Historians and philosophers of science generally conceptualize scientific progress to be dichotomous, viz., experimental observations lead to scientific laws, which later facilitate the elaboration of explanatory theories. There is considerable controversy in the literature with respect to Mendeleev’s contribution to the origin, nature, and development of the periodic table. The objectives of this study are to explore and reconstruct: a) periodicity in the periodic table as a function of atomic theory; b) role of predictions in scientific theories and its implications (...) for the periodic table; and c) Mendeleev’s contribution: theory or an empirical law? The reconstruction shows that despite Mendeleev’s own ambivalence, periodicity of properties of chemical elements in the periodic table can be attributed to the atomic theory. It is argued that based on the Lakatosian framework, predictions play an important role in the development of scientific theories. In this context, Mendeleev’s predictions played a crucial role in the development of the periodic table. Finally, it is concluded that Mendeleev’s contribution can be considered as an “interpretative” theory which became “explanatory” after the periodic table was based on atomic numbers.Author Keywords: Periodic table; Mendeleev’s contribution; Theory; Empirical law; Interpretative theory. (shrink)

This paper addresses the conceptual as well as social origins of Mendeleev’s discovery of the periodic law and its reception by the chemical community by taking account of three factors: Mendeleev’s early research and its relevance to the discovery; his concepts of chemistry, especially that of the chemical elements; and the social context of the discovery and the reception in the chemical community. Mendeleev's clear distinction between abstract elements and simple bodies was a departure from Lavoisier’s famous definition of elements (...) as an endpoint of analysis and originated from his research in indefinite compounds. As a comparison, the paper also analyzes Lothar Meyer’s approach to the classification of the elements. Mendeleev’s new concept of chemical elements and the existence of an audience in the form of the newly established Russian Chemical Society, and his ``German connection'', helped Mendeleev in his discovery and its reception. (shrink)

Robin Hendry has recently argued that although the term ‘element’ has traditionally been used in two different senses, there has nonetheless been a continuity of reference. The present article examines this author’s historical and philosophical claims and suggests that he has misdiagnosed the situation in several respects. In particular it is claimed that Hendry’s arguments for the nature of one particular element, oxygen, do not generalize to all elements as he implies. The second main objection is to Hendry’s view that (...) the qua problem can be illuminated by appeal to the intention of scientists.Keywords: Element; Simple substance; Basic substance; Antoine Lavoisier; Dmitri Mendeleev; Reference; Qua problem. (shrink)

One of the consequences of the renewed interest in philosophical aspects of chemistry has been the corresponding renewed interest in the periodic system of the elements which embodies so much chemical knowledge in an implicit form.We have therefore decided to further promote scholarship on the periodic system by compiling a bibliography of previously published material. As the title of this article implies, we restrict ourselves to secondary sources. Readers interested in primary material can consult a number of useful references for (...) this purpose. These include the classical treatment on the History of the periodic system by van Spronsen as well as Mazurs’s compilation of over 700 forms of the periodic system. Mazurs also includes a detailed bibliography of articles and books in several different languages. Additional sources of primary articles which come to mind include David Knight’s Classics in the History of Chemistry, Carmen Giunta’s web pages for the history of chemistry and entries under individual scientists in the Dictionary of Scientific Biography. Turning to the present compilation we do not claim this to be a comprehensive list, since it partly reflects the interests of the senior author (E.R.S.), namely the relationship between the periodic system and quantum mechanics. For example, in addition to articles specifically on the periodic system we include a number of articles which deal with the related themes of electronic configurations of the elements. This bias also explains the disproportionate number of references to the work of the senior author.We have tried to include as many as possible of the articles on the periodic system which have appeared in the philosophy of science literature. These include Bensaude, Christie, Hettema and Kuipers, Kultgen, Lipton, Maher, Scerri, Shapere and Sundaram, among others. (shrink)

Some recent work in mathematical chemistry is discussed. It is claimed that quantum mechanics does not provide a conclusive means of classifying certain elements like hydrogen and helium into their appropriate groups. An alternative approach using atomic number triads is proposed and the validity of this approach is defended in the light of some predictions made via an information theoretic approach that suggests a connection between nuclear structure and electronic structure of atoms.

Dmitrii Mendeleev’s periodic system is known for its predictive accuracy, but talk of its completeness is rarer. This is surprising because completeness was a quality that Mendeleev saw as important for a systematization of the chemical elements. Here, I explain how Mendeleev’s valuing of completeness influenced the development of his periodic system. After introducing five indicators of its completeness, I zoom into one in particular: Mendeleev’s inclusion of a schematic row of oxides. I then show how it guided Mendeleev’s predictions (...) of indium and ekaboron, which suggests that the valuing of completeness was instrumental for making predictions. (shrink)

This article focuses on the Russian chemist Dmitri Ivanovich Mendeleev's assessment of certain representations of various aspects of the periodic system that employed more mathematical methodology. The equations of interest were created by E. J. Mills, B. N. Chicherin, and J. H. Vincent. The English chemist Mills tried to find a firmer numerical basis for the periodicity of the elements. The Russian lawyer and political philosopher Chicherin was convinced of the existence of a mathematical law underlying the periodic system. The (...) English physicist Vincent explored the connection between atomic weights and the elements' order in listings based on atomic weights—a project which he associated with the periodic system of elements. Although, for Mendeleev, the equations of Mills, Chicherin, and Vincent promised a more precise expression of the law of periodicity, he continued to invoke his earlier standards. In particular, Mendeleev wanted the equations to respect the individuality of the elements, and called for completeness in conveying the complexities of chemical phenomena. Thus, the very qualities that he had valued while developing his periodic system in 1869–1871 also characterised his evaluation of the new means of representing aspects of that system. (shrink)

The theme surrounding scientific discoveries is quite neglected in and about the sciences, especially in terms of historical and epistemological understanding. Discoveries are often treated as simple information about dates, places, and people. This work presents discussions centered on historical episodes related to chemical elements and the Periodic Law, based on reflections by Thomas Kuhn and Norwood Hanson, aiming to highlight and contextualize specific scientific discoveries' conceptual and epistemological structure. With that in mind, issues related to the inseparability of the (...) contexts of discovery and justification are recovered, along with the complex intrinsic structures of the genesis of scientific knowledge and distinct types and categories of scientific discoveries. (shrink)

The history of the diffusion and confirmation of Mendeleev’s periodic table of elements has proven to be a challenging testbed for contemporary philosophical debates on the role of predictions in science. More than ten years of fruitful literature came after Scerri and Worrall :407–452, 2001) versus Maher and Lipton ; nevertheless, such a long-lasting debate left quite a few open questions. The aim of this contribution is to go through the various cases that emerged during the debate, in an effort (...) to explain them coherently in a weak predictivist perspective. Maher’s early account—according to which the astounding success of the major predictions alone was enough to explain the confirmation of the periodic table—can now be replaced by a more balanced and thorough picture, where both predictions and accommodations do weight. (shrink)

Measurement theory in (Hand in The world through quantification. Oxford University Press, 2004; Suppes and Zinnes in Basic measurement theory. Psychology Series, 1962) is concerned with the assignment of number to objects of phenomena. Representational aspect of measurement is the extent to which the assigned numbers and arithmetics truthfully represent the underlying objects and their relations, and is characteristic to natural sciences; pragmatic aspect is the extent to which the assigned numbers serve purposes other than representing the underlying phenomena, and (...) is characteristic to social sciences (Hand in The world through quantification. Oxford University Press, 2004). Here I criticise this distinction of representational and pragmatic measurements on the basis of the earlier history of the periodic system of chemical elements, viewed in terms of a practice based philosophy of science by Rein Vihalemm. I argue that the periodic system, although a natural scientific system interpretable as a measurement system, has considerable, in Hand’s terms pragmatic, aspects in it. Those aspects include: tampering with the material measurement results for the theoretical ideal of systematicity; adopting metaphysical assumptions that cannot be experimentally proven, like individuality of elements and atomicity; theoretical construction of the abstract entity—element—as the reference of the measurement system amenable to mathematically elegant ordering. Contrary to Suppes and Zinnes (Basic measurement theory. Psychology Series, 1962) I also argue for the dependence of the assigned numerical system on the material-procedural base of the measurement. (shrink)