For the generalizations of thermodynamics to obtain, it appears that a very ‘special’ initial condition of the universe is required. Is this initial condition itself in need of explanation? I argue that it is not. In so doing, I offer a framework in which to think about ‘special’ initial conditions in all areas of science, though I concentrate on the case of thermodynamics. I urge the view that it is not always a serious mark against a theory that it must (...) posit an ‘improbable’ initial condition. (shrink)

This article argues that most of the approaches to the foundations of statistical mechanics have severed their link with the original foundational project, the project of demonstrating how real mechanical systems can behave thermodynamically.

This book is an attempt to get to the bottom of an acute and perennial tension between our best scientific pictures of the fundamental physical structure of the world and our everyday empirical experience of it. The trouble is about the direction of time. The situation (very briefly) is that it is a consequence of almost every one of those fundamental scientific pictures--and that it is at the same time radically at odds with our common sense--that whatever can happen can (...) just as naturally happen backwards. Albert provides an unprecedentedly clear, lively, and systematic new account--in the context of a Newtonian-Mechanical picture of the world--of the ultimate origins of the statistical regularities we see around us, of the temporal irreversibility of the Second Law of Thermodynamics, of the asymmetries in our epistemic access to the past and the future, and of our conviction that by acting now we can affect the future but not the past. Then, in the final section of the book, he generalizes the Newtonian picture to the quantum-mechanical case and (most interestingly) suggests a very deep potential connection between the problem of the direction of time and the quantum-mechanical measurement problem. The book aims to be both an original contribution to the present scientific and philosophical understanding of these matters at the most advanced level, and something in the nature of an elementary textbook on the subject accessible to interested high-school students. Table of Contents: Preface 1. Time-Reversal Invariance 2. Thermodynamics 3. Statistical Mechanics 4. The Reversibility Objections and the Past-Hypothesis 5. The Scope of Thermodynamics 6. The Asymmetries of Knowledge and Intervention 7. Quantum Mechanics Appendix: Gedankenexperiments with Heat Engines Index Reviews of this book: The foundations of statistical mechanisms are often presented in physics textbooks in a rather obscure and confused way. By challenging common ways of thinking about this subject, Time and Chance can do quite a lot to improve this situation. --Jean Bricmont, Science Albert is perfecting a style of foundational analysis that is uniquely his own...It has a surgical precision...and it is ruthless with pretensions. The foundations of thermodynamics is a topic that has accumulated a good deal of dead wood; this is a fire that will burn and burn. --Simon W. Saunders, Oxford University As usual with Albert's work, the exposition is brisk and to the point, and exceptionally clear...The book will be an extremely valuable contribution to the literature on the subject of philosophical issues in thermodynamics and statistical mechanics, a literature which has been thin on the ground but is now growing as it deserves to. --Lawrence Sklar, University of Michigan. (shrink)

It has become something of a dogma in the philosophy of science that modern cosmology has completed Boltzmann's program for explaining the statistical validity of the Second Law of thermodynamics by providing the low entropy initial state needed to ground the asymmetry in entropic behavior that underwrites our inference about the past. This dogma is challenged on several grounds. In particular, it is argued that it is likely that the Boltzmann entropy of the initial state of the universe is an (...) ill-defined or severely hobbled concept. It is also argued that even if the entropy of the initial state of the universe had a well-defined, low value, this would not suffice to explain why thermodynamics works as well as it does for the kinds of systems we care about. Because the role of Boltzmann entropy in our inferences to the past has been vastly overrated, the failure of the Boltzmann program does not pose a serious problem for our knowledge of the past. But it does call a different explanation of why thermodynamics works as well as it does. A suggestion is offered for a different approach. (shrink)

This paper proves that Maxwell's Demon is compatible with classical mechanics. In particular it shows how the cycle of operation - including measurement and erasure - can be carried out with no entropy cost, contrary to the Landauer-Bennett thesis (according to which memory erasure costs kln2 of entropy increase per bit). The Landauer-Bennet thesis is thus proven to be mistaken.

This paper investigates what the source of time-asymmetry is in thermodynamics, and comments on the question whether a time-symmetric formulation of the Second Law is possible.

In a previous article, we have demonstrated by a general phase space argument that a Maxwellian Demon is compatible with statistical mechanics. In this article, we show how this idea can be put to work in the prevalent model of the Demon, namely, a particle-in-a-box, used, for example, by Szilard and Bennett. In the literature, this model is used in order to show that a Demon is incompatible with statistical mechanics, either classical or quantum. However, we show that a detailed (...) phase space analysis of this model illustrates that a Maxwellian Demon is compatible with statistical mechanics. (shrink)

In his recent book, Time and Chance, David Albert claims that by positing that there is a uniform probability distribution defined, on the standard measure, over the space of microscopic states that are compatible with both the current macrocondition of the world, and with what he calls the “past hypothesis”, we can explain the time asymmetry of all of the thermodynamic behavior in the world. The principal purpose of this paper is to dispute this claim. I argue that Albert's proposal (...) fails in his stated goal—to show how to use the time‐reversible dynamics of Newtonian physics to “underwrite the actual content of our thermodynamic experience” (Albert 2000, 159). Albert's proposal can satisfactorily explain why the overall entropy of the universe as a whole is increasing, but it does not and cannot explain the increasing entropy of relatively small, relatively short‐lived systems in energetic isolation without making use of a principle that leads to reversibility objections. (shrink)

It is generally thought that objective chances for particular events different from 1 and 0 and determinism are incompatible. However, there are important scientific theories whose laws are deterministic but which also assign non-trivial probabilities to events. The most important of these is statistical mechanics whose probabilities are essential to the explanations of thermodynamic phenomena. These probabilities are often construed as 'ignorance' probabilities representing our lack of knowledge concerning the microstate. I argue that this construal is incompatible with the role (...) of probability in explanation and laws. This is the 'paradox of deterministic probabilities'. After surveying the usual list of accounts of objective chance and finding them inadequate I argue that an account of chance sketched by David Lewis can be modified to solve the paradox of deterministic probabilities and provide an adequate account of the probabilities in deterministic theories like statistical mechanics. (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the alleged foundation of the very notion (...) of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

The renewed interest in the foundations of quantum statistical mechanics in recent years has led us to study John von Neumann’s 1929 article on the quantum ergodic theorem. We have found this almost forgotten article, which until now has been available only in German, to be a treasure chest, and to be much misunderstood. In it, von Neumann studied the long-time behavior of macroscopic quantum systems. While one of the two theorems announced in his title, the one he calls the (...) “quantum H-theorem,” is actually a much weaker statement than Boltzmann’s classical H-theorem, the other theorem, which he calls the “quantum ergodic theorem,” is a beautiful and very non-trivial result. It expresses a fact we call “normal typicality” and can be summarized as follows: For a “typical” finite family of commuting macroscopic observables, every initial wave function ψ0 from a micro-canonical energy shell so evolves that for most times t in the long run, the joint probability distribution of these observables obtained from ψt is close to their micro-canonical distribution. (shrink)