This chapter will review selected aspects of the terrain of discussions about probabilities in statistical mechanics (with no pretensions to exhaustiveness, though the major issues will be touched upon), and will argue for a number of claims. None of the claims to be defended is entirely original, but all deserve emphasis. The first, and least controversial, is that probabilistic notions are needed to make sense of statistical mechanics. The reason for this is the same reason that convinced Maxwell, Gibbs, and (...) Boltzmann that probabilities would be needed, namely, that the second law of thermodynamics, which in its original formulation says that certain processes are impossible, must, on the kinetic theory, be replaced by a weaker formulation according to which what the original version deems impossible is merely improbable. Second is that we ought not take the standard measures invoked in equilibrium statistical mechanics as giving, in any sense, the correct probabilities about microstates of the system. We can settle for a much weaker claim: that the probabilities for outcomes of experiments yielded by the standard distributions are effectively the same as those yielded by any distribution that we should take as a representing probabilities over microstates. Lastly, (and most controversially): in asking about the status of probabilities in statistical mechanics, the familiar dichotomy between epistemic probabilities (credences, or degrees of belief) and ontic (physical) probabilities is insufficient; the concept of probability that is best suited to the needs of statistical mechanics is one that combines epistemic and physical considerations. (shrink)

This book is an attempt to get to the bottom of an acute and perennial tension between our best scientific pictures of the fundamental physical structure of the world and our everyday empirical experience of it. The trouble is about the direction of time. The situation (very briefly) is that it is a consequence of almost every one of those fundamental scientific pictures--and that it is at the same time radically at odds with our common sense--that whatever can happen can (...) just as naturally happen backwards. Albert provides an unprecedentedly clear, lively, and systematic new account--in the context of a Newtonian-Mechanical picture of the world--of the ultimate origins of the statistical regularities we see around us, of the temporal irreversibility of the Second Law of Thermodynamics, of the asymmetries in our epistemic access to the past and the future, and of our conviction that by acting now we can affect the future but not the past. Then, in the final section of the book, he generalizes the Newtonian picture to the quantum-mechanical case and (most interestingly) suggests a very deep potential connection between the problem of the direction of time and the quantum-mechanical measurement problem. The book aims to be both an original contribution to the present scientific and philosophical understanding of these matters at the most advanced level, and something in the nature of an elementary textbook on the subject accessible to interested high-school students. Table of Contents: Preface 1. Time-Reversal Invariance 2. Thermodynamics 3. Statistical Mechanics 4. The Reversibility Objections and the Past-Hypothesis 5. The Scope of Thermodynamics 6. The Asymmetries of Knowledge and Intervention 7. Quantum Mechanics Appendix: Gedankenexperiments with Heat Engines Index Reviews of this book: The foundations of statistical mechanisms are often presented in physics textbooks in a rather obscure and confused way. By challenging common ways of thinking about this subject, Time and Chance can do quite a lot to improve this situation. --Jean Bricmont, Science Albert is perfecting a style of foundational analysis that is uniquely his own...It has a surgical precision...and it is ruthless with pretensions. The foundations of thermodynamics is a topic that has accumulated a good deal of dead wood; this is a fire that will burn and burn. --Simon W. Saunders, Oxford University As usual with Albert's work, the exposition is brisk and to the point, and exceptionally clear...The book will be an extremely valuable contribution to the literature on the subject of philosophical issues in thermodynamics and statistical mechanics, a literature which has been thin on the ground but is now growing as it deserves to. --Lawrence Sklar, University of Michigan. (shrink)

Statistical mechanics involves probabilities. At the same time, most approaches to the foundations of statistical mechanics--programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics--are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are deterministic. This raises some potential puzzles about the proper interpretation of these probabilities.

The traditional use of ergodic theory in the foundations of equilibrium statistical mechanics is that it provides a link between thermodynamic observables and microcanonical probabilities. First of all, the ergodic theorem demonstrates the equality of microcanonical phase averages and infinite time averages (albeit for a special class of systems, and up to a measure zero set of exceptions). Secondly, one argues that actual measurements of thermodynamic quantities yield time averaged quantities, since measurements take a long time. The combination of these (...) two points is held to be an explanation why calculating microcanonical phase averages is a successful algorithm for predicting the values of thermodynamic observables. It is also well-known that this account is problematic.

This survey intends to show that ergodic theory nevertheless may have important roles to play, and it explores three other uses of ergodic theory. Particular attention is paid, firstly, to the relevance of specific interpretations of probability, and secondly, to the way in which the concern with systems in thermal equilibrium is translated into probabilistic language. With respect to the latter point, it is argued that equilibrium should not be represented as a stationary probability distribution as is standardly done; instead, a weaker definition is presented. (shrink)

Can there be deterministic chance? That is, can there be objective chance values other than 0 or 1, in a deterministic world? I will argue that the answer is no. In a deterministic world, the only function that can play the role of chance is one that outputs just Os and 1s. The role of chance involves connections from chance to credence, possibility, time, intrinsicness, lawhood, and causation. These connections do not allow for deterministic chance.

We often use symmetries to infer outcomes’ probabilities, as when we infer that each side of a fair coin is equally likely to come up on a given toss. Why are these inferences successful? I argue against answering this with an a priori indifference principle. Reasons to reject that principle are familiar, yet instructive. They point to a new, empirical explanation for the success of our probabilistic predictions. This has implications for indifference reasoning in general. I argue that a priori (...) symmetries need never constrain our probability attributions, even when it comes to our initial credences. (shrink)

This pair of articles provides a critical commentary on contemporary approaches to statistical mechanical probabilities. These articles focus on the two ways of understanding these probabilities that have received the most attention in the recent literature: the epistemic indifference approach, and the Lewis-style regularity approach. These articles describe these approaches, highlight the main points of contention, and make some attempts to advance the discussion. The first of these articles provides a brief sketch of statistical mechanics, and discusses the indifference approach (...) to statistical mechanical probabilities. (shrink)

The conspicuous similarities between interpretive strategies in classical statistical mechanics and in quantum mechanics may be grounded on their employment of common implementations of probability. The objective probabilities which represent the underlying stochasticity of these theories can be naturally associated with three of their common formal features: initial conditions, dynamics, and observables. Various well-known interpretations of the two theories line up with particular choices among these three ways of implementing probability. This perspective has significant application to debates on primitive ontology (...) and to the quantum measurement problem. (shrink)

It is generally thought that objective chances for particular events different from 1 and 0 and determinism are incompatible. However, there are important scientific theories whose laws are deterministic but which also assign non-trivial probabilities to events. The most important of these is statistical mechanics whose probabilities are essential to the explanations of thermodynamic phenomena. These probabilities are often construed as 'ignorance' probabilities representing our lack of knowledge concerning the microstate. I argue that this construal is incompatible with the role (...) of probability in explanation and laws. This is the 'paradox of deterministic probabilities'. After surveying the usual list of accounts of objective chance and finding them inadequate I argue that an account of chance sketched by David Lewis can be modified to solve the paradox of deterministic probabilities and provide an adequate account of the probabilities in deterministic theories like statistical mechanics. (shrink)

The role of probability is one of the most contested issues in the interpretation of contemporary physics. In this paper, I’ll be reevaluating some widely held assumptions about where and how probabilities arise. Larry Sklar voices the conventional wisdom about probability in classical physics in a piece in the Stanford Online Encyclopedia of Philosophy, when he writes that “Statistical mechanics was the first foundational physical theory in which probabilistic concepts and probabilistic explanation played a fundamental role.” And the conventional wisdom (...) about quantum probabilities is that they are basic, not reducible to the types of probabilities we see in statistical mechanics. In the first section of this paper, I’ll argue that in fact classical physics was steeped in probability long before statistical mechanics came on the scene, specifically, that an objective measure over phase space is an indispensable component of any informative physical theory. In the next section, I’ll argue that this objective measure is the fundamental form of physical probability and that quantum probabilities can be defined in terms of it. In the last, I’ll raise some questions about the metaphysical status of the fundamental measure. (shrink)

First para: Before the 17th century, there was not much discussion, and little uniformity in conception, of natural laws. The rise of science in 17th century, Newton’s mathematization of physics, and the provision of strict, deterministic laws that applied equally to the heavens and to the terrestrial realm had a profound impact in transforming the philosophical imagination. A philosophical conception of physical law built on the example of Newtonian Mechanics became quickly entrenched. Between the 17th and 20th centuries, there was (...) a great deal of philosophical interest in probabilities, but probabilities were mostly regarded as having something to do with the management of opinion, not as having a fundamental role in science. Probabilities made their first appearance in an evidently ineliminable way in the laws of a fundamental theory with the advent of quantum mechanics. Quantum probabilities have come to be called ‘chances’ in the philosophical literature, and their interpretation has been one of the central problems in philosophy of science now for almost a century. There continue to be hold-outs that insist that there must be an underlying probability-free replacement for quantum mechanics and Bohmians have had some success in formulating a deterministic alternative to quantum mechanics, but most physicists accept that the probabilistic character of the quantum mechanical laws is likely to be retained in any successor theory. While physics has adjusted itself comfortably to the existence of ineliminably probabilistic laws, philosophy has not managed arrive at a stable interpretation of quantum probability. The difficulty is that there are a number of constraints that an interpretation of chance must satisfy, constraints that appear to be partially definitive of the concept and it proves to be extraordinarily difficult to meet them simultaneously. (shrink)

The goal of this paper is to sketch and defend a new interpretation or 'theory' of objective chance, one that lets us be sure such chances exist and shows how they can play the roles we traditionally grant them. The account is 'Humean' in claiming that objective chances supervene on the totality of actual events, but does not imply or presuppose a Humean approach to other metaphysical issues such as laws or causation. Like Lewis (1994) I take the Principal Principle (...) (PP) to be the key to understanding objective chance. After describing the main features of Humean objective chance (HOC), I deduce the validity of PP for Humean chances, and end by exploring the limitations of Humean chance. (shrink)

We outline Ladyman's 'metaphysical' or 'ontic' form of structuralrealism and defend it against various objections. Cao, in particular, has questioned theview of ontology presupposed by this approach and we argue that by reconceptualisingobjects in structural terms it offers the best hope for the realist in thecontext of modern physics.

An important obstacle to lawhood in the special sciences is the worry that such laws would require metaphysically extravagant conspiracies among fundamental particles. How, short of conspiracy, is this possible? In this paper we'll review a number of strategies that allow for the projectibility of special science generalizations without positing outlandish conspiracies: non-Humean pluralism, classical MRL theories of laws, and Albert and Loewer's theory. After arguing that none of the above fully succeed, we consider the conspiracy problem through the lens (...) of our preferred view of laws, an elaboration of the MRL view that we call the Better Best System (BBS) theory. BBS offers a picture on which, although all events supervene on a fundamental level, there is no one unique locus of projectibility; rather there are a large number of loci corresponding to the different areas (ecology, economics, solid-state chemistry, etc.) in which there are simple and strong generalizations to be made. While we expect that some amount of conspiracy-fear-inducing special science projectibility is inevitable given BBS, we'll argue that this is unobjectionable. It follows from BBS that the laws of any particular special or fundamental science amount to a proper subset of the laws. From this vantage point, the existence of projectible special science generalizations not guaranteed by the fundamental laws is not an occasion for conspiracy fantasies, but a predictable fact of life in a complex world. (shrink)

This paper searches for an explicit expression of the so-called problem of the direction of time. I argue that the traditional version of the problem is an artifact of a mistaken view in the foundations of statistical mechanics, and that to the degree it is a problem, it is really one general to all the special sciences. I then search the residue of the traditional problem for any remaining difficulty particular to time's arrow and find that there is a special (...) puzzle for some types of scientific realist. (shrink)

This paper discusses the mistake of understanding the laws and concepts of thermodynamics too literally in the foundations of statistical mechanics. Arguing that this error is still made in subtle ways, the article explores its occurrence in three examples: the Second Law, the concept of equilibrium and the definition of phase transitions.

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

We review the question of whether objective chances are compatible with determinism. We first outline what we mean by chance and what we mean by determinism. We then look at the alleged incompatibility between those concepts. Finally, we look at some ways that one might attempt to overcome the incompatibility.

The fundamental problem on which Ilya Prigogine and the Brussels–Austin Group have focused can be stated briefly as follows. Our observations indicate that there is an arrow of time in our experience of the world (e.g., decay of unstable radioactive atoms like uranium, or the mixing of cream in coffee). Most of the fundamental equations of physics are time reversible, however, presenting an apparent conflict between our theoretical descriptions and experimental observations. Many have thought that the observed arrow of time (...) was either an artifact of our observations or due to very special initial conditions. An alternative approach, followed by the Brussels–Austin Group, is to consider the observed direction of time to be a basic physical phenomenon due to the dynamics of physical systems. This essay focuses mainly on recent developments in the Brussels–Austin Group after the mid-1980s. The fundamental concerns are the same as in their earlier approaches (subdynamics, similarity transformations), but the contemporary approach utilizes rigged Hilbert space (whereas the older approaches used Hilbert space). While the emphasis on nonequilibrium statistical mechanics remains the same, their more recent approach addresses the physical features of large Poincare systems, nonlinear dynamics and the mathematical tools necessary to analyze them. (shrink)

I discuss recent work in ergodic theory and statistical mechanics, regarding the compatibility and origin of random and chaotic behavior in deterministic dynamical systems. A detailed critique of some quite radical proposals of the Prigogine school is given. I argue that their conclusion regarding the conceptual bankruptcy of the classical conceptions of an exact microstate and unique phase space trajectory is not completely justified. The analogy they want to draw with quantum mechanics is not sufficiently close to support their most (...) radical conclusion. (shrink)

I discuss a broad critique of the classical approach to the foundations of statistical mechanics (SM) offered by N. S. Krylov. He claims that the classical approach is in principle incapable of providing the foundations for interpreting the "laws" of statistical physics. Most intriguing are his arguments against adopting a de facto attitude towards the problem of irreversibility. I argue that the best way to understand his critique is as setting the stage for a positive theory which treats SM as (...) a theory in its own right, involving a completely different conception of a system's state. As the orthodox approach treats SM as an extension of the classical or quantum theories (one which deals with large systems), Krylov is advocating a major break with the traditional view of statistical physics. (shrink)

This book is an attempt to get to the bottom of an acute and perennial tension between our best scientific pictures of the fundamental physical structure of the ...

Foundational issues in statistical mechanics and the more general question of how probability is to be understood in the context of physical theories are both areas that have been neglected by philosophers of physics. This book fills an important gap in the literature by providing a most systematic study of how to interpret probabilistic assertions in the context of statistical mechanics. The book explores both subjectivist and objectivist accounts of probability, and takes full measure of work in the foundations of (...) probability theory, in statistical mechanics, and in mathematical theory. It will be of particular interest to philosophers of science, physicists and mathematicians interested in foundational issues, and also to historians of science. (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

This chapter unfolds a central philosophical problem of statistical mechanics. This problem lies in a clash between the Static Probabilities offered by statistical mechanics and the Dynamic Probabilities provided by classical or quantum mechanics. The chapter looks at the Boltzmann and Gibbs approaches in statistical mechanics and construes some of the great controversies in the field — for instance the Reversibility Paradox — as instances of this conflict. It furthermore argues that a response to this conflict is a critical choice (...) that shapes one's understanding of statistical mechanics itself, namely, whether it is to be conceived as a special or fundamental science. The chapter details some of the pitfalls of the latter ‘globalist’ position and seeks defensible ground for a kind of ‘localist’ alternative. (shrink)

An investigation is made into how the foundations of statistical mechanics are affected once we treat classical mechanics as an approximation to quantum mechanics in certain domains rather than as a theory in its own right; this is necessary if we are to understand statistical-mechanical systems in our own world. Relevant structural and dynamical differences are identified between classical and quantum mechanics (partly through analysis of technical work on quantum chaos by other authors). These imply that quantum mechanics significantly affects (...) a number of foundational questions, including the nature of statistical probability and the direction of time. (shrink)

This is an extensive review of recent work on the foundations of statistical mechanics.

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of their central concepts. (...) The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

Several philosophers have developed accounts to dissolve the apparent conflict between deterministic laws of nature and objective chances. These philosophers advocate the compatibility of determinism and chance. I argue that determinism and chance are incompatible and criticize the various notions of “deterministic chance” supplied by the compatibilists. Many of the compatibilists are strongly motivated by scientific theories where objective probabilities are combined with deterministic laws, the most salient of which is classical statistical mechanics. I show that, properly interpreted, statistical mechanics (...) is either an indeterministic theory or else its probabilities are not chances, just as incompatibilism demands. (shrink)

Foundational issues in statistical mechanics and the more general question of how probability is to be understood in the context of physical theories are both areas that have been neglected by philosophers of physics. This book fills an important gap in the literature by providing a most systematic study of how to interpret probabilistic assertions in the context of statistical mechanics. The book explores both subjectivist and objectivist accounts of probability, and takes full measure of work in the foundations of (...) probability theory, in statistical mechanics, and in mathematical theory. It will be of particular interest to philosophers of science, physicists and mathematicians interested in foundational issues, and also to historians of science. (shrink)

Statistical Mechanics (SM) involves probabilities. At the same time, most approaches to the foundations of SM—programs whose goal is to understand the macroscopic laws of thermal physics from the point of view of microphysics—are classical; they begin with the assumption that the underlying dynamical laws that govern the microscopic furniture of the world are (or can without loss of generality be treated as) deterministic. This raises some potential puzzles about the proper interpretation of these probabilities. It also raises, more generally, (...) the question of what kinds, if any, of objective probabilities can exist in a deterministic world. (shrink)