EMERGENT EVOLUTION- THE GIFFORD LECTURES DELIVERED IN THE UNIVERSITY OF ST.

Introduction: Science and Common Sense Long before the beginnings of modern civilization, men ac- quired vast funds of information about their environment. ...

Truth and Ontology is a lively book, brimming with arguments, and drawing the reader towards the radical conclusion that what is true does not depend on what there is. If there is a central line of argument, it is that the best account of truthmaking requires truths to be about their truthmakers, but negative existentials, modals, and claims about the past and future are not about what is, but rather about what is not, what might be, and what was and (...) will be. (shrink)

The eminent radiochemist Friedrich Paneth (1887–1958) tried to come to terms with the following epistemological problem: On the one hand chemical elements are characterized empirically as indestructible material species, on the other hand they are characterized theoretically as having the same number of protons in the nuclei of their atoms. Paneth used the dualistic Kantian epistemology (using Eduard von Hartmann's interpretation) in order to describe the combination of these two aspects, applying the terms “Grundstoff”, fundamental matter, to the latter and (...) “einfacher Stoff”, simple matter, to the former. The present paper discusses the applicability of Kant's philosophy – in the interpretation of Paneth – to the (modern) philosophy of chemistry. (shrink)

Immanuel Kant has built up a dualistic epistemology that seems to fit to the peculiarities of chemistry quite well. Friedrich Paneth used Kant’s concept and characterised simple and basic substances which refer to the empirical and to the transcendental world, respectively. This paper takes account of the Kantian influences in Paneth’s philosophy of chemistry, and discusses pertinent topics, like observables, atomism and realism.

The eminent radiochemist Friedrich Paneth (1887–1958) tried to come to terms with the following epistemological problem: On the one hand chemical elements are characterized empirically as indestructible material species, on the other hand they are characterized theoretically as having the same number of protons in the nuclei of their atoms. Paneth used the dualistic Kantian epistemology (using Eduard von Hartmann's interpretation) in order to describe the combination of these two aspects, applying the terms “Grundstoff”, fundamental matter, to the latter and (...) “einfacher Stoff”, simple matter, to the former. The present paper discusses the applicability of Kant's philosophy – in the interpretation of Paneth – to the (modern) philosophy of chemistry. (shrink)

In a recent article in this journal (Foundations of Chemistry, 7 (2005), 125–148) Lombardi and Labarca call into question a thesis of ontological reduction to which several writers on reduction subscribe despite rejecting a thesis of epistemological reduction. Lombardi and Labarca advocate instead a pluralistic ontology inspired by Putnam’s internal realism. I suggest that it is not necessary to go so far, and that a more critical view of the ontological reduction espoused by the authors they criticise circumvents the need (...) to resort to their radical alternative. (shrink)

Despite all the criticism showered on Nagel’s classic account of reduction, it meets a fundamental desideratum in an analysis of reduction that is difficult to question, namely of providing for a proper identification of the reducing theory. This is not clearly accommodated in radically different accounts. However, the same feature leads me to question Nagel’s claim that the reducing theory can be separated from the putative bridge laws, and thus to question his notion of heterogeneous reduction. A further corollary to (...) the requirement that all the necessary conditions be incorporated in an adequate formulation of the putative reducing theory is that the standard example of gas temperature is not reducible to average molecular kinetic energy. As originally conceived, Nagel’s conception of reduction takes no account of approximate reasoning and this failure has certainly restricted its applicability, perhaps to the point of making it unrealistic as a model of reduction in science. I suggest approximation can be accommodated by weakening the original requirement of deduction without jeopardizing the fundamental desideratum. Finally, I turn to briefly consider the idea sometimes raised of the ontological reducibility of chemistry. (shrink)

In the problem of the relationship between chemistry and physics, many authors take for granted the ontological reduction of the chemical world to the world of physics. The autonomy of chemistry is usually defended on the basis of the failure of epistemological reduction: not all chemical concepts and laws can be derived from the theoretical framework of physics. The main aim of this paper is to argue that this line of argumentation is not strong enough for eliminate the idea of (...) a hierarchical dependence of chemistry with respect to physics. The rejection of the secondary position of chemistry and the defense of the legitimacy of the philosophy of chemistry require a radically different philosophical perspective that denies not only epistemological reduction but also ontological reduction. Only on the basis of a philosophically grounded ontological pluralism it is possible to accept the ontological autonomy of the chemical world and, with this, to reverse the traditional idea of the ‘superiority’ of physics in the context of natural sciences. (shrink)

The aim of this paper is to introduce a new member of the family of the modal interpretations of quantum mechanics. In this modal-Hamiltonian interpretation, the Hamiltonian of the quantum system plays a decisive role in the property-ascription rule that selects the definite-valued observables whose possible values become actual. We show that this interpretation is effective for solving the measurement problem, both in its ideal and its non-ideal versions, and we argue for the physical relevance of the property-ascription rule by (...) applying it to well-known physical situations. Moreover, we explain how this interpretation supplies a description of the elemental categories of the ontology referred to by the theory, where quantum systems turn out to be bundles of possible properties. (shrink)

The aim of this paper is to introduce a new member of the family of the modal interpretations of quantum mechanics. In this modal-Hamiltonian interpretation, the Hamiltonian of the quantum system plays a decisive role in the property-ascription rule that selects the definite-valued observables whose possible values become actual. We show that this interpretation is effective for solving the measurement problem, both in its ideal and its non-ideal versions, and we argue for the physical relevance of the property-ascription rule by (...) applying it to well-known physical situations. Moreover, we explain how this interpretation supplies a description of the elemental categories of the ontology referred to by the theory, where quantum systems turn out to be bundles of possible properties. (shrink)

Does chemistry reduce to physics? If this means ‘Can we derive the laws of chemistry from the laws of physics?’, recent discussions suggest that the answer is ‘no’. But sup posing that kind of reduction—‘epistemological reduction’—to be impossible, the thesis of ontological reduction may still be true: that chemical properties are determined by more fundamental properties. However, even this thesis is threatened by some objections to the physicalist programme in the philosophy of mind, objections that generalize to the chemical case. (...) Two objections are discussed: that physicalism is vacuous, and that nothing grounds the asymmetry of dependence which reductionism requires. Although it might seem rather surprising that the philosophy of chemistry is affected by shock waves from debates in the philosophy of mind, these objections show that there is an argumentative gap between, on the one hand, the theoretical connection linking chemical properties with properties at the sub-atomic level, and, on the other, the philosophical thesis of ontological reduction. The aim of this paper is to identify the missing premises (among them a theory of physical possibility) that would bridge this gap. Introduction: missing elements and the mystery of discreteness The refutation of physicalism A combinatorial theory of physical possibilia Combinatorialism and the Bohr model Objections The missing premises and a disanalogy with mind. (shrink)

Este trabajo presenta algunas discusiones preliminares a una reconstrucción de la mecánicacuántica desde una perspectiva estructuralista. Intento responder a la pregunta por lostérminos MQ- no teóricos, es decir, qué magnitudes pueden ser medidas con independenciade la ecuación de Schrödinger y de la regla de Born. Uno de los aspectos relevantes que puedeser analizado una vez que se ha respondido a esta pregunta es el problema de la medición.Dado que el problema de la medición está directamente relacionado con el carácter linealde (...) la evolución temporal del estado dada por la ecuación de Schrödinger, la medición delos valores de aquellos conceptos que no presupongan esta ley no se verá afectada por esteproblema. Si bien esto no responde a todas las preguntas sobre la medición cuántica, indicaun primer paso a dar en la dirección hacia una comprensión más acabada de este problema. (shrink)

Rae Langton offers a new interpretation and defense of Kant's doctrine of things in themselves. Kant distinguishes things in themselves from phenomena, and in so doing he makes a metaphysical distinction between intrinsic and relational properties of substances. Langton argues that his claim that we have no knowledge of things in themselves is not idealism, but epistemic humility: we have no knowledge of the intrinsic properties of substances. This interpretation vindicates Kant's scientific realism, and shows his primary/secondary quality distinction to (...) be superior even to modern-day competitors. And it answers the famous charge that Kant's tale of things in themselves is one that makes itself untellable. (shrink)

Two books have been particularly influential in contemporary philosophy of science: Karl R. Popper's Logic of Scientific Discovery, and Thomas S. Kuhn's Structure of Scientific Revolutions. Both agree upon the importance of revolutions in science, but differ about the role of criticism in science's revolutionary growth. This volume arose out of a symposium on Kuhn's work, with Popper in the chair, at an international colloquium held in London in 1965. The book begins with Kuhn's statement of his position followed by (...) seven essays offering criticism and analysis, and finally by Kuhn's reply. The book will interest senior undergraduates and graduate students of the philosophy and history of science, as well as professional philosophers, philosophically inclined scientists, and some psychologists and sociologists. (shrink)

In this paper we will address the problem of the existence of orbitals by analyzing the relationship between molecular chemistry and quantum mechanics. In particular, we will consider the concept of orbital in the light of the arguments that deny its referring character. On this basis, we will conclude that the claim that orbitals do not exist relies on a metaphysical reductionism which, if consistently sustained, would lead to consequences clashing with the effective practice of science in its different branches.

R.I.G Hughes offers the first detailed and accessible analysis of the Hilbert-space models used in quantum theory and explains why they are so successful.

In this paper I investigate two views of theoretical explanation in quantum chemistry, advocated by John Clarke Slater and Charles Coulson. Slater argued for quantum‐mechanical rigor, and the primacy of fundamental principles in models of chemical bonding. Coulson emphasized systematic explanatory power within chemistry, and continuity with existing chemical explanations. I relate these views to the epistemic contexts of their disciplines.

In this article I sketch G. N. Lewis’s views on chemical bonding and Linus Pauling’s attempt to preserve Lewis’s insights within a quantum‐mechanical theory of the bond. I then set out two broad conceptions of the chemical bond, the structural and the energetic views, which differ on the extent in which they preserve anything like the classical chemical bond in the modern quantum‐mechanical understanding of molecular structure. †To contact the author, please write to: Department of Philosophy, Durham University, 50 Old (...) Elvet, Durham DH1 3HN, UK; e‐mail: [email protected]. (shrink)

The focus of this volume, which collects both recent and now-classic essays, is the historical emergence of concepts and objects, through new uses of words and ...

This paper analyzes the generation and function of hitherto ignored or misrepresented interfield theories , theories which bridge two fields of science. Interfield theories are likely to be generated when two fields share an interest in explaining different aspects of the same phenomenon and when background knowledge already exists relating the two fields. The interfield theory functions to provide a solution to a characteristic type of theoretical problem: how are the relations between fields to be explained? In solving this problem (...) the interfield theory may provide answers to questions which arise in one field but cannot be answered within it alone, may focus attention on domain items not previously considered important, and may predict new domain items for one or both fields. Implications of this analysis for the problems of reduction and the unity and progress of science are mentioned. (shrink)

A variety of recent philosophical discussions, particularly on topics relating to complexity, have begun to reemploy the concept of 'emergence'. Although multiple concepts of 'emergence' are available, little effort has been made to systematically distinguish them. In this paper, I provide a taxonomy of higher-order properties that (inter alia) distinguishes three classes of emergent properties: (1) ontologically basic properties of complex entities, such as the mythical vital properties, (2) fully configurational properties, such as mental properties as they are conceived of (...) by functionalists and computationalists, and (3) highly configurational/holistic properties, such as the higher-level patterns characteristic of complex dynamical systems. Or more simply: emergence as ontological liberality, emergence as multiple realizability, and emergence as interactive complexity. (shrink)

A variety of recent philosophical discussions, particularly on topics relating to complexity, have begun to reemploy the concept of 'emergence'. Although multiple concepts of 'emergence' are available, little effort has been made to systematically distinguish them. In this paper, I provide a taxonomy of higher-order properties that distinguishes three classes of emergent properties: ontologically basic properties of complex entities, such as the mythical vital properties, fully configurational properties, such as mental properties as they are conceived of by functionalists and computationalists, (...) and highly configurational/holistic properties, such as the higher-level patterns characteristic of complex dynamical systems. Or more simply: emergence as ontological liberality, emergence as multiple realizability, and emergence as interactive complexity. (shrink)

According to ontological reductionism, molecular chemistry refers, at last, to the quantum ontology; therefore, the ontological commitments of chemistry turn out to be finally grounded on quantum mechanics. The main problem of this position is that nobody really knows what quantum ontology is. The purpose of this work is to argue that the confidence in the existence of the physical entities described by quantum mechanics does not take into account the interpretative problems of the theory: in the discussions about the (...) relationship between chemistry and physics, difficulties are seen only on the side of chemistry, whereas matters highly controversial on the side of physics are taken for granted. For instance, it is usually supposed that the infinite mass limit in the Born-Oppenheimer approximation leads by itself to the concept of molecular framework used in molecular chemistry. We will argue that this assumption is implicitly based on an interpretative postulate for quantum mechanics, which, in turn, runs into difficulties when applied to the explanation of the simplest model of the hydrogen atom. (shrink)

Every Thing Must Go aruges that the only kind of metaphysics that can contribute to objective knowledge is one based specifically on contemporary science as it ...

This book has grown out of eight years of close collaboration among its authors. From the very beginning we decided that its content should come out as the result of a truly common effort. That is, we did not "distribute" parts of the text planned to each one of us. On the contrary, we made a point that each single paragraph be the product of a common reflection. Genuine team-work is not as usual in philosophy as it is in other (...) academic disciplines. We think, however, that this is more due to the idiosyncrasy of philosophers than to the nature of their subject. Close collaboration with positive results is as rewarding as anything can be, but it may also prove to be quite difficult to implement. In our case, part of the difficulties came from purely geographic separation. This caused unsuspected delays in coordinating the work. But more than this, as time passed, the accumulation of particular results and ideas outran our ability to fit them into an organic unity. Different styles of exposition, different ways of formalization, different levels of complexity were simultaneously present in a voluminous manuscript that had become completely unmanageable. In particular, a portion of the text had been conceived in the language of category theory and employed ideas of a rather abstract nature, while another part was expounded in the more conventional set-theoretic style, stressing intui tivity and concreteness. (shrink)

Chemistry and physics are two sciences that are hard to connect. Yet there is significant overlap in their aims, methods, and theoretical approaches. In this book, the reduction of chemistry to physics is defended from the viewpoint of a naturalised Nagelian reduction, which is based on a close reading of Nagel's original text. This naturalised notion of reduction is capable of characterising the inter-theory relationships between theories of chemistry and theories of physics. The reconsideration of reduction also leads to a (...) new characterisation of chemical theories. This book is primarily aimed at philosophers of chemistry and chemists with an interest in philosophy, but is also of interest to the general philosopher of science. (shrink)

This book offers a philosophy for error-prone humans trying to understand messy systems in the real world.

Approaches to explanation -- Causal and explanatory relevance -- The kairetic account of /D making -- The kairetic account of explanation -- Extending the kairetic account -- Event explanation and causal claims -- Regularity explanation -- Abstraction in regularity explanation -- Approaches to probabilistic explanation -- Kairetic explanation of frequencies -- Kairetic explanation of single outcomes -- Looking outward -- Looking inward.

It is often supposed that the spectacular successes of our modern mathematical sciences support a lofty vision of a world completely ordered by one single elegant theory. In this book Nancy Cartwright argues to the contrary. When we draw our image of the world from the way modern science works - as empiricism teaches us we should - we end up with a world where some features are precisely ordered, others are given to rough regularity and still others behave in (...) their own diverse ways. This patchwork makes sense when we realise that laws are very special productions of nature, requiring very special arrangements for their generation. Combining classic and newly written essays on physics and economics, The Dappled World carries important philosophical consequences and offers serious lessons for both the natural and the social sciences. (shrink)

The controversy over the notion of emergence has recently re-emerged But a rigorous debate concerning how it might be explained or defined is often lacking Emergence is discussed here under two strict conditions (l) emergents can be predictable from the knowledge about a system's parts, (ll) emergents can be regarded as dependent on, and deternuned by, the system's micro-structure O'Connor's definmon of an emergent property is taken as a starting-point for a new definmon, incorporating Emmeche and colleagues' analysis of dounward (...) causation and Baas' treatment of emergence It is not necessary to assume that this defintaon might provide the solution to the problem of emergence Rather, theoretical pluralism regarding different pragmatically-workable notions of emergence is welcome The reality of emergents is discussed here from the standpoint of Dennet's mild realism. (shrink)