This book exhibits deep philosophical quandaries and intricacies of the historical development of science lying behind a simple and fundamental item of common sense in modern science, namely the composition of water as H2O. Three main phases of development are critically re-examined, covering the historical period from the 1760s to the 1860s: the Chemical Revolution, early electrochemistry, and early atomic chemistry. In each case, the author concludes that the empirical evidence available at the time was not decisive in settling the (...) central debates and therefore the consensus that was reached was unjustified or at least premature. This leads to a significant re-examination of the realism question in the philosophy of science and a unique new advocacy for pluralism in science. Each chapter contains three layers, allowing readers to follow various parts of the book at their chosen level of depth and detail. The second major study in "complementary science", this book offers a rare combination of philosophy, history and science in a bid to improve scientific knowledge through history and philosophy of science. (shrink)

The aim of this paper is to show that quantum mechanics can be interpreted according to a pragmatist approach. The latter consists, first, in giving a pragmatic definition to each term used in microphysics, second, in making explicit the functions any theory must fulfil so as to ensure the success of the research activity in microphysics, and third, in showing that quantum mechanics is the only theory which fulfils exactly these functions.

This paper first queries what type of concept of emergence, if any, could be connected with the different chemical activities subsumed under the label ‘quantum chemistry’. In line with Roald Hoffmann, we propose a ‘rotation to research laboratory’ in order to point out how practitioners hold a molecular whole, its parts, and the surroundings together within their various methods when exploring chemical transformation. We then identify some requisite contents that a concept of emergence must incorporate in order to be coherent (...) from the standpoint of the scientific practices involved. In this respect, we finally propose a relational form of emergence which pays attention to the constitutive role of the modes of intervention and to the co-definition of the levels of organization. No metaphysical distinction between the higher and basic levels of organization is supposed, but only a plurality of modes of access. Moreover, these modes of access are not construed as mere ways of revealing intrinsic patterns of organization but, on the contrary, are considered to be active elements on which the constitution of those patterns depends. What is at stake in this paper is therefore not an ontological form of emergence but an agnostic one which fits what chemists do in their daily work. (shrink)

Mulliken proposed an Aufbauprinzip for the molecules on the basis of molecular spectroscopy while establishing, point by point, his concept of molecular orbit. It is the concept of electronic state which becomes the lever for his attribution of electronic configurations to a molecule. In 1932, the concept of orbit was transmuted into that of the molecular orbital to integrate the probabilistic approach of Born and to achieve quantitative accuracy. On the basis of the quantum works of Hund, Wigner, Lennard-Jones and (...) group theory, he suggested the fragment method to establish the characteristics of molecular orbital for polyatomic molecules. These developments make it possible to bring elements of thought on the relation between a molecular whole and its parts . An operational realism combined with the second law of thermodynamics can pave the way for interesting tracks in the mereological study of chemical systems. (shrink)

"The first two lectures place the alternative I defend -- a kind of pragmatic realism -- in a historical and metaphysical context. Part of that context is provided by Husserl's remark that the history of modern philosophy begins with Galileo -- that is, modern philosophy has been hypnotized by the idea that scientific facts are all the facts there are. Another part is provided by the analysis of a very simple example of what I call 'contextual relativity'. The position I (...) defend holds that truth depends on conceptual scheme and it is nonetheless 'real truth'. "In my third lecture I turn to the Kantian antecedents of this view, explaining what I think should be retained of the Kantian idea of autonomy as the central theme of morality, and extracting from Kant's work a 'moral image of the world' that connects the ideals of equality and intellectual liberty. In this lecture I defend the idea that moral images are an indispensible part of our moral and cultural heritage. "In the final lecture I defend the idea of moral objectivity. I compare our epistemological positions in ethics, history, analysis of human character, and science, and I argue that in no area can we hope for a 'foundation' which is more ultimate than the beliefs that actually, at a given time, function as foundational in the area, the beliefs concerning which one has to say 'this is where my spade is turned'. In ethics such beliefs are represented in moral images of the world.". (shrink)

Introduction: Science and Common Sense Long before the beginnings of modern civilization, men ac- quired vast funds of information about their environment. ...

1 Knowledge and Justification This book is an investigation of one central problem which arises in the attempt to give a philosophical account of empirical ...

This chapter contains sections titled: Introduction What is Chemistry about? Is Chemistry Reducible to Physics? Are There Fundamental Limits to Chemical Knowledge? Is Chemical Research Ethically Neutral? Conclusion References.

Given the rich diversity of research fields usually ascribed to chemistry in a broad sense, the present paper tries to dig our characteristic parts of chemistry that can be conceptually distinguished from interdisciplinary, applied, and specialized subfields of chemistry, and that may be called chemistry in a very narrow sense, or 'the chemical core of chemistry'. Unlike historical, ontological, and 'anti-reductive' approaches, I use a conceptual approach together with some methodological implications that allow to develop step by step a kind (...) of cognitive architecture for chemistry, which basically contains: (1) systematic chemical knowledge on the experimental level; (2) clarification of chemical species; (3) chemical classification systems; (4) theoretical foundation through the chemical theory of structural formulas. In a succeeding paper the results will be checked for resisting physicalistic reduction. (shrink)

The ArgumentEtienn-François Geoffroy' Table des Rapports is generally regarded as a landmark in the evolution of chemistry during the eighteenth century. Issues have arisen among historians concerning the significance and originality of the Table that require fuller attention to the immediate context of chemical research in the Academie des sciences during the two decades that preceded its appearance. The present paper argues that, despite the transition from communal to individual research projects that marked the reorganization of the Academy in 1699, (...) chemists continued to pursue shared problems within a communal ethos. The interactions between Wilhelm Homberg, Etienne-François Geoffroy, and Louis Lemery were particularly prominent. The paper traces one example of this interaction, involving the sulfur principle and its influence on one entry in Geoffroy's Table. Further such studies are needed to elucidate the relation between the concepts of chemical composition and reactions implied in Geoffroy's table and the concepts embodied in the previous work of Geoffroy and his associates in the Academy. (shrink)

Had more philosophers of science come from chemistry, their thinking would have been different. I begin by looking at a typical chemical paper, in which making something is the leitmotif, and conjecture/refutation is pretty much irrelevant. What in fact might have been, might be, different? The realism of chemists is reinforced by their remarkable ability to transform matter; they buy into reductionism where it serves them, but make no real use of it. Incommensurability is taken without a blink, and actually (...) serves. The preeminence of synthesis in chemistry could have led philosophers of science to take more seriously questions of aesthetics within science, and to find a place in aesthetics for utility. The necessary motion twixt macroscopic and microscopic views of matter in modern chemistry leads to the coexistence of symbolic and iconic representations. And in another way to the deliberate, creative violation of categories. (shrink)

Nowadays it is well known among historians of science that Francis Bacon, one of the modern defender of the experimental method, owed much of his thoughts to the chemical or alchemical tradition (cf. e.g., Gregory 1938, West 1961, Linden 1974, and Rees 1977). In fact, alchemy, particularly in the Arabic tradition, was always based on laboratory investigations by carefully examining the results of controlled manipulation of materials.1 It is also well known that Francis Bacon’s appeal to the experimental method was (...) severe criticism of scholasticism in philosophy of nature and, in particular, of authority as the basis of knowledge.2 If we compare philosophy of nature in the early 17th century with phi-. (shrink)

Chemical ideas about the diversity of matter in terms of elements and compound substances and their transformations have been pivotal to any scientific or pre-scientific approach ever since. From ancient natural philosophy and alchemy to modern 19th-century chemistry, these ideas were made both the basis of philosophical systems and the target of critical reflection. After temporary interruption, when modern philosophy of science materialized as a discourse on mathematical physics, philosophy of chemistry emerged anew in the 1980s and is now a (...) flourishing field in which philosophers, chemists, and historians of chemistry are engaged. While many of the old philosophical issues have been rediscovered and discussed, new issues have appeared due to shifts of general philosophical foci, alliances with historians and sociologists of science, and the changes of chemistry and its role in society. (shrink)

Unlike other branches of science, the scientific products of synthetic chemistry are not only ideas but also new substances that change our material world, for the benefit or harm of living beings. This paper provides for the first time a systematical analysis of moral issues arising from chemical synthesis, based on concepts of responsibility and general morality. Topics include the questioning of moral neutrality of chemical synthesis as an end in itself, chemical weapons research, moral objections against improving material conditions (...) of life by chemical means, and freedom of research. The paper aims at providing both a sound basis for moral judgements of chemistry in a public discourse and a framework for chemists to reflect on the moral relevance of their activity. (shrink)

The paper shows epistemological, methodological and ontological peculiarities of chemistry taken as a classificatory science of materials using experimental methods. Without succumbing to standard interpretations of physical science, chemical methods of experimental investigation, classification, reference, theorizing, prediction and production of new entities are developed one by one as first steps towards a philosophy of chemistry. Chemistry challenges traditional concepts of empirical object, empirical predicate, reference frame and theory, but also the distinction commonly drawn between natural science and technology. Due to (...) its many peculiarities, I propose to treat chemistry philosophically as a special type of science, apart from other sciences. (shrink)

Nowadays it is well known among historians of science that Francis Bacon, one of the modern defender of the experimental method, owed much of his thoughts to the chemical or alchemical tradition (cf. e.g., Gregory 1938, West 1961, Linden 1974, and Rees 1977). In fact, alchemy, particularly in the Arabic tradition, was always based on laboratory investigations by carefully examining the results of controlled manipulation of materials.1..