The problem of the peculiarcharacter of chemical laws and theories is a central topic in philosophy of chemistry. Oneof the most characteristic and, at the sametime, most puzzling examples in discussions onchemical laws and theories is Mendeleev''speriodic law. This law seems to be essentiallydifferent in its nature from the exact laws ofclassical physics, the latter being usuallyregarded as a paradigm of science byphilosophers. In this paper the main argumentsconcerning the peculiar character of chemicallaws and theories are examined. The laws ofchemistry (...) are natural laws to the same extentas are the laws of physics. The law discoveredby Mendeleev is a normal law of nature. It isnot a law of physics, nevertheless, it is exactin the same philosophical sense as are the lawsof physics. The periodic system of chemicalelements was established by constructing anidealized system of idealized elements. Thefundamental idealization substantiated byexperimental chemistry was the chemicalelement as a place in the periodicsystem. (shrink)

The philosophical analysis of chemistry has advanced at such a pace during the last dozen years that the existence of philosophy of chemistry as an autonomous discipline cannot be doubted any more. The present paper will attempt to analyse the experience of philosophy of chemistry at the, so to say, meta-level. Philosophers of chemistry have especially stressed that all sciences need not be similar to physics. They have tried to argue for chemistry as its own type of science and for (...) a pluralistic understanding of science in general. However, when stressing the specific character of chemistry, philosophers do not always analyse the question ‘What is science?’ theoretically. It is obvious that a ‘monistic’ understanding of science should not be based simply on physics as the epitome of science, regarding it as a historical accident that physics has obtained this status. The author’s point is that the philosophical and methodological image of science should not be chosen arbitrarily; instead, it should be theoretically elaborated as an idealization (theoretical model) substantiated on the historical practice of science. It is argued that although physics has, in a sense, justifiably obtained the status of a paradigm of science, chemistry, which is not simply a physical science, but a discipline with a dual character, is also relevant for elaborating a theoretical model of science. The theoretical model of science is a good tool for examining various issues in philosophy of chemistry as well as in philosophy of science or science studies generally. (shrink)

This is an attempt to take a look at chemistry from the point of view of practical realism. Besides its social–historical and normative aspects, the latter involves a direct reference to experimental research. According to Edward Caldin chemistry depends on our being able to isolate pure substances with reproducible properties. Thus, the very basis of chemistry is practical. Even the laws of chemistry are not stable but are subject to correction. At the same time, these statements do not necessarily make (...) Edward Caldin a predecessor of practical realism. The latter has other predecessors, like Rom Harré’s policy realism or Sami Pihlström’s pragmatic realism. Chemistry is an experimental science. The experiment is a purposeful and critically theory-guided constructive, manipulative, material interference with nature according to Rein Vihalemm, the founder of practical realism. Chemistry is physics-like science but just partly so. This is an important point in the context of the current paper. (shrink)

This 1983 book is a lively and clearly written introduction to the philosophy of natural science, organized around the central theme of scientific realism. It has two parts. 'Representing' deals with the different philosophical accounts of scientific objectivity and the reality of scientific entities. The views of Kuhn, Feyerabend, Lakatos, Putnam, van Fraassen, and others, are all considered. 'Intervening' presents the first sustained treatment of experimental science for many years and uses it to give a new direction to debates about (...) realism. Hacking illustrates how experimentation often has a life independent of theory. He argues that although the philosophical problems of scientific realism can not be resolved when put in terms of theory alone, a sound philosophy of experiment provides compelling grounds for a realistic attitude. A great many scientific examples are described in both parts of the book, which also includes lucid expositions of recent high energy physics and a remarkable chapter on the microscope in cell biology. (shrink)

In this work the distinguished physical chemist and philosopher, Michael Polanyi, demonstrates that the scientist's personal participation in his knowledge, in both its discovery and its validation, is an indispensable part of science itself. Even in the exact sciences, "knowing" is an art, of which the skill of the knower, guided by his personal commitment and his passionate sense of increasing contact with reality, is a logically necessary part. In the biological and social sciences this becomes even more evident. The (...) tendency to make knowledge impersonal in our culture has split fact from value, science from humanity. Polanyi wishes to substitute for the objective, impersonal ideal of scientific detachment an alternative ideal which gives attention to the personal involvement of the knower in all acts of understanding. His book should help to restore science to its rightful place in an integrated culture, as part of the whole person's continuing endeavor to make sense of the totality of his experience. In honor of this work and his The Study of Man Polanyi was presented with the Lecomte de Noüy Award for 1959. (shrink)

This lucidly written book examines the social and political significance of the natural sciences through a detailed and original account of science as an interpretive social practice.

In this paper, the elaboration of the concept of practical realist philosophy of science which began in the author's previous papers is continued. It is argued that practical realism is opposed to standard scientific realism, on the one hand, and antirealism, on the other. Standard scientific realism is challengeable due to its abstract character, as being isolated from practice. It is based on a metaphysical-ontological presupposition which raises the problem of the God's Eye point of view (as it was called (...) by Hilary Putnam). Joseph Rouse's conception of science as practice, Sami Pihlström's pragmatic realism, and even Ilkka Niiniluoto's critical scientific realism are interpreted as practical realist conceptions. Pihlström suggests that the contemporary scientific realist should be prepared to accept the pragmatically naturalized Kantian transcendental perspective on realism. It is argued, however, that this realistically naturalized Kantianism can be nothing more than practical realism, as originated by Karl Marx. (shrink)

This article is a translation into english of a lecture given by paneth in 1931. The content of the work is described by the section titles: (1) the need for epistemological clarification of the fundamental concepts of chemistry, (2) the concept of substance in chemistry, (3) the epistemological standpoint of the ancient atomists, (4) the epistemological position of the concept of element introduced by lavoisier, (5) the double meaning of the chemical concept of element: 'basic substance' and 'simple substance', And (...) (6) the double meaning of other chemical concepts. Sections (4)-(6) are published in the following number of this journal. (staff). (shrink)

Measurement theory in (Hand in The world through quantification. Oxford University Press, 2004; Suppes and Zinnes in Basic measurement theory. Psychology Series, 1962) is concerned with the assignment of number to objects of phenomena. Representational aspect of measurement is the extent to which the assigned numbers and arithmetics truthfully represent the underlying objects and their relations, and is characteristic to natural sciences; pragmatic aspect is the extent to which the assigned numbers serve purposes other than representing the underlying phenomena, and (...) is characteristic to social sciences (Hand in The world through quantification. Oxford University Press, 2004). Here I criticise this distinction of representational and pragmatic measurements on the basis of the earlier history of the periodic system of chemical elements, viewed in terms of a practice based philosophy of science by Rein Vihalemm. I argue that the periodic system, although a natural scientific system interpretable as a measurement system, has considerable, in Hand’s terms pragmatic, aspects in it. Those aspects include: tampering with the material measurement results for the theoretical ideal of systematicity; adopting metaphysical assumptions that cannot be experimentally proven, like individuality of elements and atomicity; theoretical construction of the abstract entity—element—as the reference of the measurement system amenable to mathematically elegant ordering. Contrary to Suppes and Zinnes (Basic measurement theory. Psychology Series, 1962) I also argue for the dependence of the assigned numerical system on the material-procedural base of the measurement. (shrink)

[Time, the fundamental dimension of our existence, has fascinated artists, philosophers, and scientists of every culture and every century. All of us can remember a moment as a child when time became a personal reality, when we realized what a "year" was, or asked ourselves when "now" happened. Common sense says time moves forward, never backward, from cradle to grave. Nevertheless, Einstein said that time is an illusion. Nature's laws, as he and Newton defined them, describe a timeless, deterministic universe (...) within which we can make predictions with complete certainty. In effect, these great physicists contended that time is reversible and thus meaningless. (shrink)

This survey article discusses the pragmatist tradition in twentieth century philosophy of science. Pragmatism, originating with Charles Peirce's writings on the pragmatic maxim in the 1870s, is a background both for scientific realism and, via the views of William James and John Dewey, for the relativist and/or constructivist forms of neopragmatism that have often been seen as challenging the very ideas of scientific rationality and objectivity. The paper shows how the issue of realism arises in pragmatist philosophy of science and (...) how some pragmatists, classical and modern, have attempted to deal with it. Various dimensions of the realism dispute are thus discussed, especially realism as contrasted to instrumentalism and realism as contrasted to relativism/constructivism. It is argued that the pragmatist tradition cannot avoid these tensions but is largely constituted by them. (shrink)

This article is a translation into english of a lecture given by paneth in 1931. The content of the work is described by the section titles: (1) the need for epistemological clarification of the fundamental concepts of chemistry, (2) the concept of substance in chemistry, (3) the epistemological standpoint of the ancient atomists, (4) the epistemological position of the concept of element introduced by lavoisier, (5) the double meaning of the chemical concept of element: 'basic substance' and 'simple substance', And (...) (6) the double meaning of other chemical concepts. Sections (4)-(6) are published in the following number of this journal. (staff). (shrink)

The autonomy of chemistry and the legitimacy of the philosophy of chemistry are usually discussed in the context of the issue of reduction of chemistry to physics, and defended making use of the failure of reductionistic claims. Until quite recent times a rather widespread viewpoint was, however, that the failure of reductionistic claims concerns actually epistemological aspect of reduction only, but the ontological reduction of chemistry to physics cannot be denied. The new problems of the autonomy of chemistry in the (...) context of reductionism seem to be ontological and metaphysical. In the present paper it is argued that there is no need for some kind of metaphysical-ontological underpinning for rejection of the secondary positions of chemistry and philosophy of chemistry with respect to physics and philosophy of physics. The issue can be elucidated in terms of the philosophy of science accepting practical realism (also known by other names). (shrink)

Practical realism is focused on the problem of how science really works. In the case of physics and chemistry, experiment is the centrepiece of scientific practice. The rapid development of contemporary natural science does not leave the experiment unaffected. The classical experiment is normally applied only to systems that can be considered structurally stable, repeatability being the key feature. After the introduction of the theoretical basis of irreversibility by Ilya Prigogine the essence of the experiment changed. The strict requirement of (...) repeatability has to be dropped. It will be discussed, whether the change is big enough for calling it revolutionary. There are means to update the understanding of the experiment by applying the experimental settings. The material experiment will probably be with us forever but its position on the scientific landscape will be shifted. (shrink)

In the philosophy of chemistry a view is developed according to which laws of nature and scientific theories are peculiar in chemistry. This view was criticized in an earlier issue of the Foundations of Chemistry (Vihalemm, Foundation of Chemistry 5(1): 7–22, 2003) referring to an essay by Maureen and John Christie (Christie and Christie, in N. Bushan and S. Rosenfeld (Eds.), Of Minds and Molecules: New Philosophical Perspectives on Chemistry. Oxford University Press, New York, 2000, pp. 34–50). This criticism was (...) responded by the Christies (Christie and Christie, Foundations of Chemistry 5(2): 165–177, 2003). In the present article the debate is continued. The main issues which need to be elucidated in order to carry the analysis forward are pointed out and discussed. The relevance of a theoretical model of science for the philosophy of chemistry is stressed. (shrink)

Nonclarity around the understandingof the concept of chaos has caused someconfusion in the contemporary natural science.For instance, not making a clear distinctionbetween the deterministic and quantum chaos hasmade it impossible to evaluate the approach ofIlya Prigogine in an appropriate way. It isshown that Jean Bricmont has missed the targetin his critique of I. Prigogine's ideas, as thelatter has concentrated his interest on systemsconsisting of infinite (arbitrarily large)number of particles in incessant mutualimpact, the former on systems that have afinite (not necessarily (...) large, althoughsometimes very large) number of particles,which move freely of any mutual impact orparticipate only in transient interaction. Thedifference may sometimes be quite crucial. Itis also suggested that if we consider theirreversibility as the basic element ofdescription of physical world, the world oftrajectories and wave functions cannot beresearched apart from this real irreversibility. (shrink)

Dans cet article, on suggère qu’un rôle central peut être assigné à la philosophie de la chimie dans la philosophie des sciences post-kuhnienne en général, et dans l’analyse du débat opposant le réalisme scientifique à l’anti-réalisme dans la philosophie des sciences standard. La philosophie des sciences construit la science comme une pratique plus que comme un réseau d’assertions. On soutient que le réalisme pratique permet d’éviter les défauts à la fois du réalisme scientifique standard et de l’anti-réalisme. On analyse un (...) livre important publié récemment, B. Bensaude-Vincent’s & J. Simon’s Chemistry — The Impure Science [Bensaude-Vincent & Simon 2008], et on interprète la position des auteurs comme une sorte de réalisme pratique. (shrink)

This is an attempt to take a look at chemistry from the point of view of practical realism. Besides its social–historical and normative aspects, the latter involves a direct reference to experimental research. According to Edward Caldin chemistry depends on our being able to isolate pure substances with reproducible properties. Thus, the very basis of chemistry is practical. Even the laws of chemistry are not stable but are subject to correction. At the same time, these statements do not necessarily make (...) Edward Caldin a predecessor of practical realism. The latter has other predecessors, like Rom Harré’s policy realism or Sami Pihlström’s pragmatic realism. Chemistry is an experimental science. The experiment is a purposeful and critically theory-guided constructive, manipulative, material interference with nature according to Rein Vihalemm, the founder of practical realism. Chemistry is physics-like science but just partly so. This is an important point in the context of the current paper. (shrink)

Whitehead’s and Prigogine’s philosophies of science are similar in this respect that they both areinterested in ontology built in the light of modern science. This kind of ontological approach, especially Whitehead’s metaphysical reasoning is usually regarded as speculative which should be avoidedin philosophy of science. Ilya Prigogine and Isabelle Stengers appreciated, however, Whitehead’s metaphysics as cosmology in that being the most ambitious attempt to elaborate a philosophy of naturethat, although speculative, is not directed against science or towards separation of philosophy (...) fromthe actual science. Although Whitehead criticized the classical science, he did not identify it withscience in general and did not acknowledge the respective domains and tasks of science and philosophy as distinct of principle from each other. According to Prigogine and Stengers Whitehead’s philosophy was somewhat the forerunner of Prigogine’s non-classical science which gives a new content to thespeculations of Whitehead. Chemistry was a starting point of Prigogine’s non-classical physical theory.In the present paper Prigogine’s conception of non-classical science is examined from the point ofview of a theoretical conception of science elaborated in the context of philosophy of chemistry.Prigogine and Stengers, as well as Whitehead, have not really presented a theoretical conception ofscience. It is argued that the latter, however, offers a key for examining various issues in philosophy ofscience and understanding science in general, including Prigogine’s non-classical science. Appreciating Prigogine’s optimism concerning the chances of science that has liberated itself from the myth,the author still finds that this optimism can also be misleading as it can create a false impression thatthis new science does not deal with idealizations any more, that it is not a means of inquiry resultingfrom special requirements and aims, but will really understand the world “as it is” to the point thatthe problems of so called human world, including those of, e.g., ethics would be, in principle, scientifically understandable. In fact, however, if non-classical science manages rid itself from the myth ofclassical science, the only change will be that it does not equate the scientific picture of world andscientifically modelled reality with the real world “as it is”.Keywords: non-classical science, philosophy of chemistry, Prigogine’s scientific ontology, theoretical model of science, Whitehead’s metaphysical ontology. (shrink)