While symbolic colour use has always played a conspicuous role in science research and education, the use of colour in historic diagrams remains a lacuna in the history of science. Investigating the colour use in diagrams often means uncovering a whole cosmology that is not otherwise explicit in the diagram itself. The periodic table is a salient and iconic example of non-mimetic colour use in science. Andreas von Antropoff's (1924) rectangular table of recurrent rainbow colours is famous, as are Alcindo (...) Flores Cabral's (1949) application of colour in his round snail form, using the RGB scheme, and Mazurs's (1967) pine tree system, consisting of warm and cold colours that he attributed to specific groups of elements—an attribution that we can relate back to humoralism and alchemy. From the first periodic tables in the 19th century, individual researchers have used different colour regimes. While standardization may play an obvious role in chemistry and its diagrams, all the more impressive is the anarchistic use of colour in the various diagrams which continue to be created. This article focuses on periodic tables in chemical journals and text books, and explores and compares the development of colour codes found in the few existing polychrome diagrams from the 1920s to the 1970s. (shrink)

Between 1869 and 1871, D. I. Mendeleev, a teacher at the University at St Petersburg published a textbook of general chemistry intended for his students. The title, Principles of Chemistry was typical for the time: it meant that chemistry was no longer an inquiry on the ultimate principles of matter but had become a science firmly established on a few principles derived from experiment.

Many standard philosophical accounts of scientific practice fail to distinguish between modeling and other types of theory construction. This failure is unfortunate because there are important contrasts among the goals, procedures, and representations employed by modelers and other kinds of theorists. We can see some of these differences intuitively when we reflect on the methods of theorists such as Vito Volterra and Linus Pauling on the one hand, and Charles Darwin and Dimitri Mendeleev on the other. Much of Volterra's and (...) Pauling's work involved modeling; much of Darwin's and Mendeleev's did not. In order to capture this distinction, I consider two examples of theory construction in detail: Volterra's treatment of post-WWI fishery dynamics and Mendeleev's construction of the periodic system. I argue that modeling can be distinguished from other forms of theorizing by the procedures modelers use to represent and to study real-world phenomena: indirect representation and analysis. This differentiation between modelers and non-modelers is one component of the larger project of understanding the practice of modeling, its distinctive features, and the strategies of abstraction and idealization it employs. (shrink)

After 150 years of scientific developments, the periodic system of chemical elements is still an icon of modern science. Its resilience is striking. The icon used today by scientists and teachers is in fact the outcome of many rearrangements and reinterpretations by the scientific community during that period. This success is often explained as a result of the underlying atomic structure, discovered in the first decades of the 20th century, an explanation that completely neglects the fine structure of the process (...) of ongoing renegotiation and successive stabilizations. How did indeed contemporary scientists navigate in times of reinterpretation? The physicist Lise Meitner and the chemist Ida Noddack were, in different ways, involved in discoveries and interpretations of the periodic system. In 1934, as part of the celebration of the centenary of Dmitri Mendeleev's birth, they each published an article on the system: Meitner in Die Naturwissenschaften, and Noddack in Angewandte Chemie. These two articles, written from the perspectives of a nuclear physicist and a chemist experienced in searching for undiscovered elements, respectively, constitute excellent sources for understanding what new discoveries and insights meant for the meaning and value of the periodic system at the very beginning of the nuclear age in science. Through an analysis of the two contributions, we will argue that resilience is the foremost value of the periodic system. We will also discuss what this value means for the future of the periodic system and its representations. (shrink)

This article focuses on the Russian chemist Dmitri Ivanovich Mendeleev's assessment of certain representations of various aspects of the periodic system that employed more mathematical methodology. The equations of interest were created by E. J. Mills, B. N. Chicherin, and J. H. Vincent. The English chemist Mills tried to find a firmer numerical basis for the periodicity of the elements. The Russian lawyer and political philosopher Chicherin was convinced of the existence of a mathematical law underlying the periodic system. The (...) English physicist Vincent explored the connection between atomic weights and the elements' order in listings based on atomic weights—a project which he associated with the periodic system of elements. Although, for Mendeleev, the equations of Mills, Chicherin, and Vincent promised a more precise expression of the law of periodicity, he continued to invoke his earlier standards. In particular, Mendeleev wanted the equations to respect the individuality of the elements, and called for completeness in conveying the complexities of chemical phenomena. Thus, the very qualities that he had valued while developing his periodic system in 1869–1871 also characterised his evaluation of the new means of representing aspects of that system. (shrink)

Book reviewed in this article: Between Science and Values. By Loren R. Graham.

Cognitive values like simplicity, broad scope, and easy handling are properties of a scientific representation that result from the idealization which is involved in the construction of a representation. These properties may facilitate the application of epistemic values to credibility assessments, which provides a rationale for assigning an auxiliary function to cognitive values. In this paper, I defend a further rationale for cognitive values which consists in the assessment of the usefulness of a representation. Usefulness includes the relevance of a (...) representation regarding the investigation of a given problem and its practicability for the users. This rationale builds on the claim that any evaluation of scientific representations should pursue two aims: providing information about their credibility and providing information about their usefulness. Cognitive values relating to the usefulness of a representation and epistemic values relating to its credibility both perform a first-order function. Cognitive values are abstract, and several values with first-order functions may conflict in their application. Thus, in order for cognitive values to account for the sort of problem that is to be investigated by means of a representation, they need to be appropriately specified and weighed. Comprehensiveness, complexity, high resolution, and easy handling, for instance, may be required in a first-order function for model-based prediction of regional climate impacts but not for explaining how the global climate system works. Specifying and weighing cognitive and epistemic values relative to a given problem is a legitimate second-order function of social values. (shrink)

The discovery of the noble gases and their incorporation into the periodic system are examined in this paper. A chronology of experimental reports on argon and helium and the properties relevant to their nature and position in the periodic system is presented. Proposals on the nature of argon and helium that appeared in the aftermath of their discovery are examined in light of the various empirical and theoretical considerations that supported and contradicted them. ``The piece that would not fit'' refers (...) not only to argon, the element that at first seemed not to fit into the periodic system, but also to the piece or pieces of evidence that various researchers and observers were prepared to discard or discount in coming to terms with the newly discovered gases. (shrink)

Traditionally, cognitive values have been thought of as a collective pool of considerations in science that frequently trade against each other. I argue here that a finer-grained account of the value of cognitive values can help reduce such tensions. I separate the values into groups, minimal epistemic criteria, pragmatic considerations, and genuine epistemic assurance, based in part on the distinction between values that describe theories per se and values that describe theory-evidence relationships. This allows us to clarify why these values (...) are central to science and what role they should play, while reducing the tensions among them. (shrink)

This article summarizes recent work by epistemologists on four related problems. (1) The value of knowledge. Briefly, the problem is to explain why knowledge is, or at least appears to be, more valuable than any proper subset of its parts, such as true belief. (2) The value of understanding. The task here is to explain why understanding appears to be more valuable than any epistemic status that falls short of understanding, such as having knowledge without understanding. (3) Truth and epistemic (...) value. The arguments considered in this section have to do with whether truth is epistemically valuable at all, and whether it is the fundamental epistemic value. (4) Intrumentalism and the epistemic goal. This final section considers the instrumentalist view of epistemic reasons and rationality, and explains why instrumentalists formulate the epistemic goal in the ways they do. (shrink)

Since its inception in 1869, the periodic system — icon of modern chemistry — has suffered from the problematic accommodation of the rare-earth elements. The substance of this paper intends to retrace Mendeleev’s shifting attitudes with regard to the rare-earth crisis during the period 1869–1871. Based on a detailed examination of Mendeleev's research papers from that period, it will be argued that the rare-earth crisis played a key role in inducing a number of important changes in Mendeleev’s philosophical viewpoints with (...) regard to the epistemological concept of a chemical element and the nature of elementary groups. Many of Mendeleev's most cherished beliefs got endangered by the nature of these elements. Their mystifying properties forced him to revise his ideas about primary and secondary groups, the elements as basic and simple substances, and the use of short and long form tables. They made him question the validity and universality of the periodic law, and led him into hypothesizing about the internal structure of matter and constitution of atoms. (shrink)

To this day, a hundred and fifty years after Mendeleev's discovery, the overal structure of the periodic system remains unaccounted for in quantum-mechanical terms. Given this dire situation, a handful of scientists in the 1970s embarked on a quest for the symmetries that lie hidden in the periodic table. Their goal was to explain the table's structure in group-theoretical terms. We argue that this symmetry program required an important paradigm shift in the understanding of the nature of chemical elements. The (...) idea, in essence, consisted of treating the chemical elements, not as particles, but as states of a superparticle. We show that the inspiration for this came from elementary particle physics, and in particular from Heisenberg's suggestion to treat the proton and neutron as different states of the nucleon. We provide a careful study of Heisenberg's last paper on the nature of elementary particles, and explain why the Democritean picture of matter no longer applied in modern physics and a Platonic symmetry-based picture was called for instead. We show how Heisenberg's Platonic philosophy came to dominate the field of elementary particle physics, and how it found its culmination point in Gell-Mann's classification of the hadrons in the eightfold way. We argue that it was the success of Heisenberg's approach in elementary particle physics that sparked the group-theoretical approach to the periodic table. We explain how it was applied to the set of chemical elements via a critical examination of the work of the Russian mathematician Abram Ilyich Fet the Turkish-American physicist Asim Orhan Barut, before giving some final reflections. (shrink)