boltzmann) form rather than the bulk (Gibbs) form thereby providing for the possibility of (...) negative temperatures and we counter the contention on the part of a number of authors that the surface entropy fails to satisfy fundamental thermodynamic relationships. (shrink)

The renormalization method is specifically aimed at connecting theories describing physical processes at different length scales and thereby connecting different theories in the physical sciences.The renormalization method used today is the outgrowth of 150 years of scientific study of thermal physics and phase transitions. Different phases of matter show qualitatively different behaviors separated by abrupt phase transitions. These qualitative differences seem to be present in experimentally observed condensed-matter systems. However, the “extended singularity theorem” in statistical mechanics shows that sharp changes (...) can only occur in infinitely large systems. Abrupt changes from one phase to another are signaled by fluctuations that show correlation over infinitely long distances, and are measured by correlation functions that show algebraic decay as well as various kinds of singularities and infinities in thermodynamic derivatives and in measured system parameters.Renormalization methods were first developed in field theory to get around difficulties caused by apparent divergences at both small and large scales. However, no renormalization gives a fully satisfactory formulation of field theory.The renormalization group theory of phase transitions was put together by Kenneth G. Wilson in 1971 based upon ideas of scaling and universality developed earlier in the context of phase transitions and of couplings dependent upon spatial scale coming from field theory. Correlations among regions with fluctuations in their order underlie renormalization ideas. Wilson's theory is the first approach to phase transitions to agree with the extended singularity theorem.Some of the history of the study of these correlations and singularities is recounted, along with the history of renormalization and related concepts of scaling and universality. Applications, particularly to condensed-matter physics and particle physics, are summarized.This note is partially a summary of a talk given at the workshop “Part and Whole” in Leiden during the period March 22–26, 2010. (shrink)

There are two theoretical approaches in statistical mechanics, one associated with Boltzmann and the other with Gibbs. The theoretical apparatus of the two approaches offer distinct descriptions of the same physical system with no obvious way to translate the concepts of one formalism into those of the other. This raises the question of the status of one approach vis-à-vis the other. We answer this question by arguing that the Boltzmannian approach is a fundamental theory while Gibbsian statistical mechanics is an (...) effective theory, and we describe circumstances under which Gibbsian calculations coincide with the Boltzmannian results. We then point out that regarding GSM as an effective theory has important repercussions for a number of projects, in particular attempts to turn GSM into a nonequilibrium theory. (shrink)

Phase transitions are an important instance of putatively emergent behavior. Unlike many things claimed emergent by philosophers, the alleged emergence of phase transitions stems from both philosophical and scientific arguments. Here we focus on the case for emergence built from physics, in particular, arguments based upon the infinite idealization invoked in the statistical mechanical treatment of phase transitions. After teasing apart several challenges, we defend the idea that phase transitions are best thought of as conceptually novel, but not ontologically or (...) explanatorily irreducible to finite physics; indeed, by looking at ongoing work on “smooth phase transitions” we even suggest that they’re not even conceptually novel. In the case of renormalization group theory, consideration of infinite systems and their singular behavior provides a central theoretical tool, but this is compatible with an explanatory reduction. Phase transitions may be “emergent” in some sense of this protean term, but not in a sense that is incompatible with the reductionist project broadly construed. (shrink)